| blob | de0752596a7e04e71bdb9a2cd0bcbd870ca9eeeb |
1 #EQUATIONS {CRIMECH, check troe,troee, RJPL, RALKE, k46, k47, k48, RO2}
2 {001:J01} O3+hv=O1D{+O2} : j(Pj_o31d) ;
3 {002:J02} O3+hv=O3P{+O2} : j(Pj_o33p) ;
4 {003:J03} H2O2+hv=OH+OH : j(Pj_h2o2) ;
5 {004:J04} NO2+hv=NO+O3P : j(Pj_no2) ;
6 {005:J05} NO3+hv=NO : j(Pj_no3o2) ;
7 {006:J06} NO3+hv=NO2+O3P : j(Pj_no3o) ;
8 {007:J07} HONO+hv=OH+NO : j(Pj_hno2) ;
9 {008:J08} HNO3+hv=OH+NO2 : j(Pj_hno3) ;
10 {009:J09} HCHO+hv=CO+HO2+HO2 : j(Pj_ch2or) ;
11 {010:J10} HCHO+hv=CO : j(Pj_ch2om) ;
12 {011:J11} CH3CHO+hv=CH3OO+HO2+CO : 4.6D-4 * j(Pj_no2) ;
13 {012:J12} C2H5CHO+hv=C2H5O2+CO+HO2 : 4.19*4.6D-4 * j(Pj_no2) ;
14 {013:J13} CH3COCH3+hv=CH3CO3+CH3OO : 7.8D-5 * j(Pj_no2) ;
15 {014:J14} MEK+hv=CH3CO3+C2H5O2 : 7.047*7.8D-5 * j(Pj_no2) ;
16 {015:J15} CARB14+hv=CH3CO3+RN10O2 : 4.74*7.047*7.8D-5 * j(Pj_no2) ;
17 {016:J16} CARB17+hv=RN8O2+RN10O2 : 1.33*7.047*7.8D-5 * j(Pj_no2) ;
18 {017:J17} CARB11A+hv=CH3CO3+C2H5O2 : 7.047*7.8D-5 * j(Pj_no2) ;
19 {018:J18} CARB7+hv=CH3CO3+HCHO+HO2 : 7.047*7.8D-5 * j(Pj_no2) ;
20 {019:J19} CARB10+hv=CH3CO3+CH3CHO+HO2 : 7.047*7.8D-5 * j(Pj_no2) ;
21 {020:J20} CARB13+hv=RN8O2+CH3CHO+HO2 : 3.00*7.047*7.8D-5 * j(Pj_no2) ;
22 {021:J21} CARB16+hv=RN8O2+C2H5CHO+HO2 : 3.35*7.047*7.8D-5 * j(Pj_no2) ;
23 {022:J22} HOCH2CHO+hv=HCHO+CO+HO2+HO2 : 9.64_dp*j(pj_ch2or) ;
24 {023:J23} UCARB10+hv=CH3CO3+HCHO+HO2 : 2.0*1.9997*4.6D-4 * j(Pj_no2) ;
25 {024:J24} CARB3+hv=CO+CO+HO2+HO2 : 9.64_dp*j(pj_ch2or) ;
26 {025:J25} CARB6+hv=CH3CO3+CO+HO2 : 32.6088*4.6D-4 * j(Pj_no2);
27 {026:J26} CARB9+hv=CH3CO3+CH3CO3 : 2.149*32.6088*4.6D-4 * j(Pj_no2);
28 {027:J27} CARB12+hv=CH3CO3+RN8O2 : 2.149*32.6088*4.6D-4 * j(Pj_no2);
29 {028:J28} CARB15+hv=RN8O2+RN8O2 : 2.149*32.6088*4.6D-4 * j(Pj_no2);
30 {029:J29} UCARB12+hv=CH3CO3+HOCH2CHO+CO+HO2 : 2.0*1.9997*4.6D-4 * j(Pj_no2) ;
31 {030:J30} NUCARB12+hv=NOA+CO+CO+HO2+HO2 : 1.9997*4.6D-4 * j(Pj_no2) ;
32 {031:J31} NOA+hv=CH3CO3+HCHO+NO2 : 1.155*4.6D-4 * j(Pj_no2) + 0.4933*4.6D-4 * j(Pj_no2) ;
33 {032:J32} UDCARB8+hv=C2H5O2+HO2 : 0.02*j(Pj_no2) ;
34 {033:J33} UDCARB11+hv=RN10O2+HO2 : 0.02*j(Pj_no2) ;
35 {034:J34} UDCARB14+hv=RN13O2+HO2 : 0.02*j(Pj_no2) ;
36 {035:J35} TNCARB26+hv=RTN26O2+HO2 : 9.64_dp*j(pj_ch2or) ;
37 {036:J36} TNCARB10+hv=CH3CO3+CH3CO3+CO : 0.5*2.149*32.6088*4.6D-4 * j(Pj_no2);
38 {037:J37} CH3NO3+hv=HCHO+HO2+NO2 : 1.0D-4 * j(Pj_no2) ;
39 {038:J38} C2H5NO3+hv=CH3CHO+HO2+NO2 : 2.3248*7.8D-5 * j(Pj_no2) ;
40 {039:J39} RN10NO3+hv=C2H5CHO+HO2+NO2 : 3.079*7.8D-5 * j(Pj_no2) ;
41 {040:J40} IC3H7NO3+hv=CH3COCH3+HO2+NO2 : 5.228*7.8D-5 * j(Pj_no2) ;
42 {041:J41} RN13NO3+hv= CH3CHO+C2H5O2+NO2 : 0.398*3.079*7.8D-5 * j(Pj_no2) ;
43 {042:J42} RN13NO3+hv= CARB11A+HO2+NO2 : 0.602*3.079*7.8D-5 * j(Pj_no2) ;
44 {043:J43} RN16NO3+hv=RN15O2+NO2 : 3.079*7.8D-5 * j(Pj_no2) ;
45 {044:J44} RN19NO3+hv=RN18O2+NO2 : 3.079*7.8D-5 * j(Pj_no2) ;
46 {045:J45} RA13NO3+hv=CARB3+UDCARB8+HO2+NO2 : 5.228*7.8D-5 * j(Pj_no2) ;
47 {046:J46} RA16NO3+hv=CARB3+UDCARB11+HO2+NO2 : 5.228*7.8D-5 * j(Pj_no2) ;
48 {047:J47} RA19NO3+hv=CARB6+UDCARB11+HO2+NO2 : 5.228*7.8D-5 * j(Pj_no2) ;
49 {048:J48} RTX24NO3+hv=TXCARB22+HO2+NO2 : 5.228*7.8D-5 * j(Pj_no2) ;
50 {049:J49} CH3OOH+hv=HCHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
51 {050:J50} C2H5OOH+hv=CH3CHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
52 {051:J51} RN10OOH+hv=C2H5CHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
53 {052:J52} IC3H7OOH+hv=CH3COCH3+HO2+OH : 0.7 * j(Pj_h2o2) ;
54 {053:J53} RN13OOH+hv= CH3CHO+C2H5O2+OH : 0.398*0.7 * j(Pj_h2o2) ;
55 {054:J54} RN13OOH+hv= CARB11A+HO2+OH : 0.602*0.7 * j(Pj_h2o2) ;
56 {055:J55} RN16OOH+hv=RN15AO2+OH : 0.7 * j(Pj_h2o2) ;
57 {056:J56} RN19OOH+hv=RN18AO2+OH : 0.7 * j(Pj_h2o2) ;
58 {057:J57} CH3CO3H+hv=CH3OO+OH : 0.7 * j(Pj_h2o2) ;
59 {058:J58} C2H5CO3H+hv=C2H5O2+OH : 0.7 * j(Pj_h2o2) ;
60 {059:J59} HOCH2CO3H+hv=HCHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
61 {060:J60} RN8OOH+hv=C2H5O2+OH : 0.7 * j(Pj_h2o2) ;
62 {061:J61} RN11OOH+hv=RN10O2+OH : 0.7 * j(Pj_h2o2) ;
63 {062:J62} RN14OOH+hv=RN13O2+OH : 0.7 * j(Pj_h2o2) ;
64 {063:J63} RN17OOH+hv=RN16O2+OH : 0.7 * j(Pj_h2o2) ;
65 {064:J64} RU14OOH+hv=UCARB12+HO2+OH : 0.252*0.7 * j(Pj_h2o2) ;
66 {065:J65} RU14OOH+hv=UCARB10+HCHO+HO2+OH : 0.748*0.7 * j(Pj_h2o2) ;
67 {066:J66} RU12OOH+hv=CARB6+HOCH2CHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
68 {067:J67} RU10OOH+hv=CH3CO3+HOCH2CHO+OH : 0.7 * j(Pj_h2o2) ;
69 {068:J68} NRU14OOH+hv=NUCARB12+HO2+OH : 0.7 * j(Pj_h2o2) ;
70 {069:J69} NRU12OOH+hv=NOA+CO+HO2+OH : 0.7 * j(Pj_h2o2) ;
71 {070:J70} HOC2H4OOH+hv=HCHO+HCHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
72 {071:J71} RN9OOH+hv=CH3CHO+HCHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
73 {072:J72} RN12OOH+hv=CH3CHO+CH3CHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
74 {073:J73} RN15OOH+hv=C2H5CHO+CH3CHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
75 {074:J74} RN18OOH+hv=C2H5CHO+C2H5CHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
76 {075:J75} NRN6OOH+hv=HCHO+HCHO+NO2+OH : 0.7 * j(Pj_h2o2) ;
77 {076:J76} NRN9OOH+hv=CH3CHO+HCHO+NO2+OH : 0.7 * j(Pj_h2o2) ;
78 {077:J77} NRN12OOH+hv=CH3CHO+CH3CHO+NO2+OH : 0.7 * j(Pj_h2o2) ;
