2 {J001} M{ = O2} + hv = O + O : .20946_dp*j(Pj_o2) ;
3 {J002} O3 + hv = O1D_CB4{ + O2} : j(Pj_o31d) ;
4 {J003} O3 + hv = O{ + O2} : j(Pj_o33p) ;
5 {J004} N2O + hv = O1D_CB4{ + N2} : j(Pj_n2o) ;
6 {J005} NO2 + hv = O + NO : j(Pj_no2) ;
7 {J006} N2O5 + hv = NO2 + NO3 : j(Pj_n2o5) ;
8 {J007} HNO3 + hv = OH + NO2 : j(Pj_hno3) ;
9 {J008} NO3 + hv = .89 NO2 + .11 NO + .89 O3 : j(Pj_no3o) ;
10 {J009} HO2NO2 + hv = 0.66 HO2 + 0.66 NO2 + 0.33 OH + 0.33 NO3 : j(Pj_hno4) ;
11 {J010} CH3OOH + hv = CH2O + HO2 + OH : j(Pj_ch3o2h) ;
12 {J011} CH2O + hv = HO2 + HO2 + CO : j(Pj_ch2or) ;
13 {J012} CH2O + hv = CO + H2 : j(Pj_ch2om) ;
14 {J013} H2O2 + hv = OH + OH : j(Pj_h2o2) ;
15 {J014} CH3CHO + hv = CH3O2 + CO + HO2 : j(Pj_ch3cho) ;
16 {J015} POOH + hv = CH3CHO + CH2O + HO2 + OH : j(Pj_pooh) ;
17 {J016} CH3COOOH + hv = CH3O2 + OH{ + CO2} : .28_dp*j(Pj_h2o2) ;
18 {J017} PAN + hv = 0.6 CH3CO3 + 0.6 NO2 + 0.4 CH3O2 + 0.4 NO3
19 { + 0.4 CO2} : j(Pj_pan) ;
20 {J018} MPAN + hv = MCO3 + NO2 : j(Pj_pan) ;
21 {J019} MACR + hv = 0.67 HO2 + 0.33 MCO3 + 0.67 CH2O + 0.67 CH3CO3
22 + 0.33 OH + 0.67 CO : j(Pj_macr) ;
23 {J020} MVK + hv = 0.7 C3H6 + 0.7 CO + 0.3 CH3O2 + 0.3 CH3CO3 : j(Pj_mvk) ;
24 {J021} C2H5OOH + hv = CH3CHO + HO2 + OH : j(Pj_ch3o2h) ;
25 {J022} C3H7OOH + hv = 0.82 CH3COCH3 + HO2 + OH : j(Pj_ch3o2h) ;
26 {J023} ROOH + hv = CH3CO3 + CH2O + OH : j(Pj_ch3o2h) ;
27 {J024} CH3COCH3 + hv = CH3CO3 + CH3O2 : j(Pj_ch3coch3) ;
28 {J025} CH3COCHO + hv = CH3CO3 + CO + HO2 : j(Pj_ch3cocho) ;
29 {J026} XOOH + hv = OH : j(Pj_ch3o2h) ;
30 {J027} ONITR + hv = HO2 + CO + NO2 + CH2O : j(Pj_ch3cho) ;
31 {J028} ISOPOOH + hv = .402 MVK + .288 MACR + .69 CH2O + HO2 : j(Pj_ch3o2h) ;
32 {J029} HYAC + hv = CH3CO3 + HO2 + CH2O : j(Pj_hyac) ;
33 {J030} GLYALD + hv = HO2 + HO2 + CO + CH2O : j(Pj_glyald) ;
34 {J031} MEK + hv = CH3CO3 + C2H5O2 : j(Pj_mek) ;
35 {J032} BIGALD + hv = 0.45 CO + 0.13 GLYOXAL + 0.56 HO2 + 0.13 CH3CO3
36 + 0.18 CH3COCHO : .2_dp*j(Pj_no2) ;
37 {J033} GLYOXAL + hv = CO + CO + HO2 + HO2 : j(Pj_gly) ;
38 {J034} ALKOOH + hv = 0.4 CH3CHO + 0.1 CH2O + 0.25 CH3COCH3 + 0.9 HO2
39 + 0.8 MEK + OH : j(Pj_ch3o2h) ;
40 {J035} MEKOOH + hv = OH + CH3CO3 + CH3CHO : j(Pj_ch3o2h) ;
41 {J036} TOLOOH + hv = OH + 0.45 GLYOXAL + 0.45 CH3COCHO + 0.9 BIGALD : j(Pj_ch3o2h) ;
42 {J037} BIGALD1 + hv = 0.6 MALO2 + HO2 : 0.140*j(Pj_no2) ;
43 {J038} BEPOMUC + hv = BIGALD1 + 1.5 HO2 + 1.5 CO : 0.100*j(Pj_no2) ;
44 {J039} TEPOMUC + hv = .5 CH3CO3 + HO2 + 1.5 CO : 0.100*j(Pj_no2) ;
45 {J040} BIGALD2 + hv = 0.6 HO2 + 0.6 DICARBO2 : 0.200*j(Pj_no2) ;
46 {J041} BIGALD3 + hv = 0.6 HO2 + 0.6 CO + 0.6 MDIALO2 : 0.200*j(Pj_no2) ;
47 {J042} BIGALD4 + hv = HO2 + CO + CH3COCHO + CH3CO3 : 0.006*j(Pj_no2) ;
48 {J043} MBOOOH + hv = OH + HO2 + 0.67 * GLYALD + 0.67 * CH3COCH3
49 + 0.33 * HMPROP + 0.33 * CH2O : j(Pj_ch3o2h) ;
50 {J044} HMPROP + hv = 2 * HO2 + CO + CH3COCH3 : j(Pj_glyald) ;
51 {J045} TERPROD1 + hv = HO2 + CO + TERPROD2 : j(Pj_ch3cho) ;
52 {J046} TERPROD2 + hv = 0.15 RO2 + 0.68 CH2O + 0.5 CH3COCH3
53 + 0.65 CH3CO3 + 1.2 HO2 + 1.7 CO{ + 0.8 CO2} : j(Pj_ch3cho) ;
54 {J047} TERPOOH + hv = 0.4 CH2O + 0.05 CH3COCH3 + TERPROD1 + HO2 + OH : j(Pj_ch3o2h) ;
55 {J048} TERP2OOH + hv = OH + 0.375 CH2O + 0.3 CH3COCH3 + 0.25 CO
56 + TERPROD2 + HO2 + 0.25 GLYALD{ + CO2} : j(Pj_ch3o2h) ;
57 {J049} HONO + hv = OH + NO : j(Pj_hno2) ;
58 {T001} O + M{ = O2} = O3 : 0.20946*(C_M *6.00e-34_dp*(TEMP/300._dp)**(-2.3_dp)) ;
59 {T002} O + O3 = M{ = O2 + O2} : ARR2(8.0e-12_dp, 2060.0_dp, TEMP) ;
61 + M{ = O2,N2} = O{ + O2,N2} : .79_dp*ARR2(2.1e-11_dp, -115.0_dp, TEMP) + .21_dp*ARR2(3.2e-11_dp, -70.0_dp, TEMP) ;
62 {T004} O1D_CB4 + H2O = OH + OH : 2.2e-10_dp ;
63 {T005} O1D_CB4 + H2 = HO2 + OH : 1.1e-10_dp ;
64 {T006} OH + H2 = HO2 + H2O : ARR2(5.5e-12_dp, 2000.0_dp, TEMP) ;
65 {T007} O + OH = HO2{ + O2} : ARR2(2.2e-11_dp, -120.0_dp, TEMP) ;
66 {T008} O + HO2 = OH{ + O2} : ARR2(3.0e-11_dp, -200.0_dp, TEMP) ;
67 {T009} OH + O3 = HO2{ + O2} : ARR2(1.7e-12_dp, 940.0_dp, TEMP) ;
68 {T010} HO2 + O3 = OH{ + O2 + O2} : ARR2(1.0e-14_dp, 490.0_dp, TEMP) ;
69 {T011} HO2 + HO2 + H2O = H2O2 : usr9( temp, c_m, c_h2o ) ;
