| blob | eb5d63d38899bbb60f405329113e6b7414406ca6 |
1 ! GRI-Mech Version 3.0 7/30/99 CHEMKIN-II format
2 ! See README30 file at anonymous FTP site unix.sri.com, directory gri;
3 ! WorldWideWeb home page http://www.me.berkeley.edu/gri_mech/ or
4 ! through http://www.gri.org , under 'Basic Research',
5 ! for additional information, contacts, and disclaimer
6 ELEMENTS
7 O H C N AR
8 END
9 SPECIES
10 CH4 CH2O CH3O H O2 H2 O OH H2O HO2 H2O2
11 C CH CH2 CH2(S) CH3 CO CO2
12 HCO CH2OH CH3OH C2H C2H2 C2H3
13 C2H4 C2H5 C2H6 HCCO CH2CO HCCOH N NH
14 NH2 NH3 NNH NO NO2 N2O HNO CN
15 HCN H2CN HCNN HCNO HOCN HNCO NCO N2
16 AR C3H7 C3H8 CH2CHO CH3CHO
17 END
18 REACTIONS
19 O+H2<=>H+OH 3.870E+04 2.700 6260.00
20 O+HO2<=>OH+O2 2.000E+13 .000 .00
21 O+H2O2<=>OH+HO2 9.630E+06 2.000 4000.00
22 O+CH<=>H+CO 5.700E+13 .000 .00
23 O+CH2<=>H+HCO 8.000E+13 .000 .00
24 O+CH2(S)<=>H2+CO 1.500E+13 .000 .00
25 O+CH2(S)<=>H+HCO 1.500E+13 .000 .00
26 O+CH3<=>H+CH2O 5.060E+13 .000 .00
27 O+CH4<=>OH+CH3 1.020E+09 1.500 8600.00
28 O+HCO<=>OH+CO 3.000E+13 .000 .00
29 O+HCO<=>H+CO2 3.000E+13 .000 .00
30 O+CH2O<=>OH+HCO 3.900E+13 .000 3540.00
31 O+CH2OH<=>OH+CH2O 1.000E+13 .000 .00
32 O+CH3O<=>OH+CH2O 1.000E+13 .000 .00
33 O+CH3OH<=>OH+CH2OH 3.880E+05 2.500 3100.00
34 O+CH3OH<=>OH+CH3O 1.300E+05 2.500 5000.00
35 O+C2H<=>CH+CO 5.000E+13 .000 .00
36 O+C2H2<=>H+HCCO 1.350E+07 2.000 1900.00
37 O+C2H2<=>OH+C2H 4.600E+19 -1.410 28950.00
38 O+C2H2<=>CO+CH2 6.940E+06 2.000 1900.00
39 O+C2H3<=>H+CH2CO 3.000E+13 .000 .00
40 O+C2H4<=>CH3+HCO 1.250E+07 1.830 220.00
41 O+C2H5<=>CH3+CH2O 2.240E+13 .000 .00
42 O+C2H6<=>OH+C2H5 8.980E+07 1.920 5690.00
43 O+HCCO<=>H+2CO 1.000E+14 .000 .00
44 O+CH2CO<=>OH+HCCO 1.000E+13 .000 8000.00
45 O+CH2CO<=>CH2+CO2 1.750E+12 .000 1350.00
46 O2+CO<=>O+CO2 2.500E+12 .000 47800.00
47 O2+CH2O<=>HO2+HCO 1.000E+14 .000 40000.00
48 H+2O2<=>HO2+O2 2.080E+19 -1.240 .00
49 H+O2+H2O<=>HO2+H2O 11.26E+18 -.760 .00
50 H+O2+N2<=>HO2+N2 2.600E+19 -1.240 .00
51 H+O2+AR<=>HO2+AR 7.000E+17 -.800 .00
52 H+O2<=>O+OH 2.650E+16 -.6707 17041.00
53 2H+H2<=>2H2 9.000E+16 -.600 .00
54 2H+H2O<=>H2+H2O 6.000E+19 -1.250 .00
