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1 #EQUATIONS { CB05 MADE/SORG Extension, Implemented by NCSU, Sep 2014}
2 //*********************************************************************
3 //The former rate constant corresponds that for the following reaction in original version of CB05 in CMAQ:
4 //< R34> HO2 + HO2 = H2O2. But CMAQ uses an older rate constant of (EP3(2.3D-13, 600.0, 1.7D-33, 1000.0, TEMP, C_M).
5 //An updated rate constant of (EP3(2.3D-13, 600.0, 1.7D-33, 1000.0, TEMP, C_M) * ARR2(1.4D-21, 2200.0_dp, TEMP) comes from
6 //Jacobson's book (2005), Table B.4, reaction 33: HO2 + HO2 = H2O2 + O2.
7 //
8 //Additions of Cl equations from CMAQ's CB05 with Cl extension, and also Hg reactions added
9 //*********************************************************************
10 < R1> NO2 + hv = NO + O : j(Pj_no2);
11 < R2> O {+ O2 + M} = O3 {+ M} : 0.21*C_M*C_M*ARR(6.0D-34, 0.0_dp, -2.4_dp, TEMP);
12 < R3> O3 + NO = NO2 {+ O2} : ARR2(3.0D-12, 1500.0_dp, TEMP);
13 < R4> O + NO2 = NO {+ O2} : ARR2(5.6D-12, -180.0_dp, TEMP);
14 < R5> O + NO2 {+ M} = NO3 {+ M} : TROE(2.5D-31, 1.8_dp, 2.2D-11, 0.7_dp, TEMP, C_M);
15 < R6> O + NO {+ M} = NO2 {+ M} : TROE(9.0D-32, 1.5_dp, 3.0D-11, 0.0_dp, TEMP, C_M);
16 < R7> NO2 + O3 = NO3 {+ O2} : ARR2(1.2D-13, 2450.0_dp, TEMP);
17 < R8> O3 + hv = O {+ O2} : j(Pj_o33p);
18 < R9> O3 + hv = O1D {+ O2} : j(Pj_o31d);
19 < R10> O1D + M = O + M : ARR2(2.1D-11, -102.0_dp, TEMP);
20 < R11> O1D + H2O = 2 OH : 2.2D-10;
21 < R12> O3 + OH = HO2 {+ O2} : ARR2(1.7D-12, 940.0_dp, TEMP);
22 < R13> O3 + HO2 = OH {+ 2 O2} : ARR2(1.0D-14, 490.0_dp, TEMP);
23 < R14> NO3 + hv = NO2 + O : j(Pj_no3o);
24 < R15> NO3 + hv = NO {+ O2} : j(Pj_no3o2);
25 < R16> NO3 + NO = 2 NO2 : ARR2(1.5D-11, -170.0_dp, TEMP);
26 < R17> NO3 + NO2 = NO + NO2 {+ O2} : ARR2(4.5D-14, 1260.0_dp, TEMP);
27 < R18> NO3 + NO2 {+ M} = N2O5 {+ M} : TROE(2.0D-30, 4.4_dp, 1.4D-12, 0.7_dp, TEMP, C_M);
28 < R19> N2O5 + H2O = 2 HNO3 : 2.5D-22;
29 < R20> N2O5 + H2O + H2O = 2 HNO3 : 1.8D-39;
30 < R21> N2O5 = NO3 + NO2 : FALL(1.0D-03, 11000.0_dp, -3.5_dp, 9.7D14, 11080.0_dp, 0.1_dp, 0.45_dp, TEMP, C_M);
31 < R22> NO + NO {+0.21M} = 2 NO2 : ARR2(3.3D-39, -530.0_dp, TEMP)*0.21*C_M;
32 < R23> NO + NO2 + H2O = 2 HONO : 5.0D-40;