70 {T012} H2O2 + OH = HO2 + H2O : ARR2(2.9e-12_dp, 160.0_dp, TEMP) ;
71 {T013} OH + HO2 = H2O{ + O2} : ARR2(4.8e-11_dp, -250.0_dp, TEMP) ;
72 {T014} OH + OH = H2O + O : ARR2(4.2e-12_dp, 240.0_dp, TEMP) ;
73 {T015} OH + OH{ + M} = H2O2{ + M} : TROE( 6.90e-31_dp , 1.0_dp , 2.60e-11_dp , 0.0_dp , TEMP, C_M) ;
74 {T016} N2O + O1D_CB4 = NO + NO : 6.7e-11_dp ;
75 {T017} N2O + O1D_CB4 = M{ = O2 + N2} : 4.9e-11_dp ;
76 {T018} NO + HO2 = NO2 + OH : ARR2(3.5e-12_dp, -250.0_dp, TEMP) ;
77 {T019} O3 + NO = NO2{ + O2} : ARR2(3.0e-12_dp, 1500.0_dp, TEMP) ;
78 {T020} O + NO2 = NO{ + O2} : ARR2(5.6e-12_dp, -180.0_dp, TEMP) ;
79 {T021} O3 + NO2 = NO3{ + O2} : ARR2(1.2e-13_dp, 2450.0_dp, TEMP) ;
80 {T022} NO3 + HO2 = OH + NO2 : ARR2(2.3e-12_dp, -170.0_dp, TEMP) ;
81 {T023} NO3 + NO2{ + M} = N2O5{ + M} : TROE( 2.e-30_dp , 4.4_dp , 1.4e-12_dp , .7_dp , TEMP, C_M) ;
82 {T024} N2O5{ + M} = NO2 + NO3{ + M} : TROEE(3.333e26_dp,10900._dp, 2.2e-30_dp , 4.4_dp , 1.4e-12_dp , .7_dp , TEMP, C_M ) ;
83 {T025} OH + NO2{ + M} = HNO3{ + M} : TROE( 2.e-30_dp , 3._dp , 2.5e-11_dp , 0._dp , TEMP, C_M) ;
84 {T026} OH + HNO3 = NO3 + H2O : usr5( TEMP, C_M ) ;
85 {T027} NO3 + NO = NO2 + NO2 : ARR2(1.5e-11_dp, -170._dp, TEMP) ;
86 {T028} HO2 + NO2{ + M} = HO2NO2{ + M} : TROE( 1.8e-31_dp , 3.2_dp , 4.7e-12_dp , 1.4_dp , TEMP, C_M) ;
87 {T029} OH + HO2NO2 = NO2 + H2O{ + O2} : ARR2(1.3e-12_dp, -380._dp, TEMP) ;
88 {T030} HO2NO2{ + M} = HO2 + NO2{ + M} : TROEE( 4.76e26_dp,10900._dp, 1.8e-31_dp , 3.2_dp , 4.7e-12_dp , 1.4_dp , TEMP, C_M ) ;
89 {T031} N2O5 + M = 2.00 HNO3{ + M} : usr16( rh, temp ) ;
90 {T032} NO3 = HNO3 : usr17(rh, temp) ;
91 {T033} NO2 = 0.5 OH + 0.5 NO + 0.5 HNO3 : usr17a(rh, temp) ;
92 {T034} CH4 + OH = CH3O2 + H2O : ARR2(2.45e-12_dp, 1775.0_dp, TEMP) ;
93 {T035} CH4 + O1D_CB4 = 0.75 CH3O2 + 0.75 OH + 0.25 CH2O + 0.4 HO2
94 + 0.05 H2 : 1.5e-10_dp ;
95 {T036} CH3O2 + NO = CH2O + NO2 + HO2 + nume : ARR2(2.8e-12_dp, -300._dp, TEMP) ;
96 {T037} CH3O2 + CH3O2 = CH2O + CH2O + HO2 + HO2 + den : ARR2(5.e-13_dp, 424._dp, TEMP) ;
97 {T038} CH3O2 + CH3O2 = CH2O + CH3OH + den : ARR2(1.9e-14_dp, -706._dp, TEMP) ;
98 {T039} CH3O2 + HO2 = CH3OOH{ + O2} + den : ARR2(4.1e-13_dp, -750._dp, TEMP) ;
99 {T040} CH3OOH + OH = 0.7 CH3O2 + 0.3 OH + 0.3 CH2O + H2O : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
100 {T041} CH2O + NO3 = CO + HO2 + HNO3 : ARR2( 6.e-13_dp, 2058._dp, TEMP) ;
101 {T042} CH2O + OH = CO + HO2 + H2O : 9.e-12_dp ;
102 {T043} CO + OH = HO2{ + CO2} : usr8(temp, c_m) ;
103 {T044} C2H4 + OH{ + M} = 0.75 EO2 + 0.5 CH2O + 0.25 HO2{ + M} : TROE( 1.e-28_dp , .8_dp , 8.8e-12_dp , 0._dp , TEMP, C_M) ;
104 {T045} C2H4 + O3 = CH2O + 0.12 HO2 + 0.5 CO + 0.12 OH + 0.5 HCOOH : ARR2(1.2e-14_dp, 2630._dp, TEMP) ;
105 {T046} SO2 + OH = SO4 : usr23( TEMP, C_M ) ;
106 {T047} GLYOXAL + OH = HO2 + CO{ + CO2} : 1.1e-11_dp ;
107 {T048} EO2 + NO = EO + NO2 + nume : ARR2(4.2e-12_dp, -180._dp, TEMP) ;
108 {T049} EO + M{ = O2} = GLYALD + HO2 : 1e-14_dp ;
109 {T050} EO = 2 CH2O + HO2 : ARR2(1.6e11_dp, 4150._dp, TEMP) ;
110 {T051} C2H6 + OH = C2H5O2{ + H2O} : ARR2(8.7e-12_dp, 1070._dp, TEMP) ;
111 {T052} C2H5O2 + NO = CH3CHO + HO2 + NO2 + nume : ARR2(2.6e-12_dp, -365._dp, TEMP) ;
112 {T053} C2H5O2 + HO2 = C2H5OOH + den{ + O2} : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
113 {T054} C2H5O2 + CH3O2 = .7 CH2O + .8 CH3CHO + .3 CH3OH + .2 C2H5OH
114 + HO2 + den : 2.e-13_dp ;
115 {T055} C2H5OOH + OH = .5 C2H5O2 + .5 CH3CHO + .5 OH : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
116 {T056} C3H6 + OH{ + M} = PO2{ + M} : JPL_TROE( 8.0e-27_dp , 3.5_dp , 3.e-11_dp , 0._dp , .5_dp, TEMP, C_M) ;
117 {T057} C3H6 + O3 = .54 CH2O + .19 HO2 + .33 OH + .08 CH4 + .56 CO
118 + .5 CH3CHO + .31 CH3O2 + .25 CH3COOH : ARR2(6.5e-15_dp, 1900._dp, TEMP) ;
119 {T058} C3H6 + NO3 = ONIT : ARR2(4.6e-13_dp, 1156._dp, TEMP) ;
120 {T059} PO2 + NO = CH3CHO + CH2O + HO2 + NO2 + nume : ARR2(4.2e-12_dp, -180._dp, TEMP) ;
121 {T060} PO2 + HO2 = POOH + den{ + O2} : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