55 2H+CO2<=>H2+CO2 5.500E+20 -2.000 .00
56 H+HO2<=>O+H2O 3.970E+12 .000 671.00
57 H+HO2<=>O2+H2 4.480E+13 .000 1068.00
58 H+HO2<=>2OH 0.840E+14 .000 635.00
59 H+H2O2<=>HO2+H2 1.210E+07 2.000 5200.00
60 H+H2O2<=>OH+H2O 1.000E+13 .000 3600.00
61 H+CH<=>C+H2 1.650E+14 .000 .00
62 H+CH2(S)<=>CH+H2 3.000E+13 .000 .00
63 H+CH4<=>CH3+H2 6.600E+08 1.620 10840.00
64 H+HCO<=>H2+CO 7.340E+13 .000 .00
65 H+CH2O<=>HCO+H2 5.740E+07 1.900 2742.00
66 H+CH2OH<=>H2+CH2O 2.000E+13 .000 .00
67 H+CH2OH<=>OH+CH3 1.650E+11 .650 -284.00
68 H+CH2OH<=>CH2(S)+H2O 3.280E+13 -.090 610.00
69 H+CH3O<=>H+CH2OH 4.150E+07 1.630 1924.00
70 H+CH3O<=>H2+CH2O 2.000E+13 .000 .00
71 H+CH3O<=>OH+CH3 1.500E+12 .500 -110.00
72 H+CH3O<=>CH2(S)+H2O 2.620E+14 -.230 1070.00
73 H+CH3OH<=>CH2OH+H2 1.700E+07 2.100 4870.00
74 H+CH3OH<=>CH3O+H2 4.200E+06 2.100 4870.00
75 H+C2H3<=>H2+C2H2 3.000E+13 .000 .00
76 H+C2H4<=>C2H3+H2 1.325E+06 2.530 12240.00
77 H+C2H5<=>H2+C2H4 2.000E+12 .000 .00
78 H+C2H6<=>C2H5+H2 1.150E+08 1.900 7530.00
79 H+HCCO<=>CH2(S)+CO 1.000E+14 .000 .00
80 H+CH2CO<=>HCCO+H2 5.000E+13 .000 8000.00
81 H+CH2CO<=>CH3+CO 1.130E+13 .000 3428.00
82 H+HCCOH<=>H+CH2CO 1.000E+13 .000 .00
83 OH+H2<=>H+H2O 2.160E+08 1.510 3430.00
84 2OH<=>O+H2O 3.570E+04 2.400 -2110.00
85 OH+HO2<=>O2+H2O 1.450E+13 .000 -500.00
86 DUPLICATE
87 OH+H2O2<=>HO2+H2O 2.000E+12 .000 427.00
88 DUPLICATE
89 OH+H2O2<=>HO2+H2O 1.700E+18 .000 29410.00
90 DUPLICATE
91 OH+C<=>H+CO 5.000E+13 .000 .00
92 OH+CH<=>H+HCO 3.000E+13 .000 .00
93 OH+CH2<=>H+CH2O 2.000E+13 .000 .00
94 OH+CH2<=>CH+H2O 1.130E+07 2.000 3000.00
95 OH+CH2(S)<=>H+CH2O 3.000E+13 .000 .00
96 OH+CH3<=>CH2+H2O 5.600E+07 1.600 5420.00
97 OH+CH3<=>CH2(S)+H2O 6.440E+17 -1.340 1417.00
98 OH+CH4<=>CH3+H2O 1.000E+08 1.600 3120.00
99 OH+CO<=>H+CO2 4.760E+07 1.228 70.00
100 OH+HCO<=>H2O+CO 5.000E+13 .000 .00
101 OH+CH2O<=>HCO+H2O 3.430E+09 1.180 -447.00
102 OH+CH2OH<=>H2O+CH2O 5.000E+12 .000 .00
103 OH+CH3O<=>H2O+CH2O 5.000E+12 .000 .00
104 OH+CH3OH<=>CH2OH+H2O 1.440E+06 2.000 -840.00
105 OH+CH3OH<=>CH3O+H2O 6.300E+06 2.000 1500.00
106 OH+C2H<=>H+HCCO 2.000E+13 .000 .00
107 OH+C2H2<=>H+CH2CO 2.180E-04 4.500 -1000.00