79 {078:J78} RA13OOH+hv=CARB3+UDCARB8+HO2+OH : 0.7 * j(Pj_h2o2) ;
80 {079:J79} RA16OOH+hv=CARB3+UDCARB11+HO2+OH : 0.7 * j(Pj_h2o2) ;
81 {080:J80} RA19OOH+hv=CARB6+UDCARB11+HO2+OH : 0.7 * j(Pj_h2o2) ;
82 {081:J81} RTN28OOH+hv=TNCARB26+HO2+OH : 0.7 * j(Pj_h2o2) ;
83 {082:J82} NRTN28OOH+hv=TNCARB26+NO2+OH : 0.7 * j(Pj_h2o2) ;
84 {083:J83} RTN26OOH+hv=RTN25O2+OH : 0.7 * j(Pj_h2o2) ;
85 {084:J84} RTN25OOH+hv=RTN24O2+OH : 0.7 * j(Pj_h2o2) ;
86 {085:J85} RTN24OOH+hv=RTN23O2+OH : 0.7 * j(Pj_h2o2) ;
87 {086:J86} RTN23OOH+hv=CH3COCH3+RTN14O2+OH : 0.7 * j(Pj_h2o2) ;
88 {087:J87} RTN14OOH+hv=TNCARB10+HCHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
89 {088:J88} RTN10OOH+hv=RN8O2+CO+OH : 0.7 * j(Pj_h2o2) ;
90 {089:J89} RTX28OOH+hv=TXCARB24+HCHO+HO2+OH : 0.7 * j(Pj_h2o2) ;
91 {090:J90} RTX24OOH+hv=TXCARB22+HO2+OH : 0.7 * j(Pj_h2o2) ;
92 {091:J90} RTX22OOH+hv=CH3COCH3+RN13O2+OH : 0.7 * j(Pj_h2o2) ;
93 {092:J90} NRTX28OOH+hv=TXCARB24+HCHO+NO2+OH : 0.7 * j(Pj_h2o2) ;
94 {093:J90} UDCARB8+hv=ANHY+HO2+HO2 : 0.02*0.36*j(Pj_no2) ;
95 {094:J90} UDCARB11+hv=ANHY+HO2+CH3OO : 0.02*0.45*j(Pj_no2) ;
96 {095:J90} UDCARB14+hv=ANHY+HO2+C2H5O2 : 0.02*0.45*j(Pj_no2) ;
97 {096:001} O3P+M{+O2}=O3 : .20946e0*(C_M *6.00D-34*(TEMP/300)**(-2.6));
98 {097:002} CH3O2NO2=CH3OO+NO2 : RJPL(1.3D-30,4.0_dp,7.5D-12,2.0_dp,C_M,TEMP)/(1.3D-28*exp(11200._dp/TEMP));
99 {098:003} O3P+O3=M {2O2} : ARR2( 8.00D-12, 2060.0_dp, TEMP) ;
100 {099:004} O3P+NO=NO2 : TROE( 9.00D-32 , 1.5_dp , 3.00D-11 , 0.0_dp , TEMP, C_M) ;
101 {100:005} O3P+NO2=NO : ARR2( 5.50D-12, -188.0_dp, TEMP) ;
102 {101:006} O3P+NO2=NO3 : TROE( 9.00D-32 , 2.0_dp , 2.20D-11 , 0.0_dp , TEMP, C_M) ;
103 {102:007} O1D+M{=O2,N2} =O3P{+O2, N2} : .20946e0* ARR2( 3.20D-11, -70.0_dp, TEMP)+ .78084* ARR2( 1.80D-11, -110.0_dp, TEMP) ;
104 {103:008} NO+O3=NO2 : ARR2( 1.40D-12, 1310.0_dp, TEMP) ;
105 {104:009} NO2+O3=NO3 : ARR2( 1.40D-13, 2470.0_dp, TEMP) ;
106 {105:010} NO+NO+M{=O2}=NO2+NO2 : .20946e0* ARR2( 3.30D-39, -530.0_dp, TEMP) ;
107 {106:011} NO+NO3=NO2+NO2 : ARR2( 1.80D-11, -110.0_dp, TEMP) ;
108 {107:012} NO2+NO3=NO+NO2 : ARR2( 4.50D-14, 1260.0_dp, TEMP) ;
109 {108:013} NO2+NO3=N2O5 : TROE( 2.20D-30 , 3.9_dp , 1.50D-12 , 0.7_dp , TEMP, C_M) ;
110 {109:014} N2O5=NO3+NO2 : TROEE(3.70D26,11000.0_dp, 2.20D-30 , 3.9_dp , 1.50D-12 , 0.7_dp , TEMP, C_M ) ;
111 {110:015} O1D+H2O=OH+OH : 2.20D-10 ;
112 {111:016} OH+O3=HO2 : ARR2( 1.70D-12, 940.0_dp, TEMP) ;
113 {112:017} OH+M = HO2+H2O : 5.31D-7*ARR2( 7.70D-12, 2100.0_dp, TEMP) ;
114 {113:018} OH+CO=HO2 : 1.20D-13*(1.0 + ((0.6*C_M)/(2.652d+19*(273.0/temp)))) ;
115 {114:019} OH+H2O2=HO2 : ARR2( 2.90D-12, 160.0_dp, TEMP) ;
116 {115:020} HO2+O3=OH : 2.03D-16*((TEMP/300)**4.57)*EXP(693/TEMP) ;
117 {116:021} OH+HO2=H2O{+O2} : ARR2( 4.80D-11, -250.0_dp, TEMP) ;
118 {117:022} HO2+HO2=H2O2 : (2.2D-13*EXP(600./TEMP) + 1.9D-33* C_M *EXP(980._dp/TEMP)) ;
119 {118:023} HO2+HO2+H2O=H2O2 : (3.08D-34* EXP(2800._dp/TEMP)+ 2.66D-54* C_M *EXP(3180._dp/TEMP)) ;
120 {119:024} OH+NO=HONO : KMT_OH_NO( TEMP, C_M) ;
121 {120:025} OH+NO2=HNO3 : TROE( 2.60D-30 , 3.2_dp , 2.40D-11 , 1.3_dp , TEMP, C_M) ;
122 {121:026} OH+NO3=HO2+NO2 : 2.00D-11 ;
123 {122:027} HO2+NO=OH+NO2 : ARR2( 3.60D-12, -270.0_dp, TEMP) ;
124 {123:028} HO2+NO2=HNO4 : TROE( 1.80D-31 , 3.2_dp , 4.70D-12 , 1.4_dp , TEMP, C_M) ;
125 {124:029} HNO4=NO2+HO2 : TROEE( 4.76D26,10900.0_dp, 1.80D-31 , 3.2_dp , 4.70D-12 , 1.4_dp , TEMP, C_M ) ;
126 {125:030} OH+HNO4=NO2 : ARR2( 1.90D-12, -270.0_dp, TEMP) ;
127 {126:031} HO2+NO3=OH+NO2 : 4.00D-12 ;
128 {127:032} OH+HONO=NO2 : ARR2( 2.50D-12, -260.0_dp, TEMP) ;
129 {128:033} OH+HNO3=NO3 : k46(TEMP,C_M) ;
130 {129:034} O3P+SO2=SO3 : C_M*ARR2( 4.00D-32, 1000.0_dp, TEMP) ;
131 {130:035} OH+SO2=HSO3 : K47(TEMP,C_M) ;
132 {131:036} HSO3+M{=O2}=HO2+SO3 : .20946e0* ARR2( 1.30D-12, -330.0_dp, TEMP) ;
133 {134:039} SO3 + H2O + H2O = H2SO4 : ARR2(3.9d-41,-6830.6_dp,TEMP) ; {Jayne et al (1997) rate}
134 {135:040} OH+CH4=CH3OO : 9.65D-20*TEMP**2.58*EXP(-1082/TEMP) ;
135 {136:041} OH+C2H6=C2H5O2 : 1.52D-17*TEMP**2*EXP(-498/TEMP) ;
136 {137:042} OH+C3H8=IC3H7O2 : 1.55D-17*TEMP**2*EXP(-61/TEMP)*0.736 ;
137 {138:043} OH+C3H8=RN10O2 : 1.55D-17*TEMP**2*EXP(-61/TEMP)*0.264 ;
138 {139:044} OH+NC4H10=RN13O2 : 1.69D-17*TEMP**2*EXP(145/TEMP) ;
139 {140:045} OH+C2H4=HOCH2CH2O2 : KMT_IUPAC(8.6D-29, 3.1_dp, 9.0D-12, 0.85_dp, 0.48_dp, TEMP,C_M) ;
140 {141:046} OH+C3H6=RN9O2 : KMT_IUPAC(8.0D-27, 3.5_dp, 3.0D-11, 1.0_dp, 0.5_dp, TEMP,C_M) ;
141 {142:047} OH+TBUT2ENE=RN12O2 : ARR2( 1.01D-11, -550.0_dp, TEMP) ;
142 {143:048} NO3+C2H4=NRN6O2 : 2.10D-16 ;
143 {144:049} NO3+C3H6=NRN9O2 : 9.40D-15 ;
144 {145:050} NO3+TBUT2ENE=NRN12O2 : 3.90D-13 ;
145 {146:051} O3+C2H4=HCHO+CO+HO2+OH : 0.13*ARR2( 9.14D-15, 2580.0_dp, TEMP) ;
146 {147:052} O3+C2H4=HCHO+HCOOH : 0.87*ARR2( 9.14D-15, 2580.0_dp, TEMP) ;
147 {148:053} O3+C3H6=HCHO+CO+CH3OO+OH : 0.36*ARR2( 5.51D-15, 1878.0_dp, TEMP) ;
148 {149:054} O3+C3H6=HCHO+CH3CO2H : 0.64*ARR2( 5.51D-15, 1878.0_dp, TEMP) ;
149 {150:055} O3+TBUT2ENE=CH3CHO+CO+CH3OO+OH : 0.69*ARR2( 6.64D-15, 1059.0_dp, TEMP) ;
150 {151:056} O3+TBUT2ENE=CH3CHO+CH3CO2H : 0.31*ARR2( 6.64D-15, 1059.0_dp, TEMP) ;
151 {152:057} OH+C5H8=RU14O2 : ARR2( 2.54D-11, -410.0_dp, TEMP) ;