122 {T061} POOH + OH = .5 PO2 + .5 OH + .5 HYAC : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
123 {T062} CH3CHO + OH = CH3CO3{ + H2O} : ARR2(5.6e-12_dp, -270._dp, TEMP) ;
124 {T063} CH3CHO + NO3 = CH3CO3 + HNO3 : ARR2(1.4e-12_dp, 1900._dp, TEMP) ;
125 {T064} CH3CO3 + NO = CH3O2 + NO2 + nume{ + CO2} : ARR2(8.1e-12_dp, -270._dp, TEMP) ;
126 {T065} CH3CO3 + NO2{ + M} = PAN{ + M} : TROE( 8.5e-29_dp , 6.5_dp , 1.1e-11_dp , 1._dp , TEMP, C_M) ;
127 {T066} CH3CO3 + HO2 = .75 CH3COOOH + .25 CH3COOH + .25 O3 + den : ARR2(4.3e-13_dp, -1040._dp, TEMP) ;
128 {T067} CH3CO3 + CH3O2 = .9 CH3O2 + .9 HO2 + .1 CH3COOH + CH2O
129 { + 0.5 CO2} + den : ARR2(2.e-12_dp, -500._dp, TEMP) ;
130 {T068} CH3COOOH + OH = .5 CH3CO3 + .5 CH2O{ + H2O + 0.5 CO2} : 1.e-12_dp ;
131 {T069} PAN{ + M} = CH3CO3 + NO2{ + M} : TROEE( 1.111e28_dp,14000._dp,8.5e-29_dp , 6.5_dp , 1.1e-11_dp , 0._dp , TEMP, C_M) ;
132 {T070} CH3CO3 + CH3CO3 = 2 CH3O2 + den{ + 2 CO2} : ARR2(2.5e-12_dp, -500._dp, TEMP) ;
133 {T071} C3H8 + OH = C3H7O2{ + H2O} : ARR2(1.e-11_dp, 660._dp, TEMP) ;
134 {T072} C3H7O2 + NO = .82 CH3COCH3 + .27 CH3CHO + NO2 + HO2 + nume : ARR2(4.e-12_dp, -180._dp, TEMP) ;
135 {T073} C3H7O2 + HO2 = C3H7OOH + den{ + O2} : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
136 {T074} C3H7O2 + CH3O2 = CH2O + HO2 + .82 CH3COCH3 + den : ARR2(3.75e-13_dp, 40._dp, TEMP) ;
137 {T075} C3H7OOH + OH = C3H7O2{ + H2O} : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
138 {T076} CH3COCH3 + OH = RO2{ + H2O} : 3.82e-11_dp*exp( -2000._dp/temp ) + 1.33e-13_dp ;
139 {T077} RO2 + NO = CH3CO3 + CH2O + NO2 + nume : ARR2(2.9e-12_dp, -300._dp, TEMP) ;
140 {T078} RO2 + HO2 = ROOH + den{ + O2} : ARR2(8.6e-13_dp, -700._dp, TEMP) ;
141 {T079} RO2 + CH3O2 = .3 CH3CO3 + .8 CH2O + .3 HO2 + .2 HYAC
142 + .5 CH3COCHO + .5 CH3OH + den : ARR2(2.e-12_dp, -500._dp, TEMP) ;
143 {T080} ROOH + OH = RO2{ + H2O} : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
144 {T081} BIGENE + OH = ENEO2 : 5.4e-11_dp ;
145 {S001} BIGENE + OH = BIGENE + OH + CVASOA4 : 5.4e-11_dp * vbs_yield(nume, den, vbs_ole2, vbs_c1000) ;
146 {S002} BIGENE + OH = BIGENE + OH + CVASOA3 : 5.4e-11_dp * vbs_yield(nume, den, vbs_ole2, vbs_c100) ;
147 {S003} BIGENE + OH = BIGENE + OH + CVASOA2 : 5.4e-11_dp * vbs_yield(nume, den, vbs_ole2, vbs_c10) ;
148 {S004} BIGENE + OH = BIGENE + OH + CVASOA1 : 5.4e-11_dp * vbs_yield(nume, den, vbs_ole2, vbs_c1) ;
149 {T082} ENEO2 + NO = CH3CHO + .5 CH2O + .5 CH3COCH3 + HO2 + NO2 + nume : ARR2(4.2e-12_dp, -180._dp, TEMP) ;
150 {T083} BIGALK + OH = ALKO2 : 3.5e-12_dp ;
151 {S005} BIGALK + OH = BIGALK + OH + CVASOA4 : 3.5e-12_dp * vbs_yield(nume, den, vbs_alk5, vbs_c1000) ;
152 {S006} BIGALK + OH = BIGALK + OH + CVASOA3 : 3.5e-12_dp * vbs_yield(nume, den, vbs_alk5, vbs_c100) ;
153 {S007} BIGALK + OH = BIGALK + OH + CVASOA2 : 3.5e-12_dp * vbs_yield(nume, den, vbs_alk5, vbs_c10) ;
154 {S008} BIGALK + OH = BIGALK + OH + CVASOA1 : 3.5e-12_dp * vbs_yield(nume, den, vbs_alk5, vbs_c1) ;
155 {T084} ALKO2 + NO = .4 CH3CHO + .1 CH2O + .25 CH3COCH3 + .9 HO2
156 + .75 MEK + .9 NO2 + .1 ONIT + nume : ARR2(4.2e-12_dp, -180._dp, TEMP) ;
157 {T085} ALKO2 + HO2 = ALKOOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
158 {T086} ALKOOH + OH = ALKO2 : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
159 {T087} ONIT + OH = NO2 + CH3COCHO : 6.8e-13_dp ;
160 {T088} MEK + OH = MEKO2 : ARR2(2.3e-12_dp, 170._dp, TEMP) ;
161 {T089} MEKO2 + NO = CH3CO3 + CH3CHO + NO2 + nume : ARR2(4.2e-12_dp, -180._dp, TEMP) ;
162 {T090} MEKO2 + HO2 = MEKOOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
163 {T091} MEKOOH + OH = MEKO2 : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
164 {T092} TOLO2 + HO2 = TOLOOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
165 {T093} TOLOOH + OH = TOLO2 : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
166 {T094} ISOP + OH = ISOPO2 : ARR2(2.54e-11_dp, -410._dp, TEMP) ;
167 {S009} ISOP + OH = ISOP + OH + CVBSOA4 : ARR2(2.54e-11_dp, -410._dp, TEMP) * vbs_yield(nume, den, vbs_isop, vbs_c1000) ;
168 {S010} ISOP + OH = ISOP + OH + CVBSOA3 : ARR2(2.54e-11_dp, -410._dp, TEMP) * vbs_yield(nume, den, vbs_isop, vbs_c100) ;