108 OH+C2H2<=>H+HCCOH 5.040E+05 2.300 13500.00
109 OH+C2H2<=>C2H+H2O 3.370E+07 2.000 14000.00
110 OH+C2H2<=>CH3+CO 4.830E-04 4.000 -2000.00
111 OH+C2H3<=>H2O+C2H2 5.000E+12 .000 .00
112 OH+C2H4<=>C2H3+H2O 3.600E+06 2.000 2500.00
113 OH+C2H6<=>C2H5+H2O 3.540E+06 2.120 870.00
114 OH+CH2CO<=>HCCO+H2O 7.500E+12 .000 2000.00
115 2HO2<=>O2+H2O2 1.300E+11 .000 -1630.00
116 DUPLICATE
117 2HO2<=>O2+H2O2 4.200E+14 .000 12000.00
118 DUPLICATE
119 HO2+CH2<=>OH+CH2O 2.000E+13 .000 .00
120 HO2+CH3<=>O2+CH4 1.000E+12 .000 .00
121 HO2+CH3<=>OH+CH3O 3.780E+13 .000 .00
122 HO2+CO<=>OH+CO2 1.500E+14 .000 23600.00
123 HO2+CH2O<=>HCO+H2O2 5.600E+06 2.000 12000.00
124 C+O2<=>O+CO 5.800E+13 .000 576.00
125 C+CH2<=>H+C2H 5.000E+13 .000 .00
126 C+CH3<=>H+C2H2 5.000E+13 .000 .00
127 CH+O2<=>O+HCO 6.710E+13 .000 .00
128 CH+H2<=>H+CH2 1.080E+14 .000 3110.00
129 CH+H2O<=>H+CH2O 5.710E+12 .000 -755.00
130 CH+CH2<=>H+C2H2 4.000E+13 .000 .00
131 CH+CH3<=>H+C2H3 3.000E+13 .000 .00
132 CH+CH4<=>H+C2H4 6.000E+13 .000 .00
133 CH+CO2<=>HCO+CO 1.900E+14 .000 15792.00
134 CH+CH2O<=>H+CH2CO 9.460E+13 .000 -515.00
135 CH+HCCO<=>CO+C2H2 5.000E+13 .000 .00
136 CH2+O2=>OH+H+CO 5.000E+12 .000 1500.00
137 CH2+H2<=>H+CH3 5.000E+05 2.000 7230.00
138 2CH2<=>H2+C2H2 1.600E+15 .000 11944.00
139 CH2+CH3<=>H+C2H4 4.000E+13 .000 .00
140 CH2+CH4<=>2CH3 2.460E+06 2.000 8270.00
141 CH2+HCCO<=>C2H3+CO 3.000E+13 .000 .00
142 CH2(S)+N2<=>CH2+N2 1.500E+13 .000 600.00
143 CH2(S)+AR<=>CH2+AR 9.000E+12 .000 600.00
144 CH2(S)+O2<=>H+OH+CO 2.800E+13 .000 .00
145 CH2(S)+O2<=>CO+H2O 1.200E+13 .000 .00
146 CH2(S)+H2<=>CH3+H 7.000E+13 .000 .00
147 CH2(S)+H2O<=>CH2+H2O 3.000E+13 .000 .00
148 CH2(S)+CH3<=>H+C2H4 1.200E+13 .000 -570.00
149 CH2(S)+CH4<=>2CH3 1.600E+13 .000 -570.00
150 CH2(S)+CO<=>CH2+CO 9.000E+12 .000 .00
151 CH2(S)+CO2<=>CH2+CO2 7.000E+12 .000 .00
152 CH2(S)+CO2<=>CO+CH2O 1.400E+13 .000 .00
153 CH2(S)+C2H6<=>CH3+C2H5 4.000E+13 .000 -550.00
154 CH3+O2<=>O+CH3O 3.560E+13 .000 30480.00
155 CH3+O2<=>OH+CH2O 2.310E+12 .000 20315.00
156 CH3+H2O2<=>HO2+CH4 2.450E+04 2.470 5180.00
157 2CH3<=>H+C2H5 6.840E+12 .100 10600.00
158 CH3+HCO<=>CH4+CO 2.648E+13 .000 .00