33 < R24> NO + OH = HONO : TROE(7.0D-31, 2.6_dp, 3.6D-11, 0.1_dp, TEMP, C_M);
34 < R25> HONO + hv = NO + OH : j(Pj_hno2);
35 < R26> OH + HONO = NO2 {+ H2O} : ARR2(1.8D-11, 390.0_dp, TEMP);
36 < R27> HONO + HONO = NO + NO2 : 1.0D-20;
37 < R28> NO2 + OH = HNO3 : TROE(2.0D-30, 3.0_dp, 2.5D-11, 0.0_dp, TEMP, C_M);
38 < R29> OH + HNO3 = NO3 : EP2(2.4D-14, -460.0_dp, 2.7D-17, -2199.0_dp, 6.5D-34, -1335.0_dp, TEMP, C_M);
39 < R30> HO2 + NO = OH + NO2 : ARR2(3.5D-12, -250.0_dp, TEMP);
40 < R31> HO2 + NO2 = PNA : TROE(1.8D-31, 3.2_dp, 4.7D-12, 0.0_dp, TEMP, C_M);
41 < R32> PNA = HO2 + NO2 : FALL(4.1D-05, 10650.0_dp, 0.0_dp, 4.8D15, 11170.0_dp, 0.0_dp, 0.6_dp, TEMP, C_M);
42 < R33> OH + PNA = NO2 : ARR2(1.3D-12, -380.0_dp, TEMP);
43 < R34> HO2 + HO2 = H2O2 : EP3(2.3D-13, -600.0_dp, 1.7D-33, -1000.0_dp, TEMP, C_M);
44 < R35> HO2 + HO2 + H2O = H2O2 : EP3(3.22D-34, -2800.0_dp, 2.38D-54, -3200.0_dp, TEMP, C_M);
45 < R36> H2O2 + hv = 2 OH : j(Pj_h2o2);
46 < R37> OH + H2O2 = HO2 {+ H2O} : ARR2(2.9D-12, 160.0_dp, TEMP);
47 < R38> O1D + H2 = OH + HO2 : 1.1D-10;
48 < R39> OH + H2 = HO2 : ARR2(5.5D-12, 2000.0_dp, TEMP);
49 < R40> OH + O = HO2 : ARR2(2.2D-11, -120.0_dp, TEMP);
50 < R41> OH + OH = O : ARR2(4.2D-12, 240.0_dp, TEMP);
51 < R42> OH + OH = H2O2 : TROE(6.9D-31, 1.0_dp, 2.6D-11, 0.0_dp, TEMP, C_M);
52 < R43> OH + HO2 = H2O {+ O2} : ARR2(4.8D-11, -250.0_dp, TEMP);
53 < R44> HO2 + O = OH {+ O2} : ARR2(3.0D-11, -200.0_dp, TEMP);
54 < R45> H2O2 + O = OH + HO2 : ARR2(1.4D-12, 2000.0_dp, TEMP);
55 < R46> NO3 + O = NO2 {+ O2} : 1.0D-11;
56 < R47> NO3 + OH = HO2 + NO2 : 2.2D-11;
57 < R48> NO3 + HO2 = HNO3 {+ O2} : 3.5D-12;
58 < R49> NO3 + O3 = NO2 {+ 2 O2} : 1.0D-17;
59 < R50> NO3 + NO3 = 2 NO2 {+ O2} : ARR2(8.5D-13, 2450.0_dp, TEMP);
60 < R51> PNA + hv = 0.61 HO2 + 0.61 NO2
61 + 0.39 OH + 0.39 NO3 : j(Pj_hno4);
62 < R52> HNO3 + hv = OH + NO2 : j(Pj_hno3);
63 < R53> N2O5 + hv = NO2 + NO3 : j(Pj_n2o5);
64 < R54> XO2 + NO = NO2 {+ XO} : ARR2(2.6D-12, -365.0_dp, TEMP);
65 < R55> XO2N + NO = NTR : ARR2(2.6D-12, -365.0_dp, TEMP);
66 < R56> XO2 + HO2 = ROOH : ARR2(7.5D-13, -700.0_dp, TEMP);
67 < R57> XO2N + HO2 = ROOH : ARR2(7.5D-13, -700.0_dp, TEMP);
68 < R58> XO2 + XO2 = 0.21 M : 6.8D-14;
69 < R59> XO2N + XO2N = 0.21 M : 6.8D-14;
70 < R60> XO2 + XO2N = 0.21 M : 6.8D-14;
71 < R61> NTR + OH = HNO3 + HO2