169 {S011} ISOP + OH = ISOP + OH + CVBSOA2 : ARR2(2.54e-11_dp, -410._dp, TEMP) * vbs_yield(nume, den, vbs_isop, vbs_c10) ;
170 {S012} ISOP + OH = ISOP + OH + CVBSOA1 : ARR2(2.54e-11_dp, -410._dp, TEMP) * vbs_yield(nume, den, vbs_isop, vbs_c1) ;
171 {T095} ISOP + O3 = .4 MACR + .2 MVK + .07 C3H6 + .27 OH + .06 HO2
172 + .6 CH2O + .3 CO + .1 O3 + .2 MCO3 + .2 CH3COOH : ARR2(1.05e-14_dp, 2000._dp, TEMP) ;
173 {S013} ISOP + O3 = ISOP + O3 + CVBSOA4 : ARR2(1.05e-14_dp, 2000._dp, TEMP) * vbs_yield(nume, den, vbs_isop, vbs_c1000) ;
174 {S014} ISOP + O3 = ISOP + O3 + CVBSOA3 : ARR2(1.05e-14_dp, 2000._dp, TEMP) * vbs_yield(nume, den, vbs_isop, vbs_c100) ;
175 {S015} ISOP + O3 = ISOP + O3 + CVBSOA2 : ARR2(1.05e-14_dp, 2000._dp, TEMP) * vbs_yield(nume, den, vbs_isop, vbs_c10) ;
176 {S016} ISOP + O3 = ISOP + O3 + CVBSOA1 : ARR2(1.05e-14_dp, 2000._dp, TEMP) * vbs_yield(nume, den, vbs_isop, vbs_c1) ;
177 {T096} ISOPO2 + NO = .08 ONITR + .92 NO2 + .23 MACR + .32 MVK
178 + .33 HYDRALD + .02 GLYOXAL + .02 GLYALD
179 + .02 CH3COCHO + .02 HYAC + .55 CH2O + .92 HO2
180 + nume : ARR2(4.4e-12_dp, -180._dp, TEMP) ;
181 {T097} ISOPO2 + NO3 = HO2 + NO2 + .6 CH2O + .25 MACR + .35 MVK
182 + .36 HYDRALD + 0.02 HYAC + .02 CH3COCHO
183 + .02 GLYOXAL + .02 GLYALD : 2.4e-12_dp ;
184 {T098} ISOPO2 + HO2 = ISOPOOH + den : ARR2(8.e-13_dp, -700._dp, TEMP) ;
185 {T099} ISOPOOH + OH = .5 XO2 + .5 ISOPO2 : ARR2(1.52e-11_dp, -200._dp, TEMP) ;
186 {T100} ISOPO2 + CH3O2 = .25 CH3OH + HO2 + 1.2 CH2O + .19 MACR + .26 MVK
187 + .3 HYDRALD + den : ARR2(5.e-13_dp, -400._dp, TEMP) ;
188 {T101} ISOPO2 + CH3CO3 = CH3O2 + HO2 + 0.6 CH2O + .25 MACR + .35 MVK
189 + .4 HYDRALD + den { + CO2} : 1.4e-11_dp ;
190 {T102} MVK + OH = MACRO2 : ARR2(4.13e-12_dp, -452._dp, TEMP) ;
191 {T103} MVK + O3 = .8 CH2O + .95 CH3COCHO + .08 OH + .2 O3
192 + .06 HO2 + .05 CO + .04 CH3CHO : ARR2(7.52e-16_dp, 1521._dp, TEMP) ;
193 {T104} MACR + OH = .5 MACRO2 + .5 MCO3{ + 0.5 H2O} : ARR2(1.86e-11_dp, -175._dp, TEMP) ;
194 {T105} MACR + O3 = .8 CH3COCHO + .275 HO2 + .2 CO + .7 CH2O
195 + .215 OH + .2 O3 : ARR2(4.4e-15_dp, 2500._dp, TEMP) ;
196 {T106} MACRO2 + NO = NO2 + .47 HO2 + .25 CH2O + .25 CH3COCHO
197 + .53 CH3CO3 + .53 GLYALD + .22 HYAC + .22 CO
198 + nume : ARR2(2.7e-12_dp, -360._dp, TEMP) ;
199 {T107} MACRO2 + NO = .8 ONITR + nume : ARR2(1.3e-13_dp, -360._dp, TEMP) ;
200 {T108} MACRO2 + NO3 = NO2 + .47 HO2 + .25 CH2O + .25 CH3COCHO
201 + .22 CO + .53 GLYALD + .22 HYAC + .53 CH3CO3 : 2.4e-12_dp ;
202 {T109} MACRO2 + HO2 = MACROOH + den : ARR2(8.e-13_dp, -700._dp, TEMP) ;
203 {T110} MACRO2 + CH3O2 = .73 HO2 + .88 CH2O + .11 CO + .24 CH3COCHO
204 + .26 GLYALD + .26 CH3CO3 + .25 CH3OH
205 + .23 HYAC + den : ARR2(5.e-13_dp, -400._dp, TEMP) ;
206 {T111} MACRO2 + CH3CO3 = .25 CH3COCHO + CH3O2 + .22 CO + .47 HO2
207 + .53 GLYALD + .22 HYAC + .25 CH2O + .53 CH3CO3
208 { + CO2} + den : 1.4e-11_dp ;
209 {T112} MACROOH + OH = .5 MCO3 + .2 MACRO2 + .1 OH + .2 HO2 : ARR2(2.3e-11_dp, -200._dp, TEMP) ;
210 {T113} MCO3 + NO = NO2 + CH2O + CH3CO3 + nume{ + CO2} : ARR2(5.3e-12_dp, -360._dp, TEMP) ;
211 {T114} MCO3 + NO3 = NO2 + CH2O + CH3CO3{ + CO2} : 5.e-12_dp ;
212 {T115} MCO3 + HO2 = .25 O3 + .25 CH3COOH + .75 CH3COOOH + den
213 { + 0.75 O2} : ARR2(4.3e-13_dp, -1040._dp, TEMP) ;
214 {T116} MCO3 + CH3O2 = 2 CH2O + HO2 + CH3CO3 + den { + CO2} : ARR2(2.e-12_dp, -500._dp, TEMP) ;
215 {T117} MCO3 + CH3CO3 = CH3O2 + CH2O + CH3CO3 + den { + 2 CO2} : ARR2(4.6e-12_dp, -530._dp, TEMP) ;
216 {T118} MCO3 + MCO3 = 2 CH2O + 2 CH3CO3 + den { + 2 CO2} : ARR2(2.3e-12_dp, -530._dp, TEMP) ;
217 {T119} MCO3 + NO2 + M = MPAN{ + M} : 1.1e-11_dp*300._dp/(temp*c_m) ;
218 {T120} MPAN + M = MCO3 + NO2{ + M} : 1.2221e17_dp*300._dp*exp( -14000._dp/temp )/(temp*c_m) ;
219 {T121} OH + BENZENE = .53 PHENOL + .12 BEPOMUC + .65 HO2 + .35 BENZO2 : ARR2(2.3e-12_dp, 193._dp, TEMP) ;
220 {S017} OH + BENZENE = OH + BENZENE + CVASOA4 : ARR2(2.3e-12_dp, 193._dp, TEMP) * vbs_yield(nume, den, vbs_aro2, vbs_c1000) ;