159 CH3+CH2O<=>HCO+CH4 3.320E+03 2.810 5860.00
160 CH3+CH3OH<=>CH2OH+CH4 3.000E+07 1.500 9940.00
161 CH3+CH3OH<=>CH3O+CH4 1.000E+07 1.500 9940.00
162 CH3+C2H4<=>C2H3+CH4 2.270E+05 2.000 9200.00
163 CH3+C2H6<=>C2H5+CH4 6.140E+06 1.740 10450.00
164 HCO+H2O<=>H+CO+H2O 1.500E+18 -1.000 17000.00
165 HCO+O2<=>HO2+CO 13.45E+12 .000 400.00
166 CH2OH+O2<=>HO2+CH2O 1.800E+13 .000 900.00
167 CH3O+O2<=>HO2+CH2O 4.280E-13 7.600 -3530.00
168 C2H+O2<=>HCO+CO 1.000E+13 .000 -755.00
169 C2H+H2<=>H+C2H2 5.680E+10 0.900 1993.00
170 C2H3+O2<=>HCO+CH2O 4.580E+16 -1.390 1015.00
171 C2H5+O2<=>HO2+C2H4 8.400E+11 .000 3875.00
172 HCCO+O2<=>OH+2CO 3.200E+12 .000 854.00
173 2HCCO<=>2CO+C2H2 1.000E+13 .000 .00
174 N+NO<=>N2+O 2.700E+13 .000 355.00
175 N+O2<=>NO+O 9.000E+09 1.000 6500.00
176 N+OH<=>NO+H 3.360E+13 .000 385.00
177 N2O+O<=>N2+O2 1.400E+12 .000 10810.00
178 N2O+O<=>2NO 2.900E+13 .000 23150.00
179 N2O+H<=>N2+OH 3.870E+14 .000 18880.00
180 N2O+OH<=>N2+HO2 2.000E+12 .000 21060.00
181 HO2+NO<=>NO2+OH 2.110E+12 .000 -480.00
182 NO2+O<=>NO+O2 3.900E+12 .000 -240.00
183 NO2+H<=>NO+OH 1.320E+14 .000 360.00
184 NH+O<=>NO+H 4.000E+13 .000 .00
185 NH+H<=>N+H2 3.200E+13 .000 330.00
186 NH+OH<=>HNO+H 2.000E+13 .000 .00
187 NH+OH<=>N+H2O 2.000E+09 1.200 .00
188 NH+O2<=>HNO+O 4.610E+05 2.000 6500.00
189 NH+O2<=>NO+OH 1.280E+06 1.500 100.00
190 NH+N<=>N2+H 1.500E+13 .000 .00
191 NH+H2O<=>HNO+H2 2.000E+13 .000 13850.00
192 NH+NO<=>N2+OH 2.160E+13 -.230 .00
193 NH+NO<=>N2O+H 3.650E+14 -.450 .00
194 NH2+O<=>OH+NH 3.000E+12 .000 .00
195 NH2+O<=>H+HNO 3.900E+13 .000 .00
196 NH2+H<=>NH+H2 4.000E+13 .000 3650.00
197 NH2+OH<=>NH+H2O 9.000E+07 1.500 -460.00
198 NNH<=>N2+H 3.300E+08 .000 .00
199 NNH+O2<=>HO2+N2 5.000E+12 .000 .00
200 NNH+O<=>OH+N2 2.500E+13 .000 .00
201 NNH+O<=>NH+NO 7.000E+13 .000 .00
202 NNH+H<=>H2+N2 5.000E+13 .000 .00
203 NNH+OH<=>H2O+N2 2.000E+13 .000 .00
204 NNH+CH3<=>CH4+N2 2.500E+13 .000 .00
205 HNO+O<=>NO+OH 2.500E+13 .000 .00
206 HNO+H<=>H2+NO 9.000E+11 .720 660.00
207 HNO+OH<=>NO+H2O 1.300E+07 1.900 -950.00
208 HNO+O2<=>HO2+NO 1.000E+13 .000 13000.00
209 CN+O<=>CO+N 7.700E+13 .000 .00
210 CN+OH<=>NCO+H 4.000E+13 .000 .00