152 {153:058} NO3+C5H8=NRU14O2 : ARR2( 3.03D-12, 446.0_dp, TEMP) ;
153 {154:059} O3+C5H8=UCARB10+CO+HO2+OH : 0.27*ARR2( 7.86D-15, 1913.0_dp, TEMP) ;
154 {155:060} O3+C5H8=UCARB10+HCOOH : 0.73*ARR2( 7.86D-15, 1913.0_dp, TEMP) ;
155 {156:061} APINENE+OH=RTN28O2 : ARR2( 1.20D-11, -444.0_dp, TEMP) ;
156 {157:062} APINENE+NO3=NRTN28O2 : ARR2( 1.19D-12, -490.0_dp, TEMP) ;
157 {158:063} APINENE+O3=OH+CH3COCH3+RN18AO2 : 0.80*ARR2( 1.01D-15, 732.0_dp, TEMP) ;
158 {159:064} APINENE+O3=TNCARB26+H2O2 : 0.075*ARR2( 1.01D-15, 732.0_dp, TEMP) ;
159 {160:065} APINENE+O3=RCOOH25 : 0.125*ARR2( 1.01D-15, 732.0_dp, TEMP) ;
160 {161:066} BPINENE+OH=RTX28O2 : ARR2( 2.38D-11, -357.0_dp, TEMP) ;
161 {162:067} BPINENE+NO3=NRTX28O2 : 2.51D-12 ;
162 {163:068} BPINENE+O3= RTX24O2+OH : 1.50D-17*0.35 ;
163 {164:069} BPINENE+O3= HCHO+TXCARB24+H2O2 : 1.50D-17*0.20 ;
164 {165:070} BPINENE+O3= HCHO+TXCARB22 : 1.50D-17*0.25 ;
165 {166:071} BPINENE+O3= TXCARB24+CO : 1.50D-17*0.20 ;
166 {167:072} C2H2+OH=HCOOH+CO+HO2 : 0.364*KMT_IUPAC(5.0D-30, 1.5_dp, 1.0D-12, 0.0_dp, 0.37_dp, TEMP,C_M) ;
167 {168:073} C2H2+OH=CARB3+OH : 0.636*KMT_IUPAC(5.0D-30, 1.5_dp, 1.0D-12, 0.0_dp, 0.37_dp, TEMP,C_M) ;
168 {169:074} BENZENE+OH=RA13O2 : 0.47*ARR2( 2.33D-12, 193.0_dp, TEMP) ;
169 {170:075} BENZENE+OH=AROH14+HO2 : 0.53*ARR2( 2.33D-12, 193.0_dp, TEMP) ;
170 {171:076} TOLUENE+OH=RA16O2 : 0.82*ARR2( 1.81D-12, -338.0_dp, TEMP) ;
171 {172:077} TOLUENE+OH=AROH17+HO2 : 0.18*ARR2( 1.81D-12, -338.0_dp, TEMP) ;
172 {173:078} OXYL+OH=RA19AO2 : 1.36D-11*0.70 ;
173 {174:079} OXYL+OH=RA19CO2 : 1.36D-11*0.30 ;
174 {175:080} OH+HCHO=HO2+CO : 1.20D-14*TEMP*EXP(287/TEMP) ;
175 {176:081} OH+CH3CHO=CH3CO3 : ARR2( 5.55D-12, -311.0_dp, TEMP) ;
176 {177:082} OH+C2H5CHO=C2H5CO3 : 1.96D-11 ;
177 {178:083} NO3+HCHO=HO2+CO+HNO3 : 5.80D-16 ;
178 {179:084} NO3+CH3CHO=CH3CO3+HNO3 : 1.44d-12*EXP(-1862.0/temp) ;
179 {180:085} NO3+C2H5CHO=C2H5CO3+HNO3 : 1.44d-12*EXP(-1862.0/temp)*2.4 ;
180 {181:086} OH+CH3COCH3=RN8O2 : 5.34D-18*TEMP**2*EXP(-230/TEMP) ;
181 {182:087} MEK+OH=RN11O2 : 3.24D-18*TEMP**2*EXP(414/TEMP) ;
182 {183:088} OH+CH3OH=HO2+HCHO : 6.01D-18*TEMP**2*EXP(170/TEMP) ;
183 {184:089} OH+C2H5OH=CH3CHO+HO2 : 6.18D-18*TEMP**2*EXP(532/TEMP)*0.887 ;
184 {185:090} OH+C2H5OH=HOCH2CH2O2 : 6.18D-18*TEMP**2*EXP(532/TEMP)*0.113 ;
185 {186:091} NPROPOL+OH=C2H5CHO+HO2 : 5.53D-12*0.49 ;
186 {187:092} NPROPOL+OH=RN9O2 : 5.53D-12*0.51 ;
187 {188:093} OH+IPROPOL=CH3COCH3+HO2 : 4.06D-18*TEMP**2*EXP(788/TEMP)*0.86 ;
188 {189:094} OH+IPROPOL=RN9O2 : 4.06D-18*TEMP**2*EXP(788/TEMP)*0.14 ;
189 {190:095} HCOOH+OH=HO2 : 4.50D-13 ;
190 {191:096} CH3CO2H+OH=CH3OO : 8.00D-13 ;
191 {192:097} CH3OO+NO=HCHO+HO2+NO2 : 0.999*ARR2( 3.00D-12, -280.0_dp, TEMP) ;
192 {193:098} C2H5O2+NO=CH3CHO+HO2+NO2 : 0.991*ARR2( 2.60D-12, -365.0_dp, TEMP) ;
193 {194:099} RN10O2+NO=C2H5CHO+HO2+NO2 : 0.980*ARR2( 2.80D-12, -360.0_dp, TEMP) ;
194 {195:100} IC3H7O2+NO=CH3COCH3+HO2+NO2 : 0.958*ARR2( 2.70D-12, -360.0_dp, TEMP) ;
195 {196:101} RN13O2+NO=CH3CHO+C2H5O2+NO2 : 2.40d-12*EXP(360.0/temp)*0.917*0.398 ;
196 {197:102} RN13O2+NO=CARB11A+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.917*0.602 ;
197 {198:103} RN16O2+NO=RN15AO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.877 ;
198 {199:104} RN19O2+NO=RN18AO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.788 ;
199 {200:105} RN13AO2+NO=RN12O2+NO2 : 2.40d-12*EXP(360.0/temp) ;
200 {201:106} RN16AO2+NO=RN15O2+NO2 : 2.40d-12*EXP(360.0/temp) ;
201 {202:107} RA13O2+NO=CARB3+UDCARB8+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.918 ;
202 {203:108} RA16O2+NO=CARB3+UDCARB11+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.889*0.7 ;
203 {204:109} RA16O2+NO=CARB6+UDCARB8+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.889*0.3 ;
204 {205:110} RA19AO2+NO=CARB3+UDCARB14+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.862 ;
205 {206:111} RA19CO2+NO=CARB9+UDCARB8+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.862 ;
206 {207:112} HOCH2CH2O2+NO=HCHO+HCHO+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.995*0.776 ;
207 {208:113} HOCH2CH2O2+NO=HOCH2CHO+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.995*0.224 ;
208 {209:114} RN9O2+NO=CH3CHO+HCHO+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.979 ;
209 {210:115} RN12O2+NO=CH3CHO+CH3CHO+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.959 ;
210 {211:116} RN15O2+NO=C2H5CHO+CH3CHO+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.936 ;
211 {212:117} RN18O2+NO=C2H5CHO+C2H5CHO+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.903 ;
212 {213:118} RN15AO2+NO=CARB13+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.975 ;
213 {214:119} RN18AO2+NO=CARB16+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.946 ;
214 {215:120} CH3CO3+NO=CH3OO+NO2 : 8.10d-12*EXP(270.0/temp) ;
215 {216:121} C2H5CO3+NO=C2H5O2+NO2 : 8.10d-12*EXP(270.0/temp) ;
216 {217:122} HOCH2CO3+NO=HO2+HCHO+NO2 : 8.10d-12*EXP(270.0/temp) ;
217 {218:123} RN8O2+NO=CH3CO3+HCHO+NO2 : 2.40d-12*EXP(360.0/temp) ;
218 {219:124} RN11O2+NO=CH3CO3+CH3CHO+NO2 : 2.40d-12*EXP(360.0/temp) ;
219 {220:125} RN14O2+NO=C2H5CO3+CH3CHO+NO2 : 2.40d-12*EXP(360.0/temp) ;
220 {221:126} RN17O2+NO=RN16AO2+NO2 : 2.40d-12*EXP(360.0/temp) ;
