updated top-level README and version_decl for V4.5 (#1847)
[WRF.git] / chem / KPP / mechanisms / cbm4 / cbm4.eqn
blob507b0cb4b60c43260588d0377613d4d97b9de020
1 #EQUATIONS {CBM4}
3 {01:J01} NO2+hv=NO+O                          :  j(pj_no2)  ;
4 {02:J02} O3+hv=O                              :  j(pj_o33p) ;
5 {03:J03} O3+hv=O1D_CB4                        :  j(pj_o31d) ;
6 {04:J04} NO3+hv=0.89 NO2+0.89 O+0.11 NO       :  j(pj_no3o)+j(pj_no3o2);
7 {05:J05} HONO+hv=HO+NO                        :  j(pj_hno2) ;
8 {06:J06} H2O2+hv=2 HO                         :  j(pj_h2o2) ; 
9 {07:J07} HCHO+hv{+2 O2}= 2 HO2+CO             :  j(pj_ch2or) ;
10 {08:J08} HCHO+hv=CO                           :  j(pj_ch2om) ;
11 {09:J09} ALD2+hv{+ 2 O2}=HCHO+XO2+CO+ 2 HO2   :  4.6D-4*j(pj_no2) ; 
12 {10:J10} OPEN+hv=C2O3+CO+HO2                  :  9.04_dp*j(pj_ch2or) ; 
13 {11:J11} MGLY+hv=C2O3+CO+HO2                  :  9.64_dp*j(pj_ch2or) ; 
14 {12:01} O{+O2+M}=O3                           :  ARR2(1.4D+3, 1175.0_dp,TEMP) ;
15 {13:02} O3+NO=NO2                             :  ARR2(1.8D-12, -1370.0_dp,TEMP) ;
16 {14:03} O+NO2=NO                              :  9.3D-12 ;
17 {15:04} O+NO2=NO3                             :  ARR2(1.6D-13, 687.0_dp,TEMP) ;
18 {16:05} O+NO=NO2                              :  ARR2(2.2D-13, 602.0_dp,TEMP) ;
19 {17:06} O3+NO2=NO3                            :  ARR2(1.2D-13, -2450.0_dp,TEMP) ;
20 {18:07} O1D_CB4=O                             :  ARR2(1.9D+8, 390.0_dp,TEMP)  ;
21 {19:08} O1D_CB4+H2O=2HO                       :  2.2D-10 ;
22 {20:09} O3+HO=HO2                             :  ARR2(1.6D-12, -940.0_dp,TEMP) ;
23 {21:10} O3+HO2=HO                             :  ARR2(1.4D-14, -580.0_dp,TEMP) ;
24 {22:11} NO3+NO=2 NO2                          :  ARR2(1.3D-11, 250.0_dp,TEMP) ;
25 {23:12} NO3+NO2=NO+NO2                        :  ARR2(2.5D-14, -1230.0_dp,TEMP) ;
26 {24:13} NO3+NO2=N2O5                          :  ARR2(5.3D-13, 256.0_dp,TEMP) ;
27 {25:14} N2O5+H2O=2 HNO3                       :  1.3D-21 ;
28 {26:15} N2O5=NO3+NO2                          :  ARR2(3.5D+14, -10897.0_dp,TEMP) ;
29 {27:16} 2 NO=2 NO2                            :  ARR2(1.8D-20, 530.0_dp,TEMP) ;
30 {28:17} NO+NO2+H2O=2 HONO                     :  4.4D-40 ;
31 {29:18} HO+NO=HONO                            :  ARR2(4.5D-13, 806.0_dp,TEMP) ;
32 {30:19} HO+HONO=NO2                           :  6.6D-12 ;
33 {31:20} 2 HONO=NO+NO2                         :  1.0D-20 ;
34 {32:21} HO+NO2=HNO3                           :  ARR2(1.0D-12, 713.0_dp,TEMP) ;
35 {33:22} HO+HNO3=NO3                           :  ARR2(5.1D-15, 1000.0_dp,TEMP) ;
36 {34:23} HO2+NO=HO+NO2                         :  ARR2(3.7D-12, 240.0_dp,TEMP) ;
37 {35:24} HO2+NO2=PNA                           :  ARR2(1.2D-13, 749.0_dp,TEMP) ;
38 {36:25} PNA=HO2+NO2                           :  ARR2(4.8D+13, -10121.0_dp,TEMP) ;
39 {37:26} HO+PNA=NO2                            :  ARR2(1.3D-12, 380.0_dp,TEMP) ;
40 {38:27} 2 HO2=H2O2                            :  ARR2(5.9D-14, 1150.0_dp,TEMP)  ;
41 {39:28} 2 HO2+H2O=H2O2                        :  ARR2(2.2D-38, 5800.0_dp,TEMP) ;
42 {40:29} HO+H2O2=HO2                           :  ARR2(3.1D-12, -187.0_dp,TEMP) ;
43 {41:30} HO+CO=HO2                             :  2.2D-13 ;
44 {42:31} HCHO+HO=HO2+CO                        :  1.0D-11 ;
45 {43:32} HCHO+O=HO+HO2+CO                      :  ARR2(3.0D-11, -1550.0_dp,TEMP) ;
46 {44:33} HCHO+NO3=HNO3+HO2+CO                  :  6.3D-16 ;
47 {45:34} ALD2+O=C2O3+HO                        :  ARR2(1.2D-11, -986.0_dp,TEMP) ;