221 {S018} OH + BENZENE = OH + BENZENE + CVASOA3 : ARR2(2.3e-12_dp, 193._dp, TEMP) * vbs_yield(nume, den, vbs_aro2, vbs_c100) ;
222 {S019} OH + BENZENE = OH + BENZENE + CVASOA2 : ARR2(2.3e-12_dp, 193._dp, TEMP) * vbs_yield(nume, den, vbs_aro2, vbs_c10) ;
223 {S020} OH + BENZENE = OH + BENZENE + CVASOA1 : ARR2(2.3e-12_dp, 193._dp, TEMP) * vbs_yield(nume, den, vbs_aro2, vbs_c1) ;
224 {T122} OH + PHENOL = 0.14 PHENO2 + 0.80 HO2 + 0.06 PHENO : ARR2(4.7e-13_dp, -1220._dp, TEMP) ;
225 {T123} PHENO2 + NO = HO2 + .70 GLYOXAL + NO2 + nume : ARR2(2.6e-12_dp, -365._dp, TEMP) ;
226 {T124} PHENO2 + HO2 = PHENOOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
227 {T125} OH + PHENOOH = PHENO2 : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
228 {T126} PHENO + NO2 = M : 2.1e-12_dp ;
229 {T127} PHENO + O3 = C6H5O2 : 2.8e-13_dp ;
230 {T128} C6H5O2 + NO = PHENO + NO2 + nume : ARR2(2.6e-12_dp, -365._dp, TEMP) ;
231 {T129} C6H5O2 + HO2 = C6H5OOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
232 {T130} OH + C6H5OOH = C6H5O2 : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
233 {T131} BENZO2 + NO = NO2 + GLYOXAL + 0.5 BIGALD1 + HO2 + nume : ARR2(2.6e-12_dp, -365._dp, TEMP) ;
234 {T132} BENZO2 + HO2 = BENZOOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
235 {T133} OH + BENZOOH = BENZO2 : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
236 {T134} MALO2 + NO2 = M : TROE( 8.5e-29_dp , 6.5_dp , 1.1e-11_dp , 1._dp , TEMP, C_M) ;
237 {T135} MALO2 + NO = 0.4 GLYOXAL + 0.4 HO2 + 0.4 CO + nume : ARR2(7.5e-12_dp, -290._dp, TEMP) ;
238 {T136} MALO2 + HO2 = 0.16 GLYOXAL + 0.16 HO2 + 0.16 CO + den : ARR2(4.3e-13_dp, -1040._dp, TEMP) ;
239 {T137} OH + TOLUENE = 0.18 CRESOL + 0.10 TEPOMUC + 0.07 BZOO
240 + 0.65 TOLO2 + 0.28 HO2 : ARR2(1.7e-12_dp, -352._dp, TEMP) ;
241 {S021} OH + TOLUENE = OH + TOLUENE + CVASOA4 : ARR2(1.7e-12_dp, -352._dp, TEMP) * vbs_yield(nume, den, vbs_aro1, vbs_c1000) ;
242 {S022} OH + TOLUENE = OH + TOLUENE + CVASOA3 : ARR2(1.7e-12_dp, -352._dp, TEMP) * vbs_yield(nume, den, vbs_aro1, vbs_c100) ;
243 {S023} OH + TOLUENE = OH + TOLUENE + CVASOA2 : ARR2(1.7e-12_dp, -352._dp, TEMP) * vbs_yield(nume, den, vbs_aro1, vbs_c10) ;
244 {S024} OH + TOLUENE = OH + TOLUENE + CVASOA1 : ARR2(1.7e-12_dp, -352._dp, TEMP) * vbs_yield(nume, den, vbs_aro1, vbs_c1) ;
245 {T138} OH + CRESOL = 0.20 PHENO2 + 0.73 HO2 + 0.07 PHENO : 4.7e-11_dp ;
246 {T139} BZOO + HO2 = BZOOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
247 {T140} OH + BZOOH = BZOO : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
248 {T141} BZOO + NO = BZALD + NO2 + HO2 + nume : ARR2(2.6e-12_dp, -365._dp, TEMP) ;
249 {T142} OH + BZALD = ACBZO2 : ARR2(5.9e-12_dp, -225._dp, TEMP) ;
250 {T143} ACBZO2 + NO2 = PBZNIT : TROE( 8.5e-29_dp , 6.5_dp , 1.1e-11_dp , 1._dp , TEMP, C_M) ;
251 {T144} PBZNIT = ACBZO2 + NO2 : TROEE( 1.111e28_dp,14000._dp,8.5e-29_dp , 6.5_dp , 1.1e-11_dp , 0._dp , TEMP, C_M) ;
252 {T145} ACBZO2 + NO = C6H5O2 + NO2 + nume : ARR2(7.5e-12_dp, -290._dp, TEMP) ;
253 {T146} ACBZO2 + HO2 = 0.4 C6H5O2 + 0.4 OH + den : ARR2(4.3e-13_dp, -1040._dp, TEMP) ;
254 {T147} TOLO2 + NO = NO2 + 0.6 GLYOXAL + 0.4 CH3COCHO + HO2
255 + 0.2 BIGALD1 + 0.2 BIGALD2 + 0.2 BIGALD3 + nume : ARR2(2.6e-12_dp, -365._dp, TEMP) ;
256 {T148} DICARBO2 + HO2 = 0.4 OH + 0.07 HO2 + 0.07 CH3COCHO + 0.07 CO
257 + 0.33 CH3O2 + den : ARR2(4.3e-13_dp, -1040._dp, TEMP) ;
258 {T149} DICARBO2 + NO = NO2 + 0.17 HO2 + 0.17 CH3COCHO + 0.17 CO
259 + 0.83 CH3O2 + nume : ARR2(7.5e-12_dp, -290._dp, TEMP) ;
260 {T150} MDIALO2 + HO2 = 0.4 OH + 0.33 HO2 + 0.07 CH3COCHO + 0.14 CO
261 + 0.07 CH3O2 + 0.07 GLYOXAL + den : ARR2(4.3e-13_dp, -1040._dp, TEMP) ;
262 {T151} MDIALO2 + NO = NO2 + 0.83 HO2 + 0.17 CH3COCHO + 0.35 CO
263 + 0.17 CH3O2 + 0.17 GLYOXAL + nume : ARR2(7.5e-12_dp, -290._dp, TEMP) ;
264 {T152} DICARBO2 + NO2 = M : TROE( 8.5e-29_dp , 6.5_dp , 1.1e-11_dp , 1._dp , TEMP, C_M) ;
265 {T153} MDIALO2 + NO2 = M : TROE( 8.5e-29_dp , 6.5_dp , 1.1e-11_dp , 1._dp , TEMP, C_M) ;
266 {T154} OH + XYLENES = 0.15 XYLOL + 0.23 TEPOMUC + 0.06 BZOO
267 + 0.56 XYLENO2 + 0.38 HO2 : 1.7e-11_dp ;