221 {222:127} RU14O2+NO=UCARB12+HO2+ NO2 : 2.40d-12*EXP(360.0/temp)*0.900*0.252 ;
222 {223:128} RU14O2+NO=UCARB10+HCHO+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.900*0.748 ;
223 {224:129} RU12O2+NO=CH3CO3+HOCH2CHO+NO2 : 2.40d-12*EXP(360.0/temp)*0.7 ;
224 {225:130} RU12O2+NO=CARB7+CO+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.3 ;
225 {226:131} RU10O2+NO=CH3CO3+HOCH2CHO+NO2 : 2.40d-12*EXP(360.0/temp)*0.5 ;
226 {227:132} RU10O2+NO=CARB6+HCHO+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.3 ;
227 {228:133} RU10O2+NO=CARB7+HCHO+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.2 ;
228 {229:134} NRN6O2+NO=HCHO+HCHO+NO2+NO2 : 2.40d-12*EXP(360.0/temp) ;
229 {230:135} NRN9O2+NO=CH3CHO+HCHO+NO2+NO2 : 2.40d-12*EXP(360.0/temp) ;
230 {231:136} NRN12O2+NO=CH3CHO+CH3CHO+NO2+NO2 : 2.40d-12*EXP(360.0/temp) ;
231 {232:137} NRU14O2+NO=NUCARB12+HO2+NO2 : 2.40d-12*EXP(360.0/temp) ;
232 {233:138} NRU12O2+NO=NOA+CO+HO2+NO2 : 2.40d-12*EXP(360.0/temp) ;
233 {234:139} RTN28O2+NO=TNCARB26+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.767*0.915 ;
234 {235:140} RTN28O2+NO=CH3COCH3+RN19O2+NO2 : 2.40d-12*EXP(360.0/temp)*0.767*0.085 ;
235 {236:141} NRTN28O2+NO=TNCARB26+NO2+NO2 : 2.40d-12*EXP(360.0/temp) ;
236 {237:142} RTN26O2+NO=RTN25O2+NO2 : 2.40d-12*EXP(360.0/temp) ;
237 {238:143} RTN25O2+NO=RTN24O2+NO2 : 2.40d-12*EXP(360.0/temp)*0.840 ;
238 {239:144} RTN24O2+NO=RTN23O2+NO2 : 2.40d-12*EXP(360.0/temp) ;
239 {240:145} RTN23O2+NO=CH3COCH3+RTN14O2+NO2 : 2.40d-12*EXP(360.0/temp) ;
240 {241:146} RTN14O2+NO=HCHO+TNCARB10+HO2+NO2 : 2.40d-12*EXP(360.0/temp) ;
241 {242:147} RTN10O2+NO=RN8O2+CO+NO2 : 2.40d-12*EXP(360.0/temp) ;
242 {243:148} RTX28O2+NO=TXCARB24+HCHO+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.767*0.915 ;
243 {244:149} RTX28O2+NO=CH3COCH3+RN19O2+NO2 : 2.40d-12*EXP(360.0/temp)*0.767*0.085 ;
244 {245:150} NRTX28O2+NO=TXCARB24+HCHO+NO2+NO2 : 2.40d-12*EXP(360.0/temp) ;
245 {246:151} RTX24O2+NO=TXCARB22+HO2+NO2 : 2.40d-12*EXP(360.0/temp)*0.843*0.6 ;
246 {247:152} RTX24O2+NO=CH3COCH3+RN13AO2+HCHO+NO2 : 2.40d-12*EXP(360.0/temp)*0.843*0.4 ;
247 {248:153} RTX22O2+NO=CH3COCH3+RN13O2+NO2 : 2.40d-12*EXP(360.0/temp)*0.700 ;
248 {249:154} CH3OO+NO=CH3NO3 : 0.001*ARR2( 3.00D-12, -280.0_dp, TEMP) ;
249 {250:155} C2H5O2+NO=C2H5NO3 : 0.009*ARR2( 2.60D-12, -365.0_dp, TEMP) ;
250 {251:156} RN10O2+NO=RN10NO3 : 0.020*ARR2( 2.80D-12, -360.0_dp, TEMP) ;
251 {252:157} IC3H7O2+NO=IC3H7NO3 : 0.042*ARR2( 2.70D-12, -360.0_dp, TEMP) ;
252 {253:158} RN13O2+NO=RN13NO3 : 2.40d-12*EXP(360.0/temp)*0.083 ;
253 {254:159} RN16O2+NO=RN16NO3 : 2.40d-12*EXP(360.0/temp)*0.123 ;
254 {255:160} RN19O2+NO=RN19NO3 : 2.40d-12*EXP(360.0/temp)*0.212 ;
255 {256:161} HOCH2CH2O2+NO=HOC2H4NO3 : 2.40d-12*EXP(360.0/temp)*0.005 ;
256 {257:162} RN9O2+NO=RN9NO3 : 2.40d-12*EXP(360.0/temp)*0.021 ;
257 {258:163} RN12O2+NO=RN12NO3 : 2.40d-12*EXP(360.0/temp)*0.041 ;
258 {259:164} RN15O2+NO=RN15NO3 : 2.40d-12*EXP(360.0/temp)*0.064 ;
259 {260:165} RN18O2+NO=RN18NO3 : 2.40d-12*EXP(360.0/temp)*0.097 ;
260 {261:166} RN15AO2+NO=RN15NO3 : 2.40d-12*EXP(360.0/temp)*0.025 ;
261 {262:167} RN18AO2+NO=RN18NO3 : 2.40d-12*EXP(360.0/temp)*0.054 ;
262 {263:168} RU14O2+NO=RU14NO3 : 2.40d-12*EXP(360.0/temp)*0.100 ;
263 {264:169} RA13O2+NO=RA13NO3 : 2.40d-12*EXP(360.0/temp)*0.082 ;
264 {265:170} RA16O2+NO=RA16NO3 : 2.40d-12*EXP(360.0/temp)*0.111 ;
265 {266:171} RA19AO2+NO=RA19NO3 : 2.40d-12*EXP(360.0/temp)*0.138 ;
266 {267:172} RA19CO2+NO=RA19NO3 : 2.40d-12*EXP(360.0/temp)*0.138 ;
267 {268:173} RTN28O2+NO=RTN28NO3 : 2.40d-12*EXP(360.0/temp)*0.233 ;
268 {269:174} RTN25O2+NO=RTN25NO3 : 2.40d-12*EXP(360.0/temp)*0.160 ;
269 {270:175} RTX28O2+NO=RTX28NO3 : 2.40d-12*EXP(360.0/temp)*0.233 ;
270 {271:176} RTX24O2+NO=RTX24NO3 : 2.40d-12*EXP(360.0/temp)*0.157 ;
271 {272:177} RTX22O2+NO=RTX22NO3 : 2.40d-12*EXP(360.0/temp)*0.300 ;
272 {273:178} CH3OO+NO3=HCHO+HO2+NO2 : 2.50d-12*0.40 ;
273 {274:179} C2H5O2+NO3=CH3CHO+HO2+NO2 : 2.50d-12 ;
274 {275:180} RN10O2+NO3=C2H5CHO+HO2+NO2 : 2.50d-12 ;
275 {276:181} IC3H7O2+NO3=CH3COCH3+HO2+NO2 : 2.50d-12 ;
276 {277:182} RN13O2+NO3=CH3CHO+C2H5O2+NO2 : 2.50d-12*0.398 ;
277 {278:183} RN13O2+NO3=CARB11A+HO2+NO2 : 2.50d-12*0.602 ;
278 {279:184} RN16O2+NO3=RN15AO2+NO2 : 2.50d-12 ;
279 {280:185} RN19O2+NO3=RN18AO2+NO2 : 2.50d-12 ;
280 {281:186} RN13AO2+NO3=RN12O2+NO2 : 2.50d-12 ;
281 {282:187} RN16AO2+NO3=RN15O2+NO2 : 2.50d-12 ;
282 {283:188} RA13O2+NO3=CARB3+UDCARB8+HO2+NO2 : 2.50d-12 ;
283 {284:189} RA16O2+NO3=CARB3+UDCARB11+HO2+NO2 : 2.50d-12*0.7 ;
284 {285:190} RA16O2+NO3=CARB6+UDCARB8+HO2+NO2 : 2.50d-12*0.3 ;
285 {286:191} RA19AO2+NO3=CARB3+UDCARB14+HO2+NO2 : 2.50d-12 ;
286 {287:192} RA19CO2+NO3=CARB9+UDCARB8+HO2+NO2 : 2.50d-12 ;
287 {288:193} HOCH2CH2O2+NO3=HCHO+HCHO+HO2+NO2 : 2.50d-12*0.776 ;
288 {289:194} HOCH2CH2O2+NO3=HOCH2CHO+HO2+NO2 : 2.50d-12*0.224 ;
289 {290:195} RN9O2+NO3=CH3CHO+HCHO+HO2+NO2 : 2.50d-12 ;
290 {291:196} RN12O2+NO3=CH3CHO+CH3CHO+HO2+NO2 : 2.50d-12 ;
291 {292:197} RN15O2+NO3=C2H5CHO+CH3CHO+HO2+NO2 : 2.50d-12 ;
292 {293:198} RN18O2+NO3=C2H5CHO+C2H5CHO+HO2+NO2 : 2.50d-12;
293 {294:199} RN15AO2+NO3=CARB13+HO2+NO2 : 2.50d-12 ;
294 {295:200} RN18AO2+NO3=CARB16+HO2+NO2 : 2.50d-12 ;
295 {296:201} CH3CO3+NO3=CH3OO+NO2 : 2.50d-12*1.60 ;