72 + 0.33 FORM + 0.33 ALD2
73 + 0.33 ALDX - 0.66 PAR : ARR2(5.9D-13, 360.0_dp, TEMP);
74 < R62> NTR + hv = NO2 + HO2
75 + 0.33 FORM + 0.33 ALD2
76 + 0.33 ALDX - 0.66 PAR : 1.0D-4*j(Pj_no2);
77 < R63> ROOH + OH = XO2 + 0.50 ALD2
78 + 0.50 ALDX : ARR2(3.01D-12, -190.0_dp, TEMP);
79 < R64> ROOH + hv = OH + HO2
80 + 0.50 ALD2 + 0.50 ALDX : 0.7 *j(Pj_h2o2);
81 < R65> OH + CO = HO2 : EP3(1.44D-13, 0.0_dp, 3.43D-33, 0.0_dp, TEMP, C_M);
82 < R66> OH + CH4 = MEO2 : ARR2(2.45D-12, 1775.0_dp, TEMP);
83 < R67> MEO2 + NO = FORM + HO2 + NO2 : ARR2(2.8D-12, -300.0_dp, TEMP);
84 < R68> MEO2 + HO2 = MEPX : ARR2(4.1D-13, -750.0_dp, TEMP);
85 < R69> MEO2 + MEO2 = 1.37 FORM + 0.74 HO2
86 + 0.63 MEOH : ARR2(9.5D-14, -390.0_dp, TEMP);
87 < R70> MEPX + OH = 0.70 MEO2 + 0.30 XO2
88 + 0.30 HO2 : ARR2(3.8D-12, -200.0_dp, TEMP);
89 < R71> MEPX + hv = FORM + HO2 + OH : 0.7 *j(Pj_h2o2);
90 < R72> MEOH + OH = FORM + HO2 : ARR2(7.3D-12, 620.0_dp, TEMP);
91 < R73> FORM + OH = HO2 + CO : 9.0D-12;
92 < R74> FORM + hv = 2.000 HO2 + CO : j(Pj_ch2or);
93 < R75> FORM + hv = CO : j(Pj_ch2om);
94 < R76> FORM + O = OH + HO2 + CO : ARR2(3.4D-11, 1600.0_dp, TEMP);
95 < R77> FORM + NO3 = HNO3 + HO2 + CO : 5.8D-16;
96 < R78> FORM + HO2 = HCO3 : ARR2(9.7D-15, -625.0_dp, TEMP);
97 < R79> HCO3 = FORM + HO2 : ARR2(2.4D+12, 7000.0_dp, TEMP);
98 < R80> HCO3 + NO = FACD + NO2 + HO2 : 5.6D-12;
99 < R81> HCO3 + HO2 = MEPX : ARR2(5.6D-15, -2300.0_dp, TEMP);
100 < R82> FACD + OH = HO2 : 4.0D-13;
101 < R83> ALD2 + O = C2O3 + OH : ARR2(1.8D-11, 1100.0_dp, TEMP);
102 < R84> ALD2 + OH = C2O3 : ARR2(5.6D-12, -270.0_dp, TEMP);
103 < R85> ALD2 + NO3 = C2O3 + HNO3 : ARR2(1.4D-12, 1900.0_dp, TEMP);
104 < R86> ALD2 + hv = MEO2 + CO + HO2 : 4.6D-4*j(Pj_no2);
105 < R87> C2O3 + NO = MEO2 + NO2 : ARR2(8.1D-12, -270.0_dp, TEMP);
106 < R88> C2O3 + NO2 = PAN : FALL(2.7D-28, 0.0_dp, -7.1_dp, 1.2D-11, 0.0_dp, -0.9_dp, 0.3_dp, TEMP, C_M);
107 < R89> PAN = C2O3 + NO2 : FALL(4.9D-03, 12100.0_dp, 0.0_dp, 5.4D16, 13830.0_dp, 0.0_dp, 0.3_dp, TEMP, C_M);
108 < R90> PAN + hv = C2O3 + NO2 : j(Pj_pan);
109 < R91> C2O3 + HO2 = 0.80 PACD + 0.20 AACD
110 + 0.20 O3 : ARR2(4.3D-13, -1040.0_dp, TEMP);
111 < R92> C2O3 + MEO2 = 0.90 MEO2 + 0.90 HO2
112 + FORM + 0.10 AACD : ARR2(2.0D-12, -500.0_dp, TEMP);