211 CN+H2O<=>HCN+OH 8.000E+12 .000 7460.00
212 CN+O2<=>NCO+O 6.140E+12 .000 -440.00
213 CN+H2<=>HCN+H 2.950E+05 2.450 2240.00
214 NCO+O<=>NO+CO 2.350E+13 .000 .00
215 NCO+H<=>NH+CO 5.400E+13 .000 .00
216 NCO+OH<=>NO+H+CO 0.250E+13 .000 .00
217 NCO+N<=>N2+CO 2.000E+13 .000 .00
218 NCO+O2<=>NO+CO2 2.000E+12 .000 20000.00
219 NCO+NO<=>N2O+CO 1.900E+17 -1.520 740.00
220 NCO+NO<=>N2+CO2 3.800E+18 -2.000 800.00
221 HCN+O<=>NCO+H 2.030E+04 2.640 4980.00
222 HCN+O<=>NH+CO 5.070E+03 2.640 4980.00
223 HCN+O<=>CN+OH 3.910E+09 1.580 26600.00
224 HCN+OH<=>HOCN+H 1.100E+06 2.030 13370.00
225 HCN+OH<=>HNCO+H 4.400E+03 2.260 6400.00
226 HCN+OH<=>NH2+CO 1.600E+02 2.560 9000.00
227 H2CN+N<=>N2+CH2 6.000E+13 .000 400.00
228 C+N2<=>CN+N 6.300E+13 .000 46020.00
229 CH+N2<=>HCN+N 3.120E+09 0.880 20130.00
230 CH2+N2<=>HCN+NH 1.000E+13 .000 74000.00
231 CH2(S)+N2<=>NH+HCN 1.000E+11 .000 65000.00
232 C+NO<=>CN+O 1.900E+13 .000 .00
233 C+NO<=>CO+N 2.900E+13 .000 .00
234 CH+NO<=>HCN+O 4.100E+13 .000 .00
235 CH+NO<=>H+NCO 1.620E+13 .000 .00
236 CH+NO<=>N+HCO 2.460E+13 .000 .00
237 CH2+NO<=>H+HNCO 3.100E+17 -1.380 1270.00
238 CH2+NO<=>OH+HCN 2.900E+14 -.690 760.00
239 CH2+NO<=>H+HCNO 3.800E+13 -.360 580.00
240 CH2(S)+NO<=>H+HNCO 3.100E+17 -1.380 1270.00
241 CH2(S)+NO<=>OH+HCN 2.900E+14 -.690 760.00
242 CH2(S)+NO<=>H+HCNO 3.800E+13 -.360 580.00
243 CH3+NO<=>HCN+H2O 9.600E+13 .000 28800.00
244 CH3+NO<=>H2CN+OH 1.000E+12 .000 21750.00
245 HCNN+O<=>CO+H+N2 2.200E+13 .000 .00
246 HCNN+O<=>HCN+NO 2.000E+12 .000 .00
247 HCNN+O2<=>O+HCO+N2 1.200E+13 .000 .00
248 HCNN+OH<=>H+HCO+N2 1.200E+13 .000 .00
249 HCNN+H<=>CH2+N2 1.000E+14 .000 .00
250 HNCO+O<=>NH+CO2 9.800E+07 1.410 8500.00
251 HNCO+O<=>HNO+CO 1.500E+08 1.570 44000.00
252 HNCO+O<=>NCO+OH 2.200E+06 2.110 11400.00
253 HNCO+H<=>NH2+CO 2.250E+07 1.700 3800.00
254 HNCO+H<=>H2+NCO 1.050E+05 2.500 13300.00
255 HNCO+OH<=>NCO+H2O 3.300E+07 1.500 3600.00
256 HNCO+OH<=>NH2+CO2 3.300E+06 1.500 3600.00
257 HCNO+H<=>H+HNCO 2.100E+15 -.690 2850.00
258 HCNO+H<=>OH+HCN 2.700E+11 .180 2120.00
259 HCNO+H<=>NH2+CO 1.700E+14 -.750 2890.00
260 HOCN+H<=>H+HNCO 2.000E+07 2.000 2000.00
261 HCCO+NO<=>HCNO+CO 0.900E+13 .000 .00