296 {297:202} C2H5CO3+NO3=C2H5O2+NO2 : 2.50d-12*1.60 ;
297 {298:203} HOCH2CO3+NO3=HO2+HCHO+NO2 : 2.50d-12*1.60 ;
298 {299:204} RN8O2+NO3=CH3CO3+HCHO+NO2 : 2.50d-12 ;
299 {300:205} RN11O2+NO3=CH3CO3+CH3CHO+NO2 : 2.50d-12 ;
300 {301:206} RN14O2+NO3=C2H5CO3+CH3CHO+NO2 : 2.50d-12 ;
301 {302:207} RN17O2+NO3=RN16AO2+NO2 : 2.50d-12 ;
302 {303:208} RU14O2+NO3=UCARB12+HO2+NO2 : 2.50d-12*0.252 ;
303 {304:209} RU14O2+NO3=UCARB10+HCHO+HO2+NO2 : 2.50d-12*0.748 ;
304 {305:210} RU12O2+NO3=CH3CO3+HOCH2CHO+NO2 : 2.50d-12*0.7 ;
305 {306:211} RU12O2+NO3=CARB7+CO+HO2+NO2 : 2.50d-12*0.3 ;
306 {307:212} RU10O2+NO3=CH3CO3+HOCH2CHO+NO2 : 2.50d-12*0.5 ;
307 {308:213} RU10O2+NO3=CARB6+HCHO+HO2+NO2 : 2.50d-12*0.3 ;
308 {309:214} RU10O2+NO3=CARB7+HCHO+HO2+NO2 : 2.50d-12*0.2 ;
309 {310:215} NRN6O2+NO3=HCHO+HCHO+NO2+NO2 : 2.50d-12 ;
310 {311:216} NRN9O2+NO3=CH3CHO+HCHO+NO2+NO2 : 2.50d-12 ;
311 {312:217} NRN12O2+NO3=CH3CHO+CH3CHO+NO2+NO2 : 2.50d-12 ;
312 {313:218} NRU14O2+NO3=NUCARB12+HO2+NO2 : 2.50d-12 ;
313 {314:219} NRU12O2+NO3=NOA+CO+HO2+NO2 : 2.50d-12 ;
314 {315:220} RTN28O2+NO3=TNCARB26+HO2+NO2 : 2.50d-12 ;
315 {316:221} NRTN28O2+NO3=TNCARB26+NO2+NO2 : 2.50d-12 ;
316 {317:222} RTN26O2+NO3=RTN25O2+NO2 : 2.50d-12 ;
317 {318:223} RTN25O2+NO3=RTN24O2+NO2 : 2.50d-12 ;
318 {319:224} RTN24O2+NO3=RTN23O2+NO2 : 2.50d-12 ;
319 {320:225} RTN23O2+NO3=CH3COCH3+RTN14O2+NO2 : 2.50d-12 ;
320 {321:226} RTN14O2+NO3=HCHO+TNCARB10+HO2+NO2 : 2.50d-12 ;
321 {322:227} RTN10O2+NO3=RN8O2+CO+NO2 : 2.50d-12 ;
322 {323:228} RTX28O2+NO3=TXCARB24+HCHO+HO2+NO2 : 2.50d-12 ;
323 {324:229} RTX24O2+NO3=TXCARB22+HO2+NO2 : 2.50d-12 ;
324 {325:230} RTX22O2+NO3=CH3COCH3+RN13O2+NO2 : 2.50d-12 ;
325 {326:231} NRTX28O2+NO3=TXCARB24+HCHO+NO2+NO2 : 2.50d-12 ;
326 {327:232} CH3OO+HO2=CH3OOH : ARR2( 3.80D-13, -780.0_dp, TEMP) ;
327 {328:233} C2H5O2+HO2=C2H5OOH : ARR2( 7.50D-13, -700.0_dp, TEMP) ;
328 {329:234} RN10O2+HO2=RN10OOH : 0.520*2.91d-13*EXP(1300.0/temp) ;
329 {330:235} IC3H7O2+HO2=IC3H7OOH : 0.520*2.91d-13*EXP(1300.0/temp) ;
330 {331:236} RN13O2+HO2=RN13OOH : 0.625*2.91d-13*EXP(1300.0/temp) ;
331 {332:237} RN16O2+HO2=RN16OOH : 0.706*2.91d-13*EXP(1300.0/temp) ;
332 {333:238} RN19O2+HO2=RN19OOH : 0.770*2.91d-13*EXP(1300.0/temp) ;
333 {334:239} RN13AO2+HO2=RN13OOH : 0.625*2.91d-13*EXP(1300.0/temp) ;
334 {335:240} RN16AO2+HO2=RN16OOH : 0.706*2.91d-13*EXP(1300.0/temp) ;
335 {336:241} RA13O2+HO2=RA13OOH : 0.770*2.91d-13*EXP(1300.0/temp) ;
336 {337:242} RA16O2+HO2=RA16OOH : 0.820*2.91d-13*EXP(1300.0/temp) ;
337 {338:243} RA19AO2+HO2=RA19OOH : 0.859*2.91d-13*EXP(1300.0/temp) ;
338 {339:244} RA19CO2+HO2=RA19OOH : 0.859*2.91d-13*EXP(1300.0/temp) ;
339 {340:245} HOCH2CH2O2+HO2=HOC2H4OOH : ARR2( 2.03D-13, -1250.0_dp, TEMP) ;
340 {341:246} RN9O2+HO2=RN9OOH : 0.520*2.91d-13*EXP(1300.0/temp) ;
341 {342:247} RN12O2+HO2=RN12OOH : 0.625*2.91d-13*EXP(1300.0/temp) ;
342 {343:248} RN15O2+HO2=RN15OOH : 0.706*2.91d-13*EXP(1300.0/temp) ;
343 {344:249} RN18O2+HO2=RN18OOH : 0.770*2.91d-13*EXP(1300.0/temp) ;
344 {345:250} RN15AO2+HO2=RN15OOH : 0.706*2.91d-13*EXP(1300.0/temp) ;
345 {346:251} RN18AO2+HO2=RN18OOH : 0.770*2.91d-13*EXP(1300.0/temp) ;
346 {347:252} CH3CO3+HO2=CH3CO3H : 4.30d-13*EXP(1040.0/temp) ;
347 {348:253} C2H5CO3+HO2=C2H5CO3H : 4.30d-13*EXP(1040.0/temp) ;
348 {349:254} HOCH2CO3+HO2=HOCH2CO3H : 4.30d-13*EXP(1040.0/temp) ;
349 {350:255} RN8O2+HO2=RN8OOH : 0.520*2.91d-13*EXP(1300.0/temp) ;
350 {351:256} RN11O2+HO2=RN11OOH : 0.625*2.91d-13*EXP(1300.0/temp) ;
351 {352:257} RN14O2+HO2=RN14OOH : 0.706*2.91d-13*EXP(1300.0/temp) ;
352 {353:258} RN17O2+HO2=RN17OOH : 0.770*2.91d-13*EXP(1300.0/temp) ;
353 {354:258} RU14O2+HO2=RU14OOH : 0.770*2.91d-13*EXP(1300.0/temp) ;
354 {355:260} RU12O2+HO2=RU12OOH : 0.706*2.91d-13*EXP(1300.0/temp) ;
355 {356:261} RU10O2+HO2=RU10OOH : 0.625*2.91d-13*EXP(1300.0/temp) ;
356 {357:262} NRN6O2+HO2=NRN6OOH : 0.387*2.91d-13*EXP(1300.0/temp) ;
357 {358:263} NRN9O2+HO2=NRN9OOH : 0.520*2.91d-13*EXP(1300.0/temp) ;
358 {359:264} NRN12O2+HO2=NRN12OOH : 0.625*2.91d-13*EXP(1300.0/temp) ;
359 {360:265} NRU14O2+HO2=NRU14OOH : 0.770*2.91d-13*EXP(1300.0/temp) ;
360 {361:266} NRU12O2+HO2=NRU12OOH : 0.625*2.91d-13*EXP(1300.0/temp) ;
361 {362:267} RTN28O2+HO2=RTN28OOH : 0.914*2.91d-13*EXP(1300.0/temp) ;
362 {363:268} NRTN28O2+HO2=NRTN28OOH : 0.914*2.91d-13*EXP(1300.0/temp) ;
363 {364:269} RTN26O2+HO2=RTN26OOH : 0.914*2.91d-13*EXP(1300.0/temp) ;
364 {365:270} RTN25O2+HO2=RTN25OOH : 0.890*2.91d-13*EXP(1300.0/temp) ;
365 {366:271} RTN24O2+HO2=RTN24OOH : 0.890*2.91d-13*EXP(1300.0/temp) ;
366 {367:272} RTN23O2+HO2=RTN23OOH : 0.890*2.91d-13*EXP(1300.0/temp) ;
367 {368:273} RTN14O2+HO2=RTN14OOH : 0.770*2.91d-13*EXP(1300.0/temp) ;
368 {369:274} RTN10O2+HO2=RTN10OOH : 0.706*2.91d-13*EXP(1300.0/temp) ;
369 {370:275} RTX28O2+HO2=RTX28OOH : 0.914*2.91d-13*EXP(1300.0/temp) ;
370 {371:276} RTX24O2+HO2=RTX24OOH : 0.890*2.91d-13*EXP(1300.0/temp) ;
371 {372:277} RTX22O2+HO2=RTX22OOH : 0.890*2.91d-13*EXP(1300.0/temp) ;
372 {373:278} NRTX28O2+HO2=NRTX28OOH : 0.914*2.91d-13*EXP(1300.0/temp) ;
373 {374:279} CH3OO=HCHO+HO2 : 0.33*RO2*ARR2( 1.82D-13, -416.0_dp, TEMP) ;
374 {375:280} CH3OO=HCHO : 0.335*RO2*ARR2( 1.82D-13, -416.0_dp, TEMP) ;
375 {376:281} CH3OO=CH3OH : 0.335*RO2*ARR2( 1.82D-13, -416.0_dp, TEMP) ;