113 < R93> C2O3 + XO2 = 0.90 MEO2 + 0.10 AACD : ARR2(4.4D-13, -1070.0_dp, TEMP);
114 < R94> C2O3 + C2O3 = 2.00 MEO2 : ARR2(2.9D-12, -500.0_dp, TEMP);
115 < R95> PACD + OH = C2O3 : ARR2(4.0D-13, -200.0_dp, TEMP);
116 < R96> PACD + hv = MEO2 + OH : 0.0*0.7 *j(Pj_h2o2);
117 < R97> AACD + OH = MEO2 : ARR2(4.0D-13, -200.0_dp, TEMP);
118 < R98> ALDX + O = CXO3 + OH : ARR2(1.3D-11, 870.0_dp, TEMP);
119 < R99> ALDX + OH = CXO3 : ARR2(5.1D-12, -405.0_dp, TEMP);
120 <R100> ALDX + NO3 = CXO3 + HNO3 : 6.5D-15;
121 <R101> ALDX + hv = MEO2 + CO + HO2 : j(Pj_ch3cho);
122 <R102> CXO3 + NO = ALD2 + NO2
123 + HO2 + XO2 : ARR2(6.7D-12, -340.0_dp, TEMP);
124 <R103> CXO3 + NO2 = PANX : FALL(2.7D-28, 0.0_dp, -7.1_dp, 1.2D-11, 0.0_dp, -0.9_dp, 0.3_dp, TEMP, C_M);
125 <R104> PANX = CXO3 + NO2 : FALL(4.9D-03, 12100.0_dp, 0.0_dp, 5.4D16, 13830.0_dp, 0.0_dp, 0.3_dp, TEMP, C_M);
126 <R105> PANX + hv = CXO3 + NO2 : j(Pj_pan);
127 <R106> PANX + OH = ALD2 + NO2 : 3.0D-13;
128 <R107> CXO3 + HO2 = 0.80 PACD + 0.20 AACD
129 + 0.20 O3 : ARR2(4.3D-13, -1040.0_dp, TEMP);
130 <R108> CXO3 + MEO2 = 0.90 ALD2 + 0.90 XO2
131 + HO2 + 0.10 AACD
132 + 0.10 FORM : ARR2(2.0D-12, -500.0_dp, TEMP);
133 <R109> CXO3 + XO2 = 0.90 ALD2 + 0.10 AACD : ARR2(4.4D-13, -1070.0_dp, TEMP);
134 <R110> CXO3 + CXO3 = 2.00 ALD2 + 2.00 XO2
135 + 2.00 HO2 : ARR2(2.9D-12, -500.0_dp, TEMP);
136 <R111> CXO3 + C2O3 = MEO2 + XO2
137 + HO2 + ALD2 : ARR2(2.9D-12, -500.0_dp, TEMP);
138 <R112> PAR + OH = 0.87 XO2 + 0.13 XO2N
139 + 0.11 HO2 + 0.06 ALD2
140 - 0.11 PAR + 0.76 ROR
141 + 0.05 ALDX : 8.1D-13;
142 <R113> ROR = 0.96 XO2 + 0.60 ALD2
143 + 0.94 HO2 - 2.10 PAR
144 + 0.04 XO2N + 0.02 ROR
145 + 0.50 ALDX : ARR2(1.0D15, 8000.0_dp, TEMP);
146 <R114> ROR = HO2 : 1.6E+03;
147 <R115> ROR + NO2 = NTR : 1.5D-11;
148 <R116> O + OLE = 0.20 ALD2 + 0.30 ALDX
149 + 0.30 HO2 + 0.20 XO2
150 + 0.20 CO + 0.20 FORM
151 + 0.01 XO2N + 0.20 PAR
152 + 0.10 OH : ARR2(1.0D-11, 280.0_dp, TEMP);
153 <R117> OH + OLE = 0.80 FORM + 0.33 ALD2
154 + 0.62 ALDX + 0.80 XO2
155 + 0.95 HO2 - 0.70 PAR : 3.2D-11;
156 <R118> O3 + OLE = 0.18 ALD2 + 0.74 FORM
157 + 0.32 ALDX + 0.22 XO2
158 + 0.10 OH + 0.33 CO
159 + 0.44 HO2 - 1.00 PAR : ARR2(6.5D-15, 1900.0_dp, TEMP);
160 <R119> NO3 + OLE = NO2 + FORM
161 + 0.91 XO2 + 0.09 XO2N
162 + 0.56 ALDX + 0.35 ALD2
