| blob | e61e47222eeef02a88c80a5a612a253d26fa3a26 |
1 ELEMENTS
2 H O SI
3 END
4 SPECIES
5 H2 O2 OH H H2O O H2O2 HO2
6 SIH4 SIH3 SIH2 SIH SIO SIO2 HSIO SIH2O SIH3O SIH3O2+ SIH4O2
7 N2
8 END
9 THERMO
10 SIH3O SI 1.H 3.O 1. G 300.000 5000.000 1
11 0.37707966E+01 0.78711497E-02-0.26563839E-05 0.39444314E-09-0.21126164E-13 2
12 -0.13296131E+04 0.59295750E+01 0.21062040E+01 0.72165951E-02 0.53384720E-05 3
13 -0.73776363E-08 0.20756105E-11-0.47884505E+03 0.16152177E+02 4
14 SIH3O2+ SI 1.H 3.O 2. N 0. G 300.000 5000.000 1
15 0.66812963E+01 0.80057271E-02-0.27188507E-05 0.40631365E-09-0.21927725E-13 2
16 -0.42105544E+04-0.99423847E+01 0.20986490E+01 0.15786357E-01 0.75683261E-05 3
17 -0.11274587E-07 0.56665133E-11-0.26671854E+04 0.15007068E+02 4
18 SIH4O2 SI 1.H 4.O 2. N 0. G 300.000 5000.000 1
19 0.66812963E+01 0.80057271E-02-0.27188507E-05 0.40631365E-09-0.21927725E-13 2
20 -0.42105544E+04-0.99423847E+01 0.20986490E+01 0.15786357E-01 0.75683261E-05 3
21 -0.11274587E-07 0.56665133E-11-0.26671854E+04 0.15007068E+02 4
22 SIH2O SI 1.H 2.O 1. N 0. G 300.000 5000.000 1
23 0.32939910E+01 0.59522360E-02-0.21083880E-05 0.33459980E-09-0.19750180E-13 2
24 -0.13283760E+04 0.70293210E+01 0.32032740E+01 0.44987760E-02-0.45214720E-05 3
25 0.10444300E-07-0.61720710E-11-0.12958860E+05 0.84842740E+01 4
26 HSIO SI 1.H 1.O 1. N 0. G 300.000 5000.000 1
27 0.34714290E+01 0.31057530E-02-0.11005030E-05 0.17477250E-09-0.10263730E-13 2
28 0.30103527E+04 0.79153820E+01 0.30781400E+01 0.10178940E-01-0.31701710E-04 3
29 0.43635320E-08-0.19549500E-10 0.31101614E+04 0.92575020E+01 4
30 SIO SI 1.H 0.O 1. N 0. G 300.000 5000.000 1
31 3.74788350E+00 8.19919430E-04-3.25253960E-07 5.73249620E-11-3.51089440E-15 2
32 -1.33174300E+04 3.66100339E+00 3.25282760E+00 4.18231260E-04 3.78062020E-06 3
33 -5.10244830E-09 1.94713170E-12-1.30903400E+04 6.66174329E+00 4
34 SIO2 SI 1.H 0.O 2. N 0. S 300.000 5000.000 1
35 0.63467463E+01 0.21952215E-02 0.0 0.0 0.0 2
36 -0.11154241E+06-0.32060643E+02 0.63467463E+01 0.21952215E-02 0.0 3
37 0.0 0.0 -0.11154241E+06-0.32060643E+02 4
38 END
39 REACTIONS
40 H2 + O2 = OH+OH 1.170E+09 0 0
41 H2 + OH = H2O + H 1.170E+09 0 0
42 O + OH = O2 + H 5.000E+14 -0.50 0.
43 !H + O2 = O + OH 1.940E+14 0.00 16440.
44 O + H2 = OH + H 5.060E+04 2.67 6290.
45 H + O2 + M = HO2 + M 2.800E+19 -1.25 0.
46 H2/2.5/ H2O/12.5/
47 !OH + HO2 = H2O + O2 7.500E+12 0.00 0.
48 OH + HO2 = H2O + O2 7.890E+13 0.00 -497.
49 !H + HO2 = OH + OH 1.400E+14 0.00 1073.
50 H + HO2 = OH + OH 1.690E+14 0.00 874.
51 O + HO2 = O2 + OH 2.400E+13 0.00 1073. ! 1.4
52 OH + OH = O + H2O 6.000E+08 1.30 0.
53 H + H + M = H2 + M 1.000E+18 -1.00 0.
54 H2/0.0/ H2O/0./
55 H + H + H2 = H2 + H2 9.200E+16 -0.60 0.
56 H + H + H2O = H2 + H2O 6.000E+19 -1.25 0.
57 H + OH + M = H2O + M 1.600E+22 -2.00 0.
58 H + O + M = OH + M 6.200E+16 -0.60 0.
59 O + O + M = O2 + M 1.890E+13 0.00 -1788.
60 !H + HO2 = H2 + O2 1.250E+13 0.00 0.