262 CH3+N<=>H2CN+H 6.100E+14 -.310 290.00
263 CH3+N<=>HCN+H2 3.700E+12 .150 -90.00
264 NH3+H<=>NH2+H2 5.400E+05 2.400 9915.00
265 NH3+OH<=>NH2+H2O 5.000E+07 1.600 955.00
266 NH3+O<=>NH2+OH 9.400E+06 1.940 6460.00
267 NH+CO2<=>HNO+CO 1.000E+13 .000 14350.00
268 CN+NO2<=>NCO+NO 6.160E+15 -0.752 345.00
269 NCO+NO2<=>N2O+CO2 3.250E+12 .000 -705.00
270 N+CO2<=>NO+CO 3.000E+12 .000 11300.00
271 O+CH3=>H+H2+CO 3.370E+13 .000 .00
272 O+C2H4<=>H+CH2CHO 6.700E+06 1.830 220.00
273 O+C2H5<=>H+CH3CHO 1.096E+14 .000 .00
274 OH+HO2<=>O2+H2O 0.500E+16 .000 17330.00
275 DUPLICATE
276 OH+CH3=>H2+CH2O 8.000E+09 .500 -1755.00
277 CH2+O2=>2H+CO2 5.800E+12 .000 1500.00
278 CH2+O2<=>O+CH2O 2.400E+12 .000 1500.00
279 CH2+CH2=>2H+C2H2 2.000E+14 .000 10989.00
280 CH2(S)+H2O=>H2+CH2O 6.820E+10 .250 -935.00
281 C2H3+O2<=>O+CH2CHO 3.030E+11 .290 11.00
282 C2H3+O2<=>HO2+C2H2 1.337E+06 1.610 -384.00
283 O+CH3CHO<=>OH+CH2CHO 2.920E+12 .000 1808.00
284 O+CH3CHO=>OH+CH3+CO 2.920E+12 .000 1808.00
285 O2+CH3CHO=>HO2+CH3+CO 3.010E+13 .000 39150.00
286 H+CH3CHO<=>CH2CHO+H2 2.050E+09 1.160 2405.00
287 H+CH3CHO=>CH3+H2+CO 2.050E+09 1.160 2405.00
288 OH+CH3CHO=>CH3+H2O+CO 2.343E+10 0.730 -1113.00
289 HO2+CH3CHO=>CH3+H2O2+CO 3.010E+12 .000 11923.00
290 CH3+CH3CHO=>CH3+CH4+CO 2.720E+06 1.770 5920.00
291 O+CH2CHO=>H+CH2+CO2 1.500E+14 .000 .00
292 O2+CH2CHO=>OH+CO+CH2O 1.810E+10 .000 .00
293 O2+CH2CHO=>OH+2HCO 2.350E+10 .000 .00
294 H+CH2CHO<=>CH3+HCO 2.200E+13 .000 .00
295 H+CH2CHO<=>CH2CO+H2 1.100E+13 .000 .00
296 OH+CH2CHO<=>H2O+CH2CO 1.200E+13 .000 .00
297 OH+CH2CHO<=>HCO+CH2OH 3.010E+13 .000 .00
298 O+C3H8<=>OH+C3H7 1.930E+05 2.680 3716.00
299 H+C3H8<=>C3H7+H2 1.320E+06 2.540 6756.00
300 OH+C3H8<=>C3H7+H2O 3.160E+07 1.800 934.00
301 C3H7+H2O2<=>HO2+C3H8 3.780E+02 2.720 1500.00
302 CH3+C3H8<=>C3H7+CH4 0.903E+00 3.650 7154.00
303 O+C3H7<=>C2H5+CH2O 9.640E+13 .000 .00
304 H+C3H7<=>CH3+C2H5 4.060E+06 2.190 890.00
305 OH+C3H7<=>C2H5+CH2OH 2.410E+13 .000 .00
306 HO2+C3H7<=>O2+C3H8 2.550E+10 0.255 -943.00
307 HO2+C3H7=>OH+C2H5+CH2O 2.410E+13 .000 .00
308 CH3+C3H7<=>2C2H5 1.927E+13 -0.320 .00
309 !
310 ! + M Reactions
311 !