163 - 1.00 PAR : ARR2(7.0D-13, 2160.0_dp, TEMP);
164 <R120> O + ETH = FORM + 1.70 HO2
165 + CO + 0.70 XO2
166 + 0.30 OH : ARR2(1.04D-11, 792.0_dp, TEMP);
167 <R121> OH + ETH = XO2 + 1.56 FORM
168 + 0.22 ALDX + HO2 : TROE(1.0D-28, 0.8_dp, 8.8D-12, 0.0_dp, TEMP, C_M);
169 <R122> O3 + ETH = FORM + 0.63 CO
170 + 0.13 HO2 + 0.13 OH
171 + 0.37 FACD : ARR2(1.2D-14, 2630.0_dp, TEMP);
172 <R123> NO3 + ETH = NO2 + XO2
173 + 2.0 FORM : ARR2(3.3D-12, 2880.0_dp, TEMP);
174 <R124> IOLE + O = 1.24 ALD2 + 0.66 ALDX
175 + 0.10 HO2 + 0.10 XO2
176 + 0.10 CO + 0.10 PAR : 2.3D-11;
177 <R125> IOLE + OH = 1.30 ALD2 + 0.70 ALDX
178 + HO2 + XO2 : ARR2(1.0D-11, -550.0_dp, TEMP);
179 <R126> IOLE + O3 = 0.65 ALD2 + 0.35 ALDX
180 + 0.25 FORM + 0.25 CO
181 + 0.50 O + 0.50 OH
182 + 0.50 HO2 : ARR2(8.4D-15, 1100.0_dp, TEMP);
183 <R127> IOLE + NO3 = 1.18 ALD2 + 0.64 ALDX
184 + HO2 + NO2 : ARR2(9.6D-13, 270.0_dp, TEMP);
185 <R128> TOL + OH = 0.44 HO2 + 0.08 XO2
186 + 0.36 CRES + 0.56 TO2
187 + 0.071 TOLAER1
188 + 0.138 TOLAER2 : ARR2(1.8D-12, -355.0_dp, TEMP);
189 <R129> TO2 + NO = 0.90 NO2 + 0.90 HO2
190 + 0.90 OPEN + 0.10 NTR : 8.1D-12;
191 <R130> TO2 = CRES + HO2 : 4.2;
192 <R131> OH + CRES = 0.40 CRO + 0.60 XO2
193 + 0.60 HO2 + 0.30 OPEN
194 + CSLAER : 4.1D-11;
195 <R132> CRES + NO3 = CRO + HNO3 + CSLAER : 2.2D-11;
196 <R133> CRO + NO2 = NTR : 1.4D-11;
197 <R134> CRO + HO2 = CRES : 5.5D-12;
198 <R135> OPEN + hv = C2O3 + HO2 + CO : 9.0 *j(Pj_ch2or);
199 <R136> OPEN + OH = XO2 + 2.0 CO
200 + 2.00 HO2 + C2O3 + FORM : 3.0D-11;
201 <R137> OPEN + O3 = 0.03 ALDX + 0.62 C2O3
202 + 0.70 FORM + 0.03 XO2
203 + 0.69 CO + 0.08 OH
204 + 0.76 HO2 + 0.20 MGLY : ARR2(5.4D-17, 500.0_dp, TEMP);
205 <R138> OH + XYL = 0.70 HO2 + 0.50 XO2
206 + 0.20 CRES + 0.80 MGLY
207 + 1.10 PAR + 0.30 TO2
208 + 0.038 XYLAER1
209 + 0.167 XYLAER2 : ARR2(1.7D-11, -116.0_dp, TEMP);
210 <R139> OH + MGLY = XO2 + C2O3 : 1.7D-11;
212 <R140> MGLY + hv = C2O3 + HO2 + CO : 9.64 *j(Pj_ch2or);
213 <R141> O + ISOP = 0.75 ISPD + 0.50 FORM
214 + 0.25 XO2 + 0.25 HO2
215 + 0.25 CXO3
216 + 0.232 ISOAER1
217 + 0.0228 ISOAER2 : 3.6D-11;
218 <R142> OH + ISOP = 0.912 ISPD + 0.629 FORM
219 + 0.991 XO2 + 0.912 HO2
220 + 0.088 XO2N
221 + 0.232 ISOAER1
222 + 0.0288 ISOAER2 : ARR2(2.54D-11, -407.6_dp, TEMP);
223 <R143> O3 + ISOP = 0.650 ISPD + 0.600 FORM