268 {S025} OH + XYLENES = OH + XYLENES + CVASOA4 : 1.7e-11_dp * vbs_yield(nume, den, vbs_aro2, vbs_c1000) ;
269 {S026} OH + XYLENES = OH + XYLENES + CVASOA3 : 1.7e-11_dp * vbs_yield(nume, den, vbs_aro2, vbs_c100) ;
270 {S027} OH + XYLENES = OH + XYLENES + CVASOA2 : 1.7e-11_dp * vbs_yield(nume, den, vbs_aro2, vbs_c10) ;
271 {S028} OH + XYLENES = OH + XYLENES + CVASOA1 : 1.7e-11_dp * vbs_yield(nume, den, vbs_aro2, vbs_c1) ;
272 {T155} OH + XYLOL = 0.30 XYLOLO2 + 0.63 HO2 + 0.07 PHENO : 8.4e-11_dp ;
273 {T156} XYLOLO2 + NO = HO2 + NO2 + .17 GLYOXAL + .51 CH3COCHO + nume : ARR2(2.6e-12_dp, -365._dp, TEMP) ;
274 {T157} XYLOLO2 + HO2 = XYLOLOOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
275 {T158} OH + XYLOLOOH = XYLOLO2 : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
276 {T159} XYLENO2 + HO2 = XYLENOOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
277 {T160} OH + XYLENOOH = XYLENO2 : ARR2(3.8e-12_dp, -200._dp, TEMP) ;
278 {T161} XYLENO2 + NO = NO2 + HO2 + 0.34 GLYOXAL + 0.54 CH3COCHO
279 + 0.06 BIGALD1 + 0.2 BIGALD2 + 0.15 BIGALD3
280 + .21 BIGALD4 + nume : ARR2(2.6e-12_dp, -365._dp, TEMP) ;
281 {T162} APIN + OH = TERPO2 : ARR2(1.2e-11_dp, -440._dp, TEMP) ;
282 {S029} APIN + OH = APIN + OH + CVBSOA4 : ARR2(1.2e-11_dp, -440._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1000) ;
283 {S030} APIN + OH = APIN + OH + CVBSOA3 : ARR2(1.2e-11_dp, -440._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c100) ;
284 {S031} APIN + OH = APIN + OH + CVBSOA2 : ARR2(1.2e-11_dp, -440._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c10) ;
285 {S032} APIN + OH = APIN + OH + CVBSOA1 : ARR2(1.2e-11_dp, -440._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1) ;
286 {T163} BPIN + OH = TERPO2 : ARR2(1.6e-11_dp, -470._dp, TEMP) ;
287 {S033} BPIN + OH = BPIN + OH + CVBSOA4 : ARR2(1.6e-11_dp, -470._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1000) ;
288 {S034} BPIN + OH = BPIN + OH + CVBSOA3 : ARR2(1.6e-11_dp, -470._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c100) ;
289 {S035} BPIN + OH = BPIN + OH + CVBSOA2 : ARR2(1.6e-11_dp, -470._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c10) ;
290 {S036} BPIN + OH = BPIN + OH + CVBSOA1 : ARR2(1.6e-11_dp, -470._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1) ;
291 {T164} LIMON + OH = TERPO2 : ARR2(4.2e-11_dp, -400._dp, TEMP) ;
292 {S037} LIMON + OH = LIMON + OH + CVBSOA4 : ARR2(4.2e-11_dp, -400._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1000) ;
293 {S038} LIMON + OH = LIMON + OH + CVBSOA3 : ARR2(4.2e-11_dp, -400._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c100) ;
294 {S039} LIMON + OH = LIMON + OH + CVBSOA2 : ARR2(4.2e-11_dp, -400._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c10) ;
295 {S040} LIMON + OH = LIMON + OH + CVBSOA1 : ARR2(4.2e-11_dp, -400._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1) ;
296 {T165} MYRC + OH = TERPO2 : 2.1e-10_dp ;
297 {T166} BCARY + OH = TERPO2 : 2.0e-10_dp ;
298 {T167} APIN + O3 = .33 TERPROD1 + .3 TERPROD2 + .63 OH + .57 HO2
299 + .23 CO + .52 CH3COCH3 + .34 CH2O + .1 BIGALD
300 + .05 HCOOH + .05 BIGALK + .06 CH3CO3 + .06 RO2
301 { + .27 CO2} : ARR2(6.3e-16_dp, 580._dp, TEMP) ;
302 {S041} APIN + O3 = APIN + O3 + CVBSOA4 : ARR2(6.3e-16_dp, 580._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1000) ;
303 {S042} APIN + O3 = APIN + O3 + CVBSOA3 : ARR2(6.3e-16_dp, 580._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c100) ;
304 {S043} APIN + O3 = APIN + O3 + CVBSOA2 : ARR2(6.3e-16_dp, 580._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c10) ;
305 {S044} APIN + O3 = APIN + O3 + CVBSOA1 : ARR2(6.3e-16_dp, 580._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1) ;
306 {T168} BPIN + O3 = .33 TERPROD1 + .3 TERPROD2 + .63 OH + .57 HO2
307 + .23 CO + .52 CH3COCH3 + .34 CH2O + .1 BIGALD
308 + .05 HCOOH + .05 BIGALK + .06 CH3CO3 + .06 RO2
309 { + .27 CO2} : ARR2(1.7e-15_dp, 1300._dp, TEMP) ;
310 {S045} BPIN + O3 = BPIN + O3 + CVBSOA4 : ARR2(1.7e-15_dp, 1300._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1000) ;
311 {S046} BPIN + O3 = BPIN + O3 + CVBSOA3 : ARR2(1.7e-15_dp, 1300._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c100) ;