312 2O+M<=>O2+M 1.200E+17 -1.000 .00
313 H2/2.40/ H2O/15.40/ CH4/ 2.00/ CO/ 1.75/ CO2/3.60/ C2H6/ 3.00/ AR/0.83/
314 O+H+M<=>OH+M 5.000E+17 -1.000 .00
315 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/
316 H+O2+M<=>HO2+M 2.800E+18 -.860 .00
317 O2/0.00/ H2O/0.00/ CO/0.75/ CO2/1.50/ C2H6/1.50/ N2/0.00/ AR/0.00/
318 2H+M<=>H2+M 1.000E+18 -1.000 .00
319 H2/0.00/ H2O/0.00/ CH4/2.00/ CO2/0.00/ C2H6/3.00/ AR/0.63/
320 ! 37
321 H+OH+M<=>H2O+M 2.200E+22 -2.000 .00
322 H2/0.73/ H2O/3.65/ CH4/2.00/ C2H6/3.00/ AR/0.38/
323 ! 36
324 HCO+M<=>H+CO+M 1.870E+17 -1.000 17000.00
325 H2/2.00/ H2O/0.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/
326 ! 35
327 NO+O+M<=>NO2+M 1.060E+20 -1.410 .00
328 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/
329 ! 34
330 NNH+M<=>N2+H+M 1.300E+14 -.110 4980.00
331 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/
332 ! 33
333 H+NO+M<=>HNO+M 4.480E+19 -1.320 740.00
334 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/
335 ! 32
336 NCO+M<=>N+CO+M 3.100E+14 .000 54050.00
337 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/
338 ! 31
339 HCN+M<=>H+CN+M 1.040E+29 -3.300 126600.00
340 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/0.70/
341 ! 30
342 HNCO+M<=>NH+CO+M 1.180E+16 .000 84720.00
343 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
344 !
345 ! (+M)
346 !
347 ! 29
348 O+CO(+M)<=>CO2(+M) 1.800E+10 .000 2385.00
349 LOW/ 6.020E+14 .000 3000.00/
350 H2/2.00/ O2/6.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/3.50/ C2H6/3.00/ AR/ .50/
351 ! 28
352 H+CH2(+M)<=>CH3(+M) 6.000E+14 .000 .00
353 LOW / 1.040E+26 -2.760 1600.00/
354 TROE/ .5620 91.00 5836.00 8552.00/
355 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
356 ! 27
357 H+CH3(+M)<=>CH4(+M) 13.90E+15 -.534 536.00
358 LOW / 2.620E+33 -4.760 2440.00/
359 TROE/ .7830 74.00 2941.00 6964.00 /
360 H2/2.00/ H2O/6.00/ CH4/3.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
361 ! 26
362 H+HCO(+M)<=>CH2O(+M) 1.090E+12 .480 -260.00
363 LOW / 2.470E+24 -2.570 425.00/
364 TROE/ .7824 271.00 2755.00 6570.00 /
365 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
366 ! 25
367 H+CH2O(+M)<=>CH2OH(+M) 5.400E+11 .454 3600.00
368 LOW / 1.270E+32 -4.820 6530.00/
369 TROE/ .7187 103.00 1291.00 4160.00 /
370 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/
371 ! 24
372 H+CH2OH(+M)<=>CH3OH(+M) 1.055E+12 .500 86.00
373 LOW / 4.360E+31 -4.650 5080.00/
374 TROE/ .600 100.00 90000.0 10000.0 /
375 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/
376 ! 23
377 H+CH3O(+M)<=>CH3OH(+M) 2.430E+12 .515 50.00
378 LOW / 4.660E+41 -7.440 14080.0/
379 TROE/ .700 100.00 90000.0 10000.00 /
380 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/
381 ! 22
382 H+C2H(+M)<=>C2H2(+M) 1.000E+17 -1.000 .00
383 LOW / 3.750E+33 -4.800 1900.00/
384 TROE/ .6464 132.00 1315.00 5566.00 /
385 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
386 ! 21
387 H+C2H2(+M)<=>C2H3(+M) 5.600E+12 .000 2400.00
388 LOW / 3.800E+40 -7.270 7220.00/
389 TROE/ .7507 98.50 1302.00 4167.00 /
390 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
391 ! 20
392 H+C2H3(+M)<=>C2H4(+M) 6.080E+12 .270 280.00
393 LOW / 1.400E+30 -3.860 3320.00/
394 TROE/ .7820 207.50 2663.00 6095.00 /
395 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
396 ! 19
397 H+C2H4(+M)<=>C2H5(+M) 0.540E+12 .454 1820.00
398 LOW / 0.600E+42 -7.620 6970.00/
399 TROE/ .9753 210.00 984.00 4374.00 /