224 + 0.200 XO2 + 0.066 HO2
225 + 0.266 OH + 0.200 CXO3
226 + 0.150 ALDX + 0.350 PAR
227 + 0.066 CO
228 + 0.232 ISOAER1
229 + 0.0288 ISOAER2 : ARR2(7.86D-15, 1912.0_dp, TEMP);
230 <R144> NO3 + ISOP = 0.200 ISPD + 0.800 NTR
231 + XO2 + 0.800 HO2
232 + 0.200 NO2 + 0.800 ALDX
233 + 0.232 ISOAER1
234 + 0.0288 ISOAER2 : ARR2(3.03D-12, 448.0_dp, TEMP);
235 <R145> OH + ISPD = 1.565 PAR + 0.167 FORM
236 + 0.713 XO2 + 0.503 HO2
237 + 0.334 CO + 0.168 MGLY
238 + 0.252 ALD2 + 0.210 C2O3
239 + 0.250 CXO3 + 0.120 ALDX : 3.36D-11;
240 <R146> O3 + ISPD = 0.114 C2O3 + 0.150 FORM
241 + 0.850 MGLY + 0.154 HO2
242 + 0.268 OH + 0.064 XO2
243 + 0.020 ALD2 + 0.360 PAR
244 + 0.225 CO : 7.1D-18;
245 <R147> NO3 + ISPD = 0.357 ALDX + 0.282 FORM
246 + 1.282 PAR + 0.925 HO2
247 + 0.643 CO + 0.850 NTR
248 + 0.075 CXO3 + 0.075 XO2
249 + 0.150 HNO3 : 1.0D-15;
250 <R148> ISPD + hv = 0.333 CO + 0.067 ALD2
251 + 0.900 FORM + 0.832 PAR
252 + 1.033 HO2 + 0.700 XO2
253 + 0.967 C2O3 : 0.0036*0.025 *j(Pj_ch2om);
254 <R149> TERP + O = 0.150 OH + 5.12 PAR
255 + TERPAER : 3.6D-11;
256 <R150> TERP + OH = 0.750 HO2 + 1.250 XO2
257 + 0.250 XO2N + 0.280 FORM
258 + 1.66 PAR + 0.470 ALDX
259 + TERPAER : ARR2(1.5D-11, -449.0_dp, TEMP);
260 <R151> TERP + O3 = 0.570 OH + 0.070 HO2
261 + 0.760 XO2 + 0.180 XO2N
262 + 0.240 FORM + 0.001 CO
263 + 7.000 PAR + 0.210 ALDX
264 + 0.390 CXO3
265 + TERPAER : ARR2(1.2D-15, 821.0_dp, TEMP);
266 <R152> TERP + NO3 = 0.470 NO2 + 0.280 HO2
267 + 1.030 XO2 + 0.250 XO2N
268 + 0.470 ALDX + 0.530 NTR
269 + TERPAER : ARR2(3.7D-12, -175.0_dp, TEMP);
270 <R153> SO2 + OH = SULF + HO2 + SULAER : TROE(3.3D-31, 4.3_dp, 1.6D-12, 0.0_dp, TEMP, C_M);
271 <R154> OH + ETOH = HO2 + 0.900 ALD2
272 + 0.050 ALDX + 0.100 FORM
273 + 0.100 XO2 : ARR2(6.9D-12, 230.0_dp, TEMP);
274 <R155> OH + ETHA = 0.991 ALD2 + 0.991 XO2
275 + 0.009 XO2N + HO2 : ARR2(8.7D-12, 1070.0_dp, TEMP);
276 <R156> NO2 + ISOP = 0.200 ISPD + 0.800 NTR
277 + XO2 + 0.800 HO2
278 + 0.200 NO + 0.800 ALDX
279 + 2.400 PAR : 1.5D-19;
280 <R157> CL2 + hv = 2.000 CL : j(Pj_cl2);
281 <R158> HOCL + hv = OH + CL : j(Pj_hocl);
282 <R159> CL + O3 = CLO : ARR2(2.3D-11, 200.0_dp, TEMP);
283 <R160> CLO + CLO = 0.300 CL2 + 1.400 CL : 1.63D-14;
284 <R161> CLO + NO = CL + NO2 : ARR2(6.4D-12, -290.0_dp, TEMP);