61 H + HO2 = H2 + O2 6.280E+13 0.00 1411.
62 !HO2 + HO2 = H2O2 + O2 2.000E+12 0.00 0.
63 HO2 + HO2 = H2O2 + O2 4.200E+14 0.00 12000.
64 DUPLICATE
65 HO2 + HO2 = H2O2 + O2 1.300E+11 0.00 -1640.
66 DUPLICATE
67 H2O2 + M = OH + OH + M 6.300E+17 0.00 45500.
68 H2O2 + H = HO2 + H2 1.600E+12 0.00 3800.
69 H2O2 + OH = H2O + HO2 1.300E+11 0.00 -1630.
70 DUPLICATE
71 H2O2 + OH = H2O + HO2 5.800E+14 0.00 9560.
72 DUPLICATE
73 H + HO2 = O + H2O 3.100E+10 0.00 3590.
74 O + OH + M = HO2 + M 1.000E+16 0.00 0.
75 H2O2 + H = H2O + OH 1.000E+13 0.00 3590.
76 H2O2 + O = H2O + O2 8.400E+11 0.00 4260.
77 H2O2 + O = OH + HO2 2.000E+13 0.00 5900.
78 H2 + HO2 = H2O + OH 2.100E+13 0.00 18800.
79 SIH4 = SIH2 + H2 1.000E+13 0.00 52700.
80 SIH2 + O2 = HSIO + OH 3.200E+14 0.00 8000.
81 SIH2 + H2O = SIH2O + H2 3.000E+12 0.00 11400.
82 SIH4 + O2 = SIH3 + HO2 4.000E+13 0.00 42800.
83 SIH4 + H = SIH3 + H2 5.000E+12 0.00 2500.
84 SIH4 + O = SIH3 + OH 4.200E+12 0.00 1600.
85 SIH4 + OH = SIH3 + H2O 9.400E+12 0.00 100.
86 SIH4 + HO2 = SIH3 + H2O2 2.000E+12 0.00 10000.
87 SIH4 + SIH3O2+ = SIH3 + SIH4O2 1.100E+13 0.00 18500.
88 SIH3 + O2 = SIH3O2+ 2.000E+15 0.00 1200.
89 SIH3O2+ = SIH3O + O 2.000E+13 0.00 34000. ! 5.e12
90 SIH3O2+ = SIH2O + OH 3.000E+12 0.00 4000.
91 SIH3O2+ + HO2 = SIH4O2 + O2 3.000E+11 0.00 0.
92 SIH4O2 + H = SIH3O2+ + H2 4.800E+13 0.00 7950.
93 SIH4O2 = SIH3O + OH 6.500E+14 0.0 48700.
94 SIH3 + O2 = SIH3O + O 1.000E+13 0.00 0. ! 2
95 SIH3O + O2 = SIH2O + HO2 2.000E+13 0.00 0.
96 SIH3 + H = SIH2 + H2 2.000E+13 0.00 0.
97 SIH3 + O = SIH2O + H 2.000E+13 0.00 0.
98 SIH3 + OH = SIH2O + H2 6.000E+12 0.00 0.
99 SIH3 + HO2 = SIH2 + H2O2 2.000E+13 0.00 0.
100 SIH3 + SIH3 = SIH2 + SIH4 2.000E+12 0.00 0.
101 SIH2O + O2 = HSIO + HO2 4.000E+14 0.00 35000.
102 SIH2O + M = HSIO + H + M 2.000E+15 0.00 84500.
103 SIH2O + H = HSIO + H2 5.300E+14 0.00 10500.
104 SIH2O + O = HSIO + OH 1.800E+13 0.00 3080.
105 SIH2O + OH = HSIO + H2O 7.500E+12 0.00 170.
106 SIH2O + HO2 = HSIO + H2O2 1.000E+13 0.00 12000.
107 HSIO + M = H + SIO + M 5.000E+14 0.00 29000.
108 HSIO + O2 = SIO + HO2 3.000E+13 0.0 0.0
109 HSIO + H = SIO + H2 2.000E+14 0.00 0.
110 REV /1 2 3/
111 LT /1 2/
112 RLT /3 4/
113 HSIO + O = SIO + OH 1.000E+14 0.00 0.
114 FIT1 /1 2 3 4/
115 HSIO + OH = SIO + H2O 1.000E+14 0.00 0.
116 HSIO + HO2 = SIO + H2O2 1.000E+14 0.00 0.
117 SIO + OH (+H) = SIO2 + H (+H) 4.000E+12 0.00 5700.
118 LOW /1 2 3/
119 TROE /1 2 3 4/
120 SIO + HO2 = SIO2 + OH 1.000E+12 0.00 0.
121 LT /1.0 3.0/
122 SIO + O + M = SIO2 + M 0.0E+13 0.0 0.0
123 UNITS /KCAL/
124 SIO + O2 = SIO2 + O 4.000E+13 0 1
125 RORD /SIO2 3/
126 FORD /O2 4/
127 REV /1 2 3/
128 END