376 {377:282} C2H5O2=CH3CHO+HO2 : 3.10D-13*0.6*RO2 ;
377 {378:283} C2H5O2=CH3CHO : 3.10D-13*0.2*RO2 ;
378 {379:284} C2H5O2=C2H5OH : 3.10D-13*0.2*RO2 ;
379 {380:285} RN10O2=C2H5CHO+HO2 : 6.00D-13*0.6*RO2 ;
380 {381:286} RN10O2=C2H5CHO : 6.00D-13*0.2*RO2 ;
381 {382:287} RN10O2=NPROPOL : 6.00D-13*0.2*RO2 ;
382 {383:288} IC3H7O2=CH3COCH3+HO2 : 4.00D-14*0.6*RO2 ;
383 {384:289} IC3H7O2=CH3COCH3 : 4.00D-14*0.2*RO2 ;
384 {385:290} IC3H7O2=IPROPOL : 4.00D-14*0.2*RO2 ;
385 {386:291} RN13O2=CH3CHO+C2H5O2 : 2.50D-13*RO2*0.398 ;
386 {387:292} RN13O2=CARB11A+HO2 : 2.50D-13*RO2*0.602 ;
387 {388:293} RN13AO2=RN12O2 : 8.80D-13*RO2 ;
388 {389:294} RN16AO2=RN15O2 : 8.80D-13*RO2 ;
389 {390:295} RA13O2=CARB3+UDCARB8+HO2 : 8.80D-13*RO2 ;
390 {391:296} RA16O2=CARB3+UDCARB11+HO2 : 8.80D-13*RO2*0.7 ;
391 {392:297} RA16O2=CARB6+UDCARB8+HO2 : 8.80D-13*RO2*0.3 ;
392 {393:298} RA19AO2=CARB3+UDCARB14+HO2 : 8.80D-13*RO2 ;
393 {394:299} RA19CO2=CARB3+UDCARB14+HO2 : 8.80D-13*RO2 ;
394 {395:300} RN16O2=RN15AO2 : 2.50D-13*RO2 ;
395 {396:301} RN19O2=RN18AO2 : 2.50D-13*RO2 ;
396 {397:302} HOCH2CH2O2=HCHO+HCHO+HO2 : 2.00D-12*RO2*0.776 ;
397 {398:303} HOCH2CH2O2=HOCH2CHO+HO2 : 2.00D-12*RO2*0.224 ;
398 {399:304} RN9O2=CH3CHO+HCHO+HO2 : 8.80D-13*RO2 ;
399 {400:305} RN12O2=CH3CHO+CH3CHO+HO2 : 8.80D-13*RO2 ;
400 {401:306} RN15O2=C2H5CHO+CH3CHO+HO2 : 8.80D-13*RO2 ;
401 {402:307} RN18O2=C2H5CHO+C2H5CHO+HO2 : 8.80D-13*RO2 ;
402 {403:308} RN15AO2=CARB13+HO2 : 8.80D-13*RO2 ;
403 {404:309} RN18AO2=CARB16+HO2 : 8.80D-13*RO2 ;
404 {405:310} CH3CO3=CH3OO : 1.00D-11*RO2 ;
405 {406:311} C2H5CO3=C2H5O2 : 1.00D-11*RO2 ;
406 {407:312} HOCH2CO3=HCHO+HO2 : 1.00D-11*RO2 ;
407 {408:313} RN8O2=CH3CO3+HCHO : 1.40D-12*RO2 ;
408 {409:314} RN11O2=CH3CO3+CH3CHO : 1.40D-12*RO2 ;
409 {410:315} RN14O2=C2H5CO3+CH3CHO : 1.40D-12*RO2 ;
410 {411:316} RN17O2=RN16AO2 : 1.40D-12*RO2 ;
411 {412:317} RU14O2=UCARB12+HO2 : 1.71D-12*RO2*0.252 ;
412 {413:318} RU14O2=UCARB10+HCHO+HO2 : 1.71D-12*RO2*0.748 ;
413 {414:319} RU12O2=CH3CO3+HOCH2CHO : 2.00D-12*RO2*0.7 ;
414 {415:320} RU12O2=CARB7+HOCH2CHO+HO2 : 2.00D-12*RO2*0.3 ;
415 {416:321} RU10O2=CH3CO3+HOCH2CHO : 2.00D-12*RO2*0.5 ;
416 {417:322} RU10O2=CARB6+HCHO+HO2 : 2.00D-12*RO2*0.3 ;
417 {418:323} RU10O2=CARB7+HCHO+HO2 : 2.00D-12*RO2*0.2 ;
418 {419:324} NRN6O2=HCHO+HCHO+NO2 : 6.00D-13*RO2 ;
419 {420:325} NRN9O2=CH3CHO+HCHO+NO2 : 2.30D-13*RO2 ;
420 {421:326} NRN12O2=CH3CHO+CH3CHO+NO2 : 2.50D-13*RO2 ;
421 {422:327} NRU14O2=NUCARB12+HO2 : 1.30D-12*RO2 ;
422 {423:328} NRU12O2=NOA+CO+HO2 : 9.60D-13*RO2 ;
423 {424:329} RTN28O2=TNCARB26+HO2 : 2.85D-13*RO2 ;
424 {425:330} NRTN28O2=TNCARB26+NO2 : 1.00D-13*RO2 ;
425 {426:331} RTN26O2=RTN25O2 : 2.00D-12*RO2 ;
426 {427:332} RTN25O2=RTN24O2 : 1.30D-12*RO2 ;
427 {428:333} RTN24O2=RTN23O2 : 6.70D-15*RO2 ;
428 {429:334} RTN23O2=CH3COCH3+RTN14O2 : 6.70D-15*RO2 ;
429 {430:335} RTN14O2=HCHO+TNCARB10+HO2 : 8.80D-13*RO2 ;
430 {431:336} RTN10O2=RN8O2+CO : 2.00D-12*RO2 ;
431 {432:337} RTX28O2=TXCARB24+HCHO+HO2 : 2.00D-12*RO2 ;
432 {433:338} RTX24O2=TXCARB22+HO2 : 2.50D-13*RO2 ;
433 {434:339} RTX22O2=CH3COCH3+RN13O2 : 2.50D-13*RO2 ;
434 {435:340} NRTX28O2=TXCARB24+HCHO+NO2 : 9.20D-14*RO2 ;
435 {436:341} OH+CARB14=RN14O2 : 1.87D-11 ;
436 {437:342} OH+CARB17=RN17O2 : 4.36D-12 ;
437 {438:343} OH+CARB11A=RN11O2 : 3.24D-18*TEMP**2*EXP(414/TEMP) ;
438 {439:344} OH+CARB7=CARB6+HO2 : 3.00D-12 ;
439 {440:345} OH+CARB10=CARB9+HO2 : 5.86D-12 ;
440 {441:346} OH+CARB13=RN13O2 : 1.65D-11 ;
441 {442:347} OH+CARB16=RN16O2 : 1.25D-11 ;
442 {443:348} OH+UCARB10=RU10O2 : 2.50D-11 ;
443 {444:349} NO3+UCARB10=RU10O2+HNO3 : 1.44d-12*EXP(-1862.0/temp) ;
444 {445:350} O3+UCARB10=HCHO+CH3CO3+CO+OH : 2.85D-18*0.59 ;
445 {446:351} O3+UCARB10=HCHO+CARB6+H2O2 : 2.85D-18*0.41 ;
446 {447:352} OH+HOCH2CHO=HOCH2CO3 : 1.00D-11 ;
447 {448:353} NO3+HOCH2CHO=HOCH2CO3+HNO3 : 1.44d-12*EXP(-1862.0/temp) ;
448 {449:354} OH+CARB3=CO+CO+HO2 : 1.14D-11 ;
449 {450:355} OH+CARB6=CH3CO3+CO : 1.72D-11 ;
450 {451:356} OH+CARB9=RN9O2 : 2.40D-13 ;
451 {452:357} OH+CARB12=RN12O2 : 1.38D-12 ;
452 {453:358} OH+CARB15=RN15O2 : 4.81D-12 ;
453 {454:359} OH+CCARB12=RN12O2 : 4.79D-12 ;
454 {455:360} OH+UCARB12=RU12O2 : 4.52D-11 ;
455 {456:361} NO3+UCARB12=RU12O2+HNO3 : 1.44d-12*EXP(-1862.0/temp)*4.25 ;
456 {457:362} O3+UCARB12=HOCH2CHO+CH3CO3+CO+OH : 2.40D-17*0.89 ;
457 {458:363} O3+UCARB12=HOCH2CHO+CARB6+H2O2 : 2.40D-17*0.11 ;
458 {459:364} OH+NUCARB12=NRU12O2 : 4.16D-11 ;
459 {460:365} OH+NOA=CARB6+NO2 : 1.30D-13 ;
460 {461:366} OH+UDCARB8=C2H5O2 : 5.20D-11*0.5 ;
461 {462:367} OH+UDCARB11=RN10O2 : 5.58D-11*0.55 ;
462 {463:368} OH+UDCARB14=RN13O2 : 7.00D-11*0.55 ;
463 {464:369} OH+TNCARB26=RTN26O2 : 4.20D-11 ;
464 {465:370} OH+TNCARB15=RN15AO2 : 1.00D-12 ;
465 {466:371} OH+TNCARB10=RTN10O2 : 1.00D-10 ;
466 {467:372} NO3+TNCARB26=RTN26O2+HNO3 : 3.80D-14 ;
467 {468:373} NO3+TNCARB10=RTN10O2+HNO3 : 1.44d-12*EXP(-1862.0/temp)*5.5 ;
468 {469:374} OH+RCOOH25=RTN25O2 : 6.65D-12 ;
469 {470:375} OH+TXCARB24=RTX24O2 : 1.55D-11 ;
470 {471:376} OH+TXCARB22=RTX22O2 : 4.55D-12 ;
471 {472:377} OH+CH3NO3=HCHO+NO2 : ARR2( 1.00D-14, -1060.0_dp, TEMP) ;
472 {473:378} OH+C2H5NO3=CH3CHO+NO2 : ARR2( 4.40D-14, -720.0_dp, TEMP) ;