400 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
401 ! 18
402 H+C2H5(+M)<=>C2H6(+M) 5.210E+17 -.990 1580.00
403 LOW / 1.990E+41 -7.080 6685.00/
404 TROE/ .8422 125.00 2219.00 6882.00 /
405 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
406 ! 17
407 H2+CO(+M)<=>CH2O(+M) 4.300E+07 1.500 79600.00
408 LOW / 5.070E+27 -3.420 84350.00/
409 TROE/ .9320 197.00 1540.00 10300.00 /
410 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
411 ! 16
412 2OH(+M)<=>H2O2(+M) 7.400E+13 -.370 .00
413 LOW / 2.300E+18 -.900 -1700.00/
414 TROE/ .7346 94.00 1756.00 5182.00 /
415 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
416 ! 15
417 OH+CH3(+M)<=>CH3OH(+M) 2.790E+18 -1.430 1330.00
418 LOW / 4.000E+36 -5.920 3140.00/
419 TROE/ .4120 195.0 5900.00 6394.00/
420 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/
421 ! 14
422 CH+CO(+M)<=>HCCO(+M) 5.000E+13 .000 .00
423 LOW / 2.690E+28 -3.740 1936.00/
424 TROE/ .5757 237.00 1652.00 5069.00 /
425 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
426 ! 13
427 CH2+CO(+M)<=>CH2CO(+M) 8.100E+11 .500 4510.00
428 LOW / 2.690E+33 -5.110 7095.00/
429 TROE/ .5907 275.00 1226.00 5185.00 /
430 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
431 ! 12
432 CH2(S)+H2O(+M)<=>CH3OH(+M) 4.820E+17 -1.160 1145.00
433 LOW / 1.880E+38 -6.360 5040.00/
434 TROE/ .6027 208.00 3922.00 10180.0 /
435 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/
436 ! 11
437 2CH3(+M)<=>C2H6(+M) 6.770E+16 -1.180 654.00
438 LOW / 3.400E+41 -7.030 2762.00/
439 TROE/ .6190 73.20 1180.00 9999.00 /
440 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
441 ! 10
442 C2H4(+M)<=>H2+C2H2(+M) 8.000E+12 .440 86770.00
443 LOW / 1.580E+51 -9.300 97800.00/
444 TROE/ .7345 180.00 1035.00 5417.00 /
445 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
446 ! 9
447 N2O(+M)<=>N2+O(+M) 7.910E+10 .000 56020.00
448 LOW / 6.370E+14 .000 56640.00/
449 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .625/
450 ! 8
451 H+HCN(+M)<=>H2CN(+M) 3.300E+13 .000 .00
452 LOW / 1.400E+26 -3.400 1900.00/
453 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
454 ! 7
455 CH+N2(+M)<=>HCNN(+M) 3.100E+12 .150 .00
456 LOW / 1.300E+25 -3.160 740.00/
457 TROE/ .6670 235.00 2117.00 4536.00 /
458 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ 1.0/
459 ! 6
460 CH+H2(+M)<=>CH3(+M) 1.970E+12 .430 -370.00
461 LOW/ 4.820E+25 -2.80 590.0 /
462 TROE/ .578 122.0 2535.0 9365.0 /
463 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
464 ! 5
465 H+CH2CO(+M)<=>CH2CHO(+M) 4.865E+11 0.422 -1755.00
466 LOW/ 1.012E+42 -7.63 3854.0/
467 TROE/ 0.465 201.0 1773.0 5333.0 /
468 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
469 ! 4
470 CH3+C2H5(+M)<=>C3H8(+M) .9430E+13 .000 .00
471 LOW/ 2.710E+74 -16.82 13065.0 /
472 TROE/ .1527 291.0 2742.0 7748.0 /
473 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
474 ! 3
475 CH3+C2H4(+M)<=>C3H7(+M) 2.550E+06 1.600 5700.00
476 LOW/ 3.00E+63 -14.6 18170./
477 TROE/ .1894 277.0 8748.0 7891.0 /
478 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
479 ! 2
480 H+C3H7(+M)<=>C3H8(+M) 3.613E+13 .000 .00
481 LOW/ 4.420E+61 -13.545 11357.0/
482 TROE/ .315 369.0 3285.0 6667.0 /
483 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/ AR/ .70/
484 ! 1
485 H+CH2O(+M)<=>CH3O(+M) 5.400E+11 .454 2600.00
486 LOW / 2.200E+30 -4.800 5560.00/
487 TROE/ .7580 94.00 1555.00 4200.00 /
488 H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/
489 END