48 {46:35} ALD2+HO=C2O3                          :  ARR2(7.0D-12, 250.0_dp,TEMP) ;
49 {47:36} ALD2+NO3=C2O3+HNO3                    :  2.5D-15  ;
50 {48:37} C2O3+NO=HCHO+XO2+HO2+NO2              :  ARR2(5.4D-12, 250.0_dp,TEMP) ;
51 {49:38} C2O3+NO2=PAN                          :  ARR2(8.0D-20, 5500.0_dp,TEMP) ;
52 {50:39} PAN=C2O3+NO2                          :  ARR2(9.4D+16, -14000.0_dp,TEMP) ;
53 {51:40} 2 C2O3=2 HCHO+2 XO2+2 HO2             :  2.0D-12  ;
54 {52:41} C2O3+HO2=0.79 HCHO+0.79 XO2
55                 +0.79 HO2+0.79 HO             :  6.5D-12 ;
56 {53:42} HO=HCHO+XO2+HO2                       :  ARR2(1.1D+2, -1710.0_dp,TEMP) ;
57 {54:43} PAR+HO=0.87 XO2+0.13 XO2N
58               +0.11 HO2+0.11 ALD2
59               +0.76 ROR-0.11 PAR              :  8.1D-13 ;
60 {55:44} ROR=1.1 ALD2+0.96 XO2
61            +0.94 HO2 +0.04 XO2N
62            +0.02 ROR-2.10 PAR                 :  ARR2(1.0D+15, -8000.0_dp,TEMP) ;
63 {56:45} ROR=HO2                               :  1.6D+03 ;
64 {57:46} ROR+NO2= PROD                         :  1.5D-11  ;
65 {58:47} O+OLE=0.63 ALD2+0.38 HO2
66              +0.28 XO2+0.3 CO
67              +0.2 HCHO+0.02 XO2N
68              +0.22 PAR+0.2 HO                 :  ARR2(1.2D-11, -324.0_dp,TEMP) ;
69 {59:48} HO+OLE=HCHO+ALD2+XO2+HO2-PAR          :  ARR2(5.2D-12, 504.0_dp,TEMP) ;
70 {60:49} O3+OLE=0.5 ALD2+0.74 HCHO
71               +0.33 CO+0.44 HO2
72               +0.22 XO2+0.1 HO-PAR            :  ARR2(1.4D-14, -2105.0_dp,TEMP)  ;
73 {61:50} NO3+OLE=0.91 XO2+HCHO
74                +ALD2+0.09 XO2N
75                +NO2-PAR                       :  7.7D-15 ;
76 {62:51} O+ETH=HCHO+0.7 XO2
77              +CO+1.7 HO2+0.3 HO               :  ARR2(1.0D-11, -792.0_dp,TEMP) ;
78 {63:52} HO+ETH=XO2+1.56 HCHO
79               +HO2+0.22 ALD2                  :  ARR2(2.0D-12, 411.0_dp,TEMP) ;
80 {64:53} O3+ETH=HCHO+0.42 CO+0.12 HO2          :  ARR2(1.3D-14, -2633.0_dp,TEMP) ;
81 {65:54} HO+TOL=0.08 XO2+0.36 CRES
82               +0.44 HO2+0.56 TO2              :  ARR2(2.1D-12, 322.0_dp,TEMP) ;
83 {66:55} TO2+NO=0.9 NO2+0.9 OPEN+0.9 HO2       :  8.1D-12 ;
84 {67:56} TO2=HO2+CRES                          :  4.20 ;
85 {68:57} HO+CRES=0.4 CRO+0.6 XO2
86                +0.6 HO2+0.3 OPEN              :  4.1D-11  ;
87 {69:58} NO3+CRES=CRO+HNO3                     :  2.2D-11 ;
88 {70:59} CRO+NO2=PROD                          :  1.4D-11 ;
89 {71:60} HO+XYL=0.7 HO2+0.5 XO2
90               +0.2 CRES+0.8 MGLY
91               +1.10 PAR+0.3 TO2               :  ARR2(1.7D-11, 116.0_dp,TEMP) ;
92 {72:61} HO+OPEN=XO2+C2O3+2 HO2+2 CO+HCHO      :  3.0D-11 ;
93 {73:62} O3+OPEN=0.03 ALD2+0.62 C2O3
94                +0.7 HCHO+0.03 XO2
95                +0.69 CO+0.08 HO
96                +0.76 HO2+0.2 MGLY             :  ARR2(5.4D-17, -500.0_dp,TEMP)  ;
97 {74:63} HO+MGLY=XO2+C2O3                      :  1.70D-11 ;
98 {75:64} O+ISOP=0.6 HO2+0.8 ALD2
99               +0.55 OLE+0.5 XO2
100               +0.5 CO+0.45 ETH
101               +0.9 PAR                        :  1.80D-11  ;
102 {76:65} HO+ISOP=HCHO+XO2
103                +0.67 HO2+0.4 MGLY
104                +0.2 C2O3+ETH
105                +0.2 ALD2+0.13 XO2N            :  9.6D-11  ;
106 {77:66} O3+ISOP=HCHO+0.4 ALD2
107                +0.55 ETH+0.2 MGLY
108                +0.06 CO+0.1 PAR
109                +0.44 HO2+0.1 HO               :  1.2D-17 ;
110 {78:67} NO3+ISOP=XO2N                         :  3.2D-13 ;
111 {79:68} XO2+NO=NO2                            :  8.1D-12 ;
112 {80:69} 2 XO2=PROD                            :  ARR2(1.7D-14, 1300.0_dp,TEMP) ;
113 {81:70} XO2N+NO=PROD                          :  6.8D-13 ;