473 {474:379} OH+RN10NO3=C2H5CHO+NO2 : 7.30D-13 ;
474 {475:380} OH+IC3H7NO3=CH3COCH3+NO2 : 4.90D-13 ;
475 {476:381} OH+RN13NO3=CARB11A+NO2 : 9.20D-13 ;
476 {477:382} OH+RN16NO3=CARB14+NO2 : 1.85D-12 ;
477 {478:383} OH+RN19NO3=CARB17+NO2 : 3.02D-12 ;
478 {479:384} OH+HOC2H4NO3=HOCH2CHO+NO2 : 1.09D-12 ;
479 {480:385} OH+RN9NO3=CARB7+NO2 : 1.31D-12 ;
480 {481:386} OH+RN12NO3=CARB10+NO2 : 1.79D-12 ;
481 {482:387} OH+RN15NO3=CARB13+NO2 : 1.03D-11 ;
482 {483:388} OH+RN18NO3=CARB16+NO2 : 1.34D-11 ;
483 {484:389} OH+RU14NO3=UCARB12+NO2 : 5.55D-11 ;
484 {485:390} OH+RA13NO3=CARB3+UDCARB8+NO2 : 7.30D-11 ;
485 {486:391} OH+RA16NO3=CARB3+UDCARB11+NO2 : 7.16D-11 ;
486 {487:392} OH+RA19NO3=CARB6+UDCARB11+NO2 : 8.31D-11 ;
487 {488:393} OH+RTN28NO3=TNCARB26+NO2 : 4.35D-12 ;
488 {489:394} OH+RTN25NO3=CH3COCH3+TNCARB15+NO2 : 2.88D-12 ;
489 {490:395} OH+RTX28NO3=TXCARB24+HCHO+NO2 : 3.53D-12 ;
490 {491:396} OH+RTX24NO3=TXCARB22+NO2 : 6.48D-12 ;
491 {492:397} OH+RTX22NO3=CH3COCH3+CCARB12+NO2 : 4.74D-12 ;
492 {493:398} OH+AROH14=RAROH14 : 2.63D-11 ;
493 {494:399} NO3+AROH14=RAROH14+HNO3 : 3.78D-12 ;
494 {495:400} RAROH14+NO2=ARNOH14 : 2.08D-12 ;
495 {496:401} OH+ARNOH14=CARB13+NO2 : 9.00D-13 ;
496 {497:402} NO3+ARNOH14=CARB13+NO2+HNO3 : 9.00D-14 ;
497 {498:403} OH+AROH17=RAROH17 : 4.65D-11 ;
498 {499:404} NO3+AROH17=RAROH17+HNO3 : 1.25D-11 ;
499 {500:405} RAROH17+NO2=ARNOH17 : 2.08D-12 ;
500 {501:406} OH+ARNOH17=CARB16+NO2 : 1.53D-12 ;
501 {502:407} NO3+ARNOH17=CARB16+NO2+HNO3 : 3.13D-13 ;
502 {503:408} OH+CH3OOH=CH3OO : ARR2( 1.90D-12, -190.0_dp, TEMP) ;
503 {504:409} OH+CH3OOH=HCHO+OH : ARR2( 1.00D-12, -190.0_dp, TEMP) ;
504 {505:410} OH+C2H5OOH=CH3CHO+OH : 1.36D-11 ;
505 {506:411} OH+RN10OOH=C2H5CHO+OH : 1.89D-11 ;
506 {507:412} OH+IC3H7OOH=CH3COCH3+OH : 2.78D-11 ;
507 {508:413} OH+RN13OOH=CARB11A+OH : 3.57D-11 ;
508 {509:414} OH+RN16OOH=CARB14+OH : 4.21D-11 ;
509 {510:415} OH+RN19OOH=CARB17+OH : 4.71D-11 ;
510 {511:416} OH+CH3CO3H=CH3CO3 : 3.70D-12 ;
511 {512:417} OH+C2H5CO3H=C2H5CO3 : 4.42D-12 ;
512 {513:418} OH+HOCH2CO3H=HOCH2CO3 : 6.19D-12 ;
513 {514:419} OH+RN8OOH=CARB6+OH : 4.42D-12 ;
514 {515:420} OH+RN11OOH=CARB9+OH : 2.50D-11 ;
515 {516:421} OH+RN14OOH=CARB12+OH : 3.20D-11 ;
516 {517:422} OH+RN17OOH=CARB15+OH : 3.35D-11 ;
517 {518:423} OH+RU14OOH=UCARB12+OH : 7.51D-11 ;
518 {519:424} OH+RU12OOH=RU12O2 : 3.00D-11 ;
519 {520:425} OH+RU10OOH=RU10O2 : 3.00D-11 ;
520 {521:426} OH+NRU14OOH=NUCARB12+OH : 1.03D-10 ;
521 {522:427} OH+NRU12OOH=NOA+CO+OH : 2.65D-11 ;
522 {523:428} OH+HOC2H4OOH=HOCH2CHO+OH : 2.13D-11 ;
523 {524:429} OH+RN9OOH=CARB7+OH : 2.50D-11 ;
524 {525:430} OH+RN12OOH=CARB10+OH : 3.25D-11 ;
525 {526:431} OH+RN15OOH=CARB13+OH : 3.74D-11 ;
526 {527:432} OH+RN18OOH=CARB16+OH : 3.83D-11 ;
527 {528:433} OH+NRN6OOH=HCHO+HCHO+NO2+OH : 5.22D-12 ;
528 {529:434} OH+NRN9OOH=CH3CHO+HCHO+NO2+OH : 6.50D-12 ;
529 {530:435} OH+NRN12OOH=CH3CHO+CH3CHO+NO2+OH : 7.15D-12 ;
530 {531:436} OH+RA13OOH=CARB3+UDCARB8+OH : 9.77D-11 ;
531 {532:437} OH+RA16OOH=CARB3+UDCARB11+OH : 9.64D-11 ;
532 {533:438} OH+RA19OOH=CARB6+UDCARB11+OH : 1.12D-10 ;
533 {534:439} OH+RTN28OOH=TNCARB26+OH : 2.38D-11 ;
534 {535:440} OH+RTN26OOH=RTN26O2 : 1.20D-11 ;
535 {536:441} OH+NRTN28OOH=TNCARB26+NO2+OH : 9.50D-12 ;
536 {537:442} OH+RTN25OOH=RTN25O2 : 1.66D-11 ;
537 {538:443} OH+RTN24OOH=RTN24O2 : 1.05D-11 ;
538 {539:444} OH+RTN23OOH=RTN23O2 : 2.05D-11 ;
539 {540:445} OH+RTN14OOH=RTN14O2 : 8.69D-11 ;
540 {541:446} OH+RTN10OOH=RTN10O2 : 4.23D-12 ;
541 {542:447} OH+RTX28OOH=RTX28O2 : 2.00D-11 ;
542 {543:448} OH+RTX24OOH=TXCARB22+OH : 8.59D-11 ;
543 {544:449} OH+RTX22OOH=CH3COCH3+CCARB12+OH : 7.50D-11 ;
544 {545:450} OH+NRTX28OOH=NRTX28O2 : 9.58D-12 ;
545 {546:451} CH3CO3+NO2=PAN : TROE( 8.5d-29 , 6.5_dp , 1.1d-11 , 1._dp , TEMP, C_M) ;
546 {547:452} PAN=CH3CO3+NO2 : TROEE( 1.111d28,14000._dp,8.5d-29 ,6.5_dp,1.1d-11,0._dp,TEMP,C_M) ;
547 {548:453} C2H5CO3+NO2=PPN : TROE( 8.5d-29 , 6.5_dp , 1.1d-11 , 1._dp , TEMP, C_M) ;
548 {549:454} PPN=C2H5CO3+NO2 : TROEE( 1.111d28,14000._dp,8.5d-29,6.5_dp , 1.1d-11 , 0._dp,TEMP, C_M) ;
549 {550:455} HOCH2CO3+NO2=PHAN : TROE( 8.5d-29 , 6.5_dp , 1.1d-11 , 1._dp , TEMP, C_M) ;
550 {551:456} PHAN=HOCH2CO3+NO2 : TROEE( 1.111d28,14000._dp,8.5d-29 , 6.5_dp,1.1d-11,0._dp,TEMP, C_M) ;
551 {552:457} OH+PAN=HCHO+CO+NO2 : ARR2( 9.50D-13, 650.0_dp, TEMP) ;
552 {553:458} OH+PPN=CH3CHO+CO+NO2 : 1.27D-12 ;
553 {554:459} OH+PHAN=HCHO+CO+NO2 : 1.12D-12 ;
554 {555:460} RU12O2+NO2=RU12PAN : 0.061*TROE( 8.5d-29 , 6.5_dp , 1.1d-11 , 1._dp ,TEMP, C_M) ;
555 {556:461} RU12PAN=RU12O2+NO2 : TROEE( 1.111d28,14000._dp,8.5d-29,6.5_dp,1.1d-11,0._dp,TEMP, C_M) ;
556 {557:462} RU10O2+NO2=MPAN : 0.041*TROE( 8.5d-29,6.5_dp,1.1d-11,1._dp,TEMP,C_M) ;
557 {558:463} MPAN=RU10O2+NO2 : TROEE(1.111d28,14000._dp,8.5d-29,6.5_dp,1.1d-11,0._dp ,TEMP, C_M) ;
558 {559:464} OH+MPAN=CARB7+CO+NO2 : 3.60D-12 ;
559 {560:465} OH+RU12PAN=UCARB10+NO2 : 2.52D-11 ;
560 {561:466} RTN26O2+NO2=RTN26PAN : 0.722*TROE( 8.5d-29 , 6.5_dp , 1.1d-11 , 1._dp,TEMP, C_M) ;
561 {562:467} RTN26PAN=RTN26O2+NO2 : TROEE(1.111d28,14000._dp,8.5d-29,6.5_dp,1.1d-11,0._dp,TEMP, C_M) ;
562 {563:468} OH+RTN26PAN=CH3COCH3+CARB16+NO2 : 3.66D-12 ;
563 {564:469} OH+ANHY=HOCH2CH2O2 : 1.50D-12 ;