285 <R162> CLO + HO2 = HOCL : ARR2(2.7D-12, -220.0_dp, TEMP);
286 <R163> OH + FMCL = CL + CO : 5.0D-13;
287 <R164> FMCL + hv = CL + CO + HO2 : j(Pj_fmcl);
288 <R165> CL + CH4 = HCL + MEO2 : ARR2(6.6D-12, 1240.0_dp, TEMP);
289 <R166> CL + PAR = HCL
290 + 0.870 XO2
291 + 0.130 XO2N
292 + 0.110 HO2
293 + 0.060 ALD2
294 - 0.110 PAR
295 + 0.760 ROR
296 + 0.050 ALDX : 5.0D-11;
297 <R167> CL + ETHA = HCL
298 + 0.991 ALD2
299 + 0.991 XO2
300 + 0.009 XO2N
301 + HO2 : ARR2(8.3D-11, 100.0_dp, TEMP);
302 <R168> CL + ETH = FMCL
303 + 2.000 XO2
304 + 1.000 HO2
305 + 1.000 FORM : 1.07D-10;
306 <R169> CL + OLE = FMCL
307 + 0.330 ALD2
308 + 0.670 ALDX
309 + 2.000 XO2
310 + 1.000 HO2
311 - 1.000 PAR : 2.5D-10;
312 <R170> CL + IOLE = 0.300 HCL
313 + 0.700 FMCL
314 + 0.450 ALD2
315 + 0.550 ALDX
316 + 0.300 OLE
317 + 0.300 PAR
318 + 1.700 XO2
319 + 1.000 HO2 : 3.5D-10;
320 <R171> CL + ISOP = 0.15 HCL
321 + 1.000 XO2
322 + 1.000 HO2
323 + 0.850 FMCL
324 + 1.000 ISPD : 4.3D-10;
325 <R172> CL + FORM = HCL
326 + 1.000 HO2
327 + 1.000 CO : ARR2(8.2D-11, 34.0_dp, TEMP);
328 <R173> CL + ALD2 = HCL
329 + 1.000 C2O3 : 7.9D-11;
330 <R174> CL + ALDX = HCL
331 + 1.000 CXO3 : 1.3D-10;
332 <R175> CL + MEOH = HCL
333 + 1.000 HO2
334 + 1.000 FORM : 5.5D-11;
335 <R176> CL + ETOH = HCL
336 + 1.000 HO2
337 + 1.000 ALD2 : ARR2(8.2D-11, -45.0_dp, TEMP);
338 <R177> HCL + OH = CL : ARR(6.58D-13, -58.0_dp, 1.16_dp, TEMP);
339 <R178> HG0 + O3 = HG2 : 3.0D-20;
340 <R179> HG0 + OH = HG2 : 8.7D-14;
341 <R180> HG0 + H2O2 = HG2 : 8.5D-19;
342 <R181> HUM + OH = HUMAER + OH : 2.93D-10;
343 <R182> LIM + OH = 0.239 LIMAER1
344 + 0.363 LIMAER2
345 + OH : 1.71D-10;
346 <R183> OCI + OH = 0.045 OCIAER1
347 + 0.149 OCIAER2
348 + OH : 2.52D-10;
349 <R184> APIN + OH = 0.038 APINAER1
350 + 0.326 APINAER2
351 + OH : 5.37D-11;
352 <R185> APIN + O3 = 0.125 APINAER3
353 + 0.102 APINAER4
354 + O3 : 8.66D-17;
355 <R186> BPIN + OH = 0.13 BPINAER1
356 + 0.0406 BPINAER2
357 + OH : 7.89D-11;
358 <R187> BPIN + O3 = 0.026 BPINAER3
359 + 0.485 BPINAER4
360 + O3 : 1.36D-17;
361 <R188> BPIN + NO3 = BPINAER5 + NO3 : 2.31D-12;
362 <R189> TER + OH = 0.091 TERAER1
363 + 0.367 TERAER2
364 + OH : 2.7D-10;
365 <R190> ALKH + OH = 1.173 ALKHAER1
366 + OH : 1.97D-11;
367 <R191> PAH + OH = 0.156 PAHAER1
368 + 0.777 PAHAER2
369 + OH : 7.7D-11;