312 {S047} BPIN + O3 = BPIN + O3 + CVBSOA2 : ARR2(1.7e-15_dp, 1300._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c10) ;
313 {S048} BPIN + O3 = BPIN + O3 + CVBSOA1 : ARR2(1.7e-15_dp, 1300._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1) ;
314 {T169} LIMON + O3 = .33 TERPROD1 + .3 TERPROD2 + .63 OH + .57 HO2
315 + .23 CO + .52 CH3COCH3 + .34 CH2O + .1 BIGALD
316 + .05 HCOOH + .05 BIGALK + .06 CH3CO3 + .06 RO2
317 { + .27 CO2} : ARR2(3.0e-15_dp, 780._dp, TEMP) ;
318 {S049} LIMON + O3 = LIMON + O3 + CVBSOA4 : ARR2(3.0e-15_dp, 780._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1000) ;
319 {S050} LIMON + O3 = LIMON + O3 + CVBSOA3 : ARR2(3.0e-15_dp, 780._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c100) ;
320 {S051} LIMON + O3 = LIMON + O3 + CVBSOA2 : ARR2(3.0e-15_dp, 780._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c10) ;
321 {S052} LIMON + O3 = LIMON + O3 + CVBSOA1 : ARR2(3.0e-15_dp, 780._dp, TEMP) * vbs_yield(nume, den, vbs_terp, vbs_c1) ;
322 {T170} MYRC + O3 = .33 TERPROD1 + .3 TERPROD2 + .63 OH + .57 HO2
323 + .23 CO + .52 CH3COCH3 + .34 CH2O + .1 BIGALD
324 + .05 HCOOH + .05 BIGALK + .06 CH3CO3 + .06 RO2
325 { + .27 CO2} : 4.7e-16_dp ;
326 {T171} BCARY + O3 = .33 TERPROD1 + .3 TERPROD2 + .63 OH + .57 HO2
327 + .23 CO + .52 CH3COCH3 + .34 CH2O + .1 BIGALD
328 + .05 HCOOH + .05 BIGALK + .06 CH3CO3 + .06 RO2
329 { + .27 CO2} : 1.2e-14_dp ;
330 {T172} LIMON + NO3 = NTERPO2 : 1.1e-11_dp ;
331 {T173} MYRC + NO3 = NTERPO2 : 1.2e-11_dp ;
332 {T174} BCARY + NO3 = NTERPO2 : 1.9e-11_dp ;
333 {T175} TERPO2 + NO = .1 ONITR + .9 NO2 + .36 CH2O + .045 CH3COCH3
334 + .9 TERPROD1 + .9 HO2 + nume : ARR2(4.2e-12_dp, -180._dp, TEMP) ;
335 {T176} TERPO2 + HO2 = TERPOOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
336 {T177} TERPO2 + CH3O2 = TERPROD1 + .95 CH2O + .25 CH3OH + HO2
337 + .025 CH3COCH3 + den : ARR2(2.0e-12_dp, -500._dp, TEMP) ;
338 {T178} TERPOOH + OH = TERPO2 : 3.3e-11_dp ;
339 {T179} TERP2OOH + OH = TERP2O2 : 2.3e-11_dp ;
340 {T180} TERPROD1 + OH = TERP2O2 : 5.7e-11_dp ;
341 {T181} TERPROD1 + NO3 = .5 TERP2O2 + .5 NTERPO2 : 1.0e-12_dp ;
342 {T182} TERP2O2 + NO = .1 ONITR + .9 NO2 + .34 CH2O + .27 CH3COCH3
343 + .225 CO + .9 TERPROD2 + .9 HO2 + .225 GLYALD
344 { + .9 CO2} + nume : ARR2(4.2e-12_dp, -180._dp, TEMP) ;
345 {T183} TERP2O2 + HO2 = TERP2OOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
346 {T184} TERP2O2 + CH3O2 = TERPROD2 + .93 CH2O + .25 CH3OH + HO2
347 { + .5 CO2} + .125 CO + .125 GLYALD
348 + .15 CH3COCH3 + den : ARR2(2.0e-12_dp, -500._dp, TEMP) ;
349 {T185} TERPROD2 + OH = .15 RO2 + .68 CH2O{ + 1.8 CO2} + .5 CH3COCH3
350 + .65 CH3CO3 + .2 HO2 + .7 CO : 3.4e-11_dp ;
351 {T186} NTERPO2 + NO = .1 ONITR + 1.9 NO2 + .9 TERPROD1 + nume : ARR2(4.2e-12_dp, -180._dp, TEMP) ;
352 {T187} NTERPO2 + HO2 = ONITR + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
353 {T188} NTERPO2 + CH3O2 = .5 ONITR + .75 CH2O + .25 CH3OH + .5 HO2
354 + .5 TERPROD1 + .5 NO2 + den : ARR2(2.0e-12_dp, -500._dp, TEMP) ;
355 {T189} NTERPO2 + NO3 = 2 NO2 + TERPROD1 : 2.4e-12_dp ;
356 {T190} CH3COOH + OH = CH3O2{ + H2O + CO2} : 7.e-13_dp ;
357 {T191} ISOP + NO3 = ISOPNO3 : ARR2(3.03e-12_dp, 446._dp, TEMP) ;
358 {T192} ISOPNO3 + NO = 1.206 NO2 + .794 HO2 + .072 CH2O + .167 MACR
359 + .039 MVK + .794 ONITR + nume : ARR2(2.7e-12_dp, -360._dp, TEMP) ;
360 {T193} ISOPNO3 + NO3 = 1.206 NO2 + .072 CH2O + .167 MACR + .039 MVK
361 + .794 ONITR + .794 HO2 : 2.4e-12_dp ;
362 {T194} ISOPNO3 + HO2 = .206 NO2 + .206 OH + .206 CH2O + .167 MACR
363 + .039 MVK + .794 ONITR + den : ARR2(8.e-13_dp, -700._dp, TEMP) ;
364 {T195} CH3COCHO + OH = CH3CO3 + CO{ + H2O} : ARR2(8.4e-13_dp, -830._dp, TEMP) ;
365 {T196} CH3COCHO + NO3 = HNO3 + CO + CH3CO3 : ARR2(1.4e-12_dp, 1860._dp, TEMP) ;
366 {T197} ONITR + OH = HYDRALD + HO2 + .4 NO2 : 4.5e-11_dp ;
367 {T198} ONITR + NO3 = HYDRALD + HO2 + NO2 : ARR2(1.4e-12_dp, 1860._dp, TEMP) ;
368 {T199} HYDRALD + OH = XO2 : ARR2(1.86e-11_dp, -175._dp, TEMP) ;
369 {T200} XO2 + NO = NO2 + HO2 + .25 CO + .25 CH2O + .25 GLYOXAL
370 + .25 CH3COCHO + .25 HYAC + .25 GLYALD + nume : ARR2(2.7e-12_dp, -360._dp, TEMP) ;
371 {T201} XO2 + NO3 = NO2 + HO2 + .25 CO + .25 CH2O + .25 GLYOXAL
372 + .25 CH3COCHO + .25 HYAC + .25 GLYALD : 2.4e-12_dp ;
373 {T202} XO2 + HO2 = XOOH + den : ARR2(8.e-13_dp, -700._dp, TEMP) ;
374 {T203} XO2 + CH3O2 = .3 CH3OH + .8 HO2 + .8 CH2O + .2 CO
375 + .1 GLYOXAL + .1 CH3COCHO + .1 HYAC
376 + .1 GLYALD + den : ARR2(5.e-13_dp, -400._dp, TEMP) ;
377 {T204} XO2 + CH3CO3 = .25 CO + .25 CH2O + .25 GLYOXAL + CH3O2 + HO2
378 + .25 CH3COCHO + .25 HYAC + .25 GLYALD { + CO2}
379 + den : ARR2(1.3e-12_dp, -640._dp, TEMP) ;
380 {T205} XOOH + OH = XO2{ + H2O} : ARR2(1.9e-12_dp, -190._dp, TEMP) ;
381 {T206} XOOH + OH = OH{ + H2O} : THERMAL_T2(7.69e-17_dp, -253._dp, TEMP) ;
382 {T207} CH3OH + OH = HO2 + CH2O : ARR2(7.3e-12_dp, 620._dp, TEMP) ;
383 {T208} C2H5OH + OH = HO2 + CH3CHO : ARR2(6.9e-12_dp, 230._dp, TEMP) ;
384 {T209} MPAN + OH = .5 HYAC + .5 NO3 + .5 CH2O + .5 HO2 { + 0.5 CO2} : JPL_TROE( 8.e-27_dp , 3.5_dp , 3.e-11_dp , 0.0_dp , .5_dp, TEMP, C_M) ;
385 {T210} PAN + OH = CH2O + NO3{ + CO2} : 4.e-14_dp ;
386 {T211} HYAC + OH = CH3COCHO + HO2 : 3.e-12_dp ;
387 {T212} GLYALD + OH = HO2 + .2 GLYOXAL + .8 CH2O { + 0.8 CO2} : 1.e-11_dp ;
388 {T213} DMS + OH = SO2 : ARR2(9.6e-12_dp, 234._dp, TEMP) ;
389 {T214} DMS + OH = .5 SO2 + .5 HO2 : usr24( temp, c_m ) ;
390 {T215} DMS + NO3 = SO2 + HNO3 : ARR2(1.9e-13_dp, -520._dp, TEMP) ;
391 {T216} NH3 + OH = M : ARR2(1.7e-12_dp, 710._dp, TEMP) ;
392 {T217} HO2 = .5 H2O2 : usr26( rh, temp ) ;
393 {T218} C2H5O2 + C2H5O2 = 1.6 CH3CHO + 1.2 HO2 + .4 C2H5OH + den : 6.8e-14_dp ;
394 {T219} MBO + OH = MBOO2 : ARR2(8.1e-12_dp, -610._dp, TEMP) ;
395 {T220} MBOO2 + NO = HO2 + .67 GLYALD + .67 CH3COCH3 + .33 HMPROP
396 + .33 CH2O + NO2 + nume : ARR2(2.6e-12_dp, -365._dp, TEMP) ;
397 {T221} MBOO2 + CH3O2 = .917 CH2O + HO2 + .25 CH3OH + .333 GLYALD
398 + .333 CH3COCH3 + .167 HMPROP + den : ARR2(3.75e-13_dp, 40._dp, TEMP) ;
399 {T222} HMPROP + OH = HMPROPO2 : 1.4e-11_dp ;
400 {T223} HMPROPO2 + NO = NO2 + HO2 + CH3COCH3{ + CO2} + nume : ARR2(2.6e-12_dp, -365._dp, TEMP) ;
401 {T224} HMPROPO2 + HO2 = .4 OH + .4 HO2 + .4 CH3COCH3{ + .4 * CO2} + den : ARR2(4.3e-13_dp, -1040._dp, TEMP) ;
402 {T225} MBOO2 + HO2 = MBOOOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
403 {T226} MBOOOH + OH = .5 MBOO2 + .5 OH : ARR2(3.8e-12_dp ,-200._dp, TEMP) ;
404 {T227} MBO + O3 = .1 CO + .5 CH2O + .1 CH3COCH3 + .9 HMPROP
405 + .25 HCOOH + .25 CO + .06 HO2 + .06 OH : 1e-17_dp ;
406 {T228} MBO + NO3 = MBONO3O2 : ARR2(4.6e-14_dp, 400._dp, TEMP) ;
407 {T229} MBONO3O2 + HO2 = .0 * H2O + den : ARR2(4.3e-13_dp, -1040._dp, TEMP) ;
408 {T230} MBONO3O2 + NO = .25 HMPROP + .25 CH2O + 1.25 NO2 + .75 ONIT
409 + .75 CH3COCH3 + .75 HO2 + nume : ARR2(2.6e-12_dp, -365._dp, TEMP) ;
410 {T231} MBONO3O2 + NO3 = .25 HMPROP + .25 CH2O + 1.25 NO2 + .75 ONIT
411 + .75 CH3COCH3 + .75 HO2 : 2.4e-12_dp ;
412 {T232} C2H2 + OH{ + M} = 0.65 GLYOXAL + 0.65 OH + 0.35 HCOOH + 0.35 HO2
413 + 0.35 CO{ + M} : TROE( 5.5e-30_dp , 0._dp, 8.3e-13_dp, -2._dp, TEMP, C_M) ;
414 {T233} HCOOH + OH = HO2 + H2O{ + CO2} : 4.5e-13 ;
415 {T234} CH2O + HO2 = HOCH2OO : ARR2(9.7e-15_dp, -625._dp, TEMP) ;
416 {T235} HOCH2OO = CH2O + HO2 : ARR2(2.4e12_dp, 7000._dp, TEMP) ;
417 {T236} HOCH2OO + NO = HCOOH + NO2 + HO2 + nume : ARR2(2.6e-12_dp, -265._dp, TEMP) ;
418 {T237} HOCH2OO + HO2 = HCOOH + den : ARR2(7.5e-13_dp, -700._dp, TEMP) ;
419 {S053} CVASOA4 + OH = 1.075 CVASOA3 + OH : ARR2(1.0D-11, 0.0_dp, TEMP) ;
420 {S054} CVASOA3 + OH = 1.075 CVASOA2 + OH : ARR2(1.0D-11, 0.0_dp, TEMP) ;
421 {S055} CVASOA2 + OH = 1.075 CVASOA1 + OH : ARR2(1.0D-11, 0.0_dp, TEMP) ;
422 {S056} CVASOA1 + OH = 1.075 CVASOAX + OH : ARR2(1.0D-11, 0.0_dp, TEMP) ;
423 {S057} CVBSOA4 + OH = 1.075 CVBSOA3 + OH : ARR2(1.0D-11, 0.0_dp, TEMP) ;
424 {S058} CVBSOA3 + OH = 1.075 CVBSOA2 + OH : ARR2(1.0D-11, 0.0_dp, TEMP) ;
425 {S059} CVBSOA2 + OH = 1.075 CVBSOA1 + OH : ARR2(1.0D-11, 0.0_dp, TEMP) ;
426 {S060} CVBSOA1 + OH = 1.075 CVBSOAX + OH : ARR2(1.0D-11, 0.0_dp, TEMP) ;