564 {565:470} OH+UDCARB8=ANHY+HO2 : 5.20D-11*0.50 ;
565 {566:471} OH+UDCARB11=ANHY+CH3OO : 5.58D-11*0.45 ;
566 {567:472} OH+UDCARB14=ANHY+C2H5O2 : 7.00D-11*0.45 ;
567 {568:473} OH+CH3CL=CH3OO : 7.33D-18*EXP(-809/TEMP)*TEMP**2 ;
568 {569:474} OH+CH2CL2=CH3OO : 6.14D-18*EXP(-389/TEMP)*TEMP**2 ;
569 {570:475} OH+CHCL3=CH3OO : 1.80D-18*EXP(-129/TEMP)*TEMP**2 ;
570 {571:476} OH+CH3CCL3=C2H5O2 : 2.25D-18*EXP(-910/TEMP)*TEMP**2 ;
571 {572:477} OH+TCE= HOCH2CH2O2 : ARR2( 9.64D-12, 1209.0_dp, TEMP) ;
572 {573:478} OH+TRICLETH=HOCH2CH2O2 : ARR2( 5.63D-13, -427.0_dp, TEMP) ;
573 {574:479} OH+CDICLETH=HOCH2CH2O2 : ARR2( 1.94D-12, -90.0_dp, TEMP) ;
574 {575:480} OH+TDICLETH=HOCH2CH2O2 : ARR2( 1.01D-12, -250.0_dp, TEMP) ;
575 {576:481} CH3OO+NO2=CH3O2NO2 : RJPL(1.3D-30,4.0_dp,7.5D-12,2.0_dp,C_M,TEMP) ;
576 {577:482} TNCARB12+hv = RN9O2 + HOCH2CO3 : 7.047*7.8D-5 * j(Pj_no2) ;
577 {578:483} TNCARB11+hv = RTN10O2 + CO + HO2 : 32.6088*4.6D-4 * j(Pj_no2) ;
578 {579:484} RA22NO3+hv = CARB6 + UDCARB14 + HO2 + NO2 : 5.228*7.8D-5 * j(Pj_no2) ;
579 {580:485} RA22OOH+hv = CARB6 + UDCARB14 + HO2 + OH : 0.7 * j(Pj_h2o2) ;
580 {581:486} RA25NO3+hv = CARB6 + UDCARB17 + HO2 + NO2 : 5.228*7.8D-5 * j(Pj_no2) ;
581 {582:487} RA25OOH+hv = CARB6 + UDCARB17 + HO2 + OH : 0.7 * j(Pj_h2o2) ;
582 {583:488} UDCARB17+hv = ANHY + HO2 + RN10O2 : 0.02*0.45*j(Pj_no2) ;
583 {584:489} UDCARB17+hv = RN16O2 + HO2 : 0.02*0.55*j(Pj_no2) ;
584 {585:490} RTN23O2 + NO = RTN23NO3 : 2.40d-12*EXP(360.0/temp)*0.118 ;
585 {586:491} RTN23NO3 + OH = CH3COCH3 + TNCARB12 + NO2 : 5.37D-12 ;
586 {587:492} TNCARB12 + OH = TNCARB11 + HO2 : 3.22D-12 ;
587 {588:493} TNCARB11 + OH = RTN10O2 + CO : 1.33D-11 ;
588 {589:494} TNCARB11 + NO3 = RTN10O2 + CO + HNO3 : 1.44d-12*EXP(-1862.0/temp)*5.5 ;
589 {590:495} TM123B + OH = RA22AO2 : 3.27D-11*0.50 ;
590 {591:496} TM123B + OH = RA22BO2 : 3.27D-11*0.50 ;
591 {592:497} TM124B + OH = RA22AO2 : 3.25D-11*0.50 ;
592 {593:498} TM124B + OH = RA22BO2 : 3.25D-11*0.50 ;
593 {594:499} TM135B + OH = RA22AO2 : 5.67D-11 ;
594 {595:500} OETHTOL + OH = RA22AO2 : 1.19D-11 ;
595 {596:501} METHTOL + OH = RA22AO2 : 1.86D-11 ;
596 {597:502} PETHTOL + OH = RA22AO2 : 1.18D-11 ;
597 {598:503} RA22AO2 + NO = CARB6 + UDCARB14 + HO2 + NO2 : 2.40d-12*EXP(360.0/temp)*0.843 ;
598 {599:504} RA22BO2 + NO = CARB9 + UDCARB11 + HO2 + NO2 : 2.40d-12*EXP(360.0/temp)*0.843 ;
599 {600:505} RA22AO2 + NO = RA22NO3 : 2.40d-12*EXP(360.0/temp)*0.157 ;
600 {601:506} RA22BO2 + NO = RA22NO3 : 2.40d-12*EXP(360.0/temp)*0.157 ;
601 {602:507} RA22AO2 + NO3 = CARB6 + UDCARB14 + HO2 + NO2 : 2.50d-12 ;
602 {603:508} RA22BO2 + NO3 = CARB9 + UDCARB11 + HO2 + NO2 : 2.50d-12 ;
603 {604:509} RA22AO2 + HO2 = RA22OOH : 0.520*2.91d-13*EXP(1300.0/temp)*0.890 ;
604 {605:510} RA22BO2 + HO2 = RA22OOH : 0.520*2.91d-13*EXP(1300.0/temp)*0.890 ;
605 {606:511} RA22AO2 = CARB6 + UDCARB14 + HO2 : 8.80D-13*RO2 ;
606 {607:512} RA22BO2 = CARB9 + UDCARB11 + HO2 : 8.80D-13*RO2 ;
607 {608:513} OH + RA22NO3 = CARB6 + UDCARB14 + NO2 : 9.45D-11 ;
608 {609:514} OH + RA22OOH = CARB6 + UDCARB14 + OH : 1.28D-10 ;
609 {610:515} DIME35EB + OH = RA25O2 : 5.67D-11 ;
610 {611:516} RA25O2 + NO = CARB6 + UDCARB17 + HO2 + NO2 : 2.40d-12*EXP(360.0/temp)*0.833 ;
611 {612:517} RA25O2 + NO = RA25NO3 : 2.40d-12*EXP(360.0/temp)*0.167 ;
612 {613:518} RA25O2 + NO3 = CARB6 + UDCARB17 + HO2 + NO2 : 2.50d-12 ;
613 {614:519} RA25O2 + HO2 = RA25OOH : 0.520*2.91d-13*EXP(1300.0/temp)*0.914 ;
614 {615:520} RA25O2 = CARB6 + UDCARB17 + HO2 : 8.80D-13*RO2 ;
615 {616:521} OH + RA25NO3 = CARB6 + UDCARB17 + NO2 : 9.57D-11 ;
616 {617:522} OH + RA25OOH = CARB6 + UDCARB17 + OH : 1.28D-10 ;
617 {618:523} OH + UDCARB17 = RN16O2 : 7.00D-11*0.55 ;
618 {619:524} OH + UDCARB17 = ANHY + RN10O2 : 7.00D-11*0.45 ;
619 {620:105} HCl = HCl : 1.0_dp ; {copied from cbmz_bb}
620 {621:106} NH3 = NH3 : 1.0_dp ; {copied from cbmz_bb}
621 {622:S04} DMS + OH = CH3SCH2OO + H2O : ARR2(1.12d-11,250._dp,temp) ; {CH3SCH3+OH->CH3SCH2+H2O ; CH3SCH2+O2->CH3SCH2OO - 1st step is slowest, so use that as reaction function (IUPAC preferred value)}
622 {623:S05} DMS + OH {+O2} = DMSO + HO2 : iupac_ch3sch3(9.5d-39,5270._dp,7.5d-29,5610._dp,C_M*0.2_dp,temp) ; {IUPAC preferred value}
623 {624:S06} DMS + NO3 {+O2} = CH3SCH2OO + HNO3 : ARR2(1.9d-13,-520._dp,temp) ;
624 {625:S12} CH3SCH2OO + NO = HCHO + CH3S + NO2 : ARR2(4.9d-12,-263._dp,temp) ;
625 {626:S13} CH3SCH2OO + CH3SCH2OO {+O2} = 2 HCHO + 2 CH3S : 1.0d-11 ;
626 {627:S14} CH3S + O3 = CH3SO {+ O2} : ARR2(1.15d-12,-432._dp,temp) ;
627 {628:S15} CH3S + NO2 = CH3SO + NO : ARR2(3.0d-11,-210._dp,temp) ;
628 {629:S16} CH3SO + NO2 {+O2} = 0.82 CH3SO2 + 0.18 SO2 + 0.18 CH3OO + NO : 1.2d-11 ;
629 {630:S17} CH3SO + O3 {+O2} = CH3SO2 : 6.0d-13 ;
630 {631:S18} CH3SO2 = SO2 + CH3OO : ARR2(5.0d13,9673._dp,temp) {ARR2(1.9d13,8661._dp,temp)} ;
631 {632:S19} CH3SO2 + NO2 = CH3SO3 + NO : 2.2d-12 ;
632 {633:S20} CH3SO2 + O3 = CH3SO3 : 3.0d-13 ;
633 {634:S21} CH3SO3 + HO2 = MSA : 5.0d-11 ;
634 {635:S22} CH3SO3 {+H2O+O2} = CH3OO + H2SO4 : ARR2(1.36d14,11071._dp,temp) ;
635 {636:S23} DMSO + OH = 0.95 MSIA + 0.95 CH3OO + 0.05 DMSO2 : 8.7d-11 ;
636 {637:S24} MSIA + OH = 0.95 CH3SO2 + 0.05 MSA + 0.05 HO2 + H2O : 9.d-11 ;
637 {638:S25} MSIA + NO3 = CH3SO2 + HNO3 : 1.0d